浏览全部资源
扫码关注微信
Received：20 October 2019，
Published：28 April 2020
移动端阅览
近年来的研究发现，鄂尔多斯盆地东南部延长组7段（长7段）中-低成熟度页岩中发育有机孔，但是对于影响陆相页岩储层中有机孔发育的影响因素有待进一步深入研究。借助氩离子剖光和场发射扫描电镜分析等技术，研究了鄂尔多斯盆地东南部长7段页岩中不同类型固体有机质中有机孔发育特征，并统计分析了不同成熟度页岩样品中干酪根和运移固体有机质的有机孔径和有机孔面积占有机质面积的百分比（
S
R
），以此为基础讨论了影响有机孔发育的主要因素。结果表明，长7段中不同成熟度页岩（
R
o
：0.50%~1.25%）中有机质均发育有机孔，但是干酪根和运移固体有机质中的有机孔发育程度具有明显差异。沉积有机质（干酪根）主要以顺层富集、孤立分散及与粘土矿物共生3种形式赋存在页岩中，有机孔发育程度相对较低，有机孔面积占有机质面积的百分比介于0~44.13%，一般小于10%，平均6.03%；有机孔孔径主要在10~40 nm。运移固体有机质主要赋存在刚性颗粒粒间孔/粒间溶蚀孔、刚性颗粒与粘土矿物间粒间孔/粒间溶蚀孔和黄铁矿晶间孔等无机矿物孔中，有机孔发育程度较高，有机孔面积占有机质面积的百分比介于0~46.51%，一般小于30%，平均23.05%；孔径较大，主要在50~100 nm。长7段页岩中有机孔的发育程度主要受控于固体有机质类型、运移有机质丰度和有机质成熟度，运移固体有机质丰度越大，有机质成熟度越高，有机孔越发育。
Recent studies have shown that organic pores are developed in the medium-to-low-maturity shale of the 7th member of Yanchang Formation in the Southeastern Ordos Basin
but the influencing factors on the development of organic pores in the continental shale reservoir need to be further understood.With the aid of argon ion polishing and FE-SEM observation
we observed the characteristics of organic pores in Chang 7 shale in the Southeastern Ordos Basin.Statistical analysis was made on the organic pore sizes in kerogen of different maturity and different types of migrated solid organic matters
and also on the ratio of organic pore area to the total organic matter ar
ea (
S
R
) of these organic matters.Thereaf-ter
main factors affecting the development of organic pores were discussed.The results indicate that organic pores were widely developed in shales of diverse maturity (
R
o
:0.5%-1.25%) in the Chang 7 member
but there were significant differences in the development of organic pores in kerogens and migrated solid organic matters.Sedimentary organic matter (kerogen) occurs mainly in the form of enrichment along beddings
isolated dispersion and combination with clay minerals in shale and has relatively lower degree of organic pore development.The ratio of the organic pore area to the total organic matter area ranges from 0% to 44.13%
averaging at 6.03%
but generally less than 10%.The majority of organic pores ranges from 10 nm to 40 nm in size.The migrated solid organic matters mainly occurs in inorganic mineral pores
including inter-particle pores/inter-particle dissolution pores in rigid particles
inter-particle pores/inter-particle dissolution pores between rigid particles and clay minerals
intercrystalline pores in pyrite of shale.These organic matters have relatively higher degree of organic pore development.The ratio of the organic pore area to the organic matter area varies from 0% to 46.51%
averaging at 23.05% and generally less than 30%.In addition
the pore size is larger
mainly ranging from 50 nm to 100 nm.The development of organic pores in the Chang 7 member shale is mainly controlled by the organic matter type
the abundance of migrated solid organic matters and the maturity of organic matter:positively correlated with higher content of migrated solid organic matters and more maturity of the organic matters.
Ambrose R J , Hartman R C , Diaz-Campos M , et al . Shale gas-in-place calculations part Ⅰ:new pore-scale considerations [J ] . SPE Journal , 2012 , 17 ( 1 ): 219 - 229 . DOI: 10.2118/131772-PA http://doi.org/10.2118/131772-PA DOI: 10.2118/131772-PA http://doi.org/10.2118/131772-PA
Ross D J K , Bustin R M . Characterizing the shale gas resource potential of Devonian-Mississippian strata in the Western Canada sedimentary basin:Application of an integrated formation evaluation [J ] . AAPG Bulletin , 2008 , 92 ( 1 ): 87 - 125 . DOI: 10.1306/09040707048 http://doi.org/10.1306/09040707048
Ross D J K , Bustin R M . The importance of shale composition and pore structure upon gas storage potential of shale gas reservoirs [J ] . Marine and Petroleum Geology , 2009 , 26 ( 6 ): 916 - 927 . DOI: 10.1016/j.marpetgeo.2008.06.004 http://doi.org/10.1016/j.marpetgeo.2008.06.004
Loucks R G , Reed R M , Ruppel S C , et al . Spectrum of pore types and networks in mudrocks and a descriptive classification for matrix-related mudrock pores [J ] . AAPG Bulletin , 2012 , 96 ( 6 ): 1071 - 1098 . DOI: 10.1306/08171111061 http://doi.org/10.1306/08171111061
Milliken K L , Rudnicki M , Awwiller D N , et al . Organic matter-hosted pore system, Marcellus formation(Devonian), Pennsylvania [J ] . AAPG Bulletin , 2013 , 97 ( 2 ): 177 - 200 . DOI: 10.1306/07231212048 http://doi.org/10.1306/07231212048
Bernard S , Wirth R , Schreiber A , et al . Formation of nanoporous pyrobitumen residues during maturation of the Barnett Shale(Fort Worth Basin) [J ] . International Journal of Coal Geology , 2012 , 103 , 3 - 11 . DOI: 10.1016/j.coal.2012.04.010 http://doi.org/10.1016/j.coal.2012.04.010
Cardott B J , Landis C R , Curtis M E . Post-oil solid bitumen network in the Woodford Shale, USA-a potential primary migration pathway [J ] . International Journal of Coal Geology , 2015 , 139 , 106 - 113 . DOI: 10.1016/j.coal.2014.08.012 http://doi.org/10.1016/j.coal.2014.08.012
俞雨溪 , 罗晓容 , 雷裕红 , 等 . 陆相页岩孔隙结构特征研究——以鄂尔多斯盆地延长组页岩为例 [J ] . 天然气地球科学 , 2016 , 27 ( 4 ): 716 - 726 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=trqdqkx201604017 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=trqdqkx201604017
Yu Yuxi , Luo Xiarong , Lei Yuhong , et al . Characterization of lacustrine shale pore structure:An example from the Upper-Triassic Yanchang Formation, Ordos Basin [J ] . Natural Gas Geoscience , 2016 , 27 ( 4 ): 716 - 726 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=trqdqkx201604017 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=trqdqkx201604017
Loucks R G , Reed R M , Ruppel S C , et al . Morphology, genesis, and distribution of nanometer-scale pores in siliceous mudstones of the Mississippian Barnett Shale [J ] . Journal of Sedimentary Research , 2009 , 79 ( 12 ): 848 - 861 . DOI: 10.2110/jsr.2009.092 http://doi.org/10.2110/jsr.2009.092
Curtis M E , Cardott B J , Sondergeld C H , et al . Development of organic porosity in the Woodford Shale with increasing thermal maturity [J ] . International Journal of Coal Geology , 2012 , 103 , 26 - 31 . DOI: 10.1016/j.coal.2012.08.004 http://doi.org/10.1016/j.coal.2012.08.004
Milliken K L , Esch W L , Reed R M , et al . Grain assemblages and strong diagenetic overprinting in siliceous mudrocks, Barnett Shale(Mississippian), Fort Worth Basin, Texas [J ] . AAPG Bulletin , 2012 , 96 ( 8 ): 1553 - 1578 . DOI: 10.1306/12011111129 http://doi.org/10.1306/12011111129
Alcantar-Lopez L, Chipera S J.Improving Our Understanding of Porosity in Source Rock Reservoirs through Advanced Imaging Techniques[C].Unconventional Resources Technology Conference.Society of Exploration Geophysicists.The Denver, Colorado, USA: 2013.
Löhr S C , Baruch E T , Hall P A , et al . Is organic pore development in gas shales influenced by the primary porosity and structure of thermally immature organic matter? [J ] . Organic Geochemistry , 2015 , 87 , 119 - 132 . DOI: 10.1016/j.orggeochem.2015.07.010 http://doi.org/10.1016/j.orggeochem.2015.07.010
杨巍 , 陈国俊 , 吕成福 , 等 . 鄂尔多斯盆地东南部延长组长7段富有机质页岩孔隙特征 [J ] . 天然气地球科学 , 2015 , 26 ( 3 ): 418 - 426 . http://d.old.wanfangdata.com.cn/Periodical/trqdqkx201503003 http://d.old.wanfangdata.com.cn/Periodical/trqdqkx201503003
Yang Wei , Chen Guojun , Lv Chengfu , et al . Micropore characteristics of the organic-rich shale in the 7~(th)Member of the Yanchang Formation in the Southeast of Ordos Basin [J ] . Natural Gas Geoscience , 2015 , 26 ( 3 ): 418 - 426 . http://d.old.wanfangdata.com.cn/Periodical/trqdqkx201503003 http://d.old.wanfangdata.com.cn/Periodical/trqdqkx201503003
王香增 , 刘国恒 , 黄志龙 , 等 . 鄂尔多斯盆地东南部延长组长7段泥页岩储层特征 [J ] . 天然气地球科学 , 2015 , 26 ( 7 ): 1385 - 1394 . http://d.old.wanfangdata.com.cn/Periodical/trqdqkx201507018 http://d.old.wanfangdata.com.cn/Periodical/trqdqkx201507018
Wang Xiangzeng , Liu Guoheng , Huang Zhilong , et al . The characteristics of shale reservoir of the No.7 members in Yanchang Formation of Southeast Ordos Basin [J ] . Natural Gas Geoscience , 2015 , 26 ( 7 ): 1385 - 1394 . http://d.old.wanfangdata.com.cn/Periodical/trqdqkx201507018 http://d.old.wanfangdata.com.cn/Periodical/trqdqkx201507018
王香增 , 范柏江 , 张丽霞 , 等 . 陆相页岩气的储集空间特征及赋存过程——以鄂尔多斯盆地陕北斜坡构造带延长探区延长组长7段为例 [J ] . 石油与天然气地质 , 2015 , 36 ( 4 ): 651 - 659 . http://ogg.pepris.com/CN/10.11743/ogg20150415 http://ogg.pepris.com/CN/10.11743/ogg20150415
Wang Xiangzeng , Fan Baijiang , Zhang Lixia , et al . Reservoir space characteristics and charging process of Lacustrine shale gas-a case study of the Chang 7 member in Yanchang Block in Shanbei slope of Erdos Basin [J ] . Oil & Gas Geology , 2015 , 36 ( 4 ): 651 - 658 . http://ogg.pepris.com/CN/10.11743/ogg20150415 http://ogg.pepris.com/CN/10.11743/ogg20150415
王香增 , 张丽霞 , 李宗田 , 等 . 鄂尔多斯盆地延长组陆相页岩孔隙类型划分方案及其油气地质意义 [J ] . 石油与天然气地质 , 2016 , 37 ( 1 ): 1 - 7 . http://ogg.pepris.com/CN/10.11743/ogg20160101 http://ogg.pepris.com/CN/10.11743/ogg20160101
Wang Xiangzeng , Zhang Lixia , Li Zongtian , et al . Pore type classification scheme for continental Yanchang shale in Ordos Basin and its geological significance [J ] . Oil & Gas Geology , 2016 , 37 ( 1 ): 1 - 7 . http://ogg.pepris.com/CN/10.11743/ogg20160101 http://ogg.pepris.com/CN/10.11743/ogg20160101
王香增 , 张丽霞 , 雷裕红 , 等 . 低熟湖相页岩内运移固体有机质和有机孔特征——以鄂尔多斯盆地东南部延长组长7段页岩为例 [J ] . 石油学报 , 2018 , 39 ( 2 ): 141 - 151 .
Wang Xiangzeng , Zhang Lixia , Lei Yuhong , et al . Characteristics of migrated solid organic matters and organic pores in low maturity lacustrine shale:a case study of the shale in Chang 7 oil-bearing formation of Yanchang Formation, southeastern Ordos Basin [J ] . Acta Petrolei Sinica , 2018 , 39 ( 2 ): 141 - 151 .
何自新 . 鄂尔多斯盆地演化与油气 [M ] . 石油工业出版社 , 2003 .
He Zixin . The evolution and petroleum of Ordos Basin [M ] . Beijing : Petroleum Industry Press , 2003 .
杨明慧 , 刘池洋 . 鄂尔多斯中生代陆相盆地层序地层格架及多种能源矿产聚集 [J ] . 石油与天然气地质 , 2006 , 27 ( 4 ): 563 - 570 . DOI: 10.3321/j.issn:0253-9985.2006.04.019 http://doi.org/10.3321/j.issn:0253-9985.2006.04.019
Yang Minghui , Liu Chiyang . Sequence stratigraphic framework and its control on accumulation of various energy resources in the Mesozoic continental basins in Ordos [J ] . Oil & Gas Geology , 2006 , 27 ( 4 ): 563 - 570 . DOI: 10.3321/j.issn:0253-9985.2006.04.019 http://doi.org/10.3321/j.issn:0253-9985.2006.04.019
王香增 , 高胜利 , 高潮 . 鄂尔多斯盆地南部中生界陆相页岩气地质特征 [J ] . 石油勘探与开发 , 2014 , 41 ( 3 ): 294 - 304 . http://d.old.wanfangdata.com.cn/Periodical/syktykf201403005 http://d.old.wanfangdata.com.cn/Periodical/syktykf201403005
Wang Xiangzeng , Gao Shengli , Gao Chao . Geological features of Mesozoic lacustrine shale gas in south of Ordos Basin, NW China [J ] . Petroleum Exploration & Development , 2014 , 41 ( 3 ): 294 - 304 . http://d.old.wanfangdata.com.cn/Periodical/syktykf201403005 http://d.old.wanfangdata.com.cn/Periodical/syktykf201403005
张文正 , 杨华 , 杨奕华 , 等 . 鄂尔多斯盆地长7优质烃源岩的岩石学、元素地球化学特征及发育环境 [J ] . 地球化学 , 2008 , 37 ( 1 ): 59 - 64 . DOI: 10.3321/j.issn:0379-1726.2008.01.008 http://doi.org/10.3321/j.issn:0379-1726.2008.01.008
Zhang Wwenzheng , Hua Y , Yang Y H . Petrology and element geochemistry and development environment of Yanchang Formation Chang-7 high quality source rocks in Ordos Basin [J ] . Geochimica , 2008 , 37 ( 1 ): 59 - 64 . DOI: 10.3321/j.issn:0379-1726.2008.01.008 http://doi.org/10.3321/j.issn:0379-1726.2008.01.008
程明 , 罗晓容 , 雷裕红 , 等 . 鄂尔多斯盆地张家滩页岩粉砂质夹层/纹层分布、分形特征和估算方法研究 [J ] . 天然气地球科学 , 2015 , 26 ( 5 ): 845 - 854 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=trqdqkx201505007 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=trqdqkx201505007
Cheng Ming , Luo X R , Lei Y H , et al . The distribution, fractal characteristic and thickness estimation of silty laminae and beds in the Zhangjiatan Shale, Ordos Basin [J ] . Natural Gas Geoscience , 2015 , 26 ( 5 ): 845 - 854 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=trqdqkx201505007 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=trqdqkx201505007
Lei Yuhong , Luo X R , Wang X Z , et al . Characteristics of silty laminae in Zhangjiatan Shale of southeastern Ordos Basin, China:Implications for shale gas formation [J ] . AAPG Bulletin , 2015 , 99 ( 4 ): 661 - 687 . DOI: 10.1306/09301414059 http://doi.org/10.1306/09301414059
孔庆芬 . 鄂尔多斯盆地延长组烃源岩有机显微组分特征 [J ] . 新疆石油地质 , 2007 , 28 ( 2 ): 163 - 166 . DOI: 10.3969/j.issn.1001-3873.2007.02.009 http://doi.org/10.3969/j.issn.1001-3873.2007.02.009
Kong Qingfen . The organic maceral characteristic of Yanchang source rock in Ordos Basin [J ] . Xinjiang Petroleum Geology , 2007 , 28 ( 2 ): 163 - 166 . DOI: 10.3969/j.issn.1001-3873.2007.02.009 http://doi.org/10.3969/j.issn.1001-3873.2007.02.009
Guo H , Jia W , Peng P , et al . The composition and its impact on the methane sorption of lacustrine shales from the Upper Triassic Yanchang Formation, Ordos Basin, China [J ] . Marine and Petroleum Geology , 2014 , 57 , 509 - 520 . DOI: 10.1016/j.marpetgeo.2014.05.010 http://doi.org/10.1016/j.marpetgeo.2014.05.010
雷裕红 , 王晖 , 罗晓容 , 等 . 鄂尔多斯盆地张家滩页岩液态烃特征及对页岩气量估算的影响 [J ] . 石油学报 , 2016 , 37 ( 8 ): 952 - 961 . http://d.old.wanfangdata.com.cn/Periodical/syxb201608002 http://d.old.wanfangdata.com.cn/Periodical/syxb201608002
Lei Yuhong , Wang Hui , Luo Xiaorong , et al . The characteristics of liquid hydrocarbons and itseffects on the estimation of shale gas content in Zhangjiatan Shale, Ordos basin [J ] . Acta Petrolei Sinica , 2016 , 37 ( 8 ): 952 - 961 . http://d.old.wanfangdata.com.cn/Periodical/syxb201608002 http://d.old.wanfangdata.com.cn/Periodical/syxb201608002
姜呈馥 , 王香增 , 张丽霞 , 等 . 鄂尔多斯盆地东南部延长组长7段陆相页岩气地质特征及勘探潜力评价 [J ] . 中国地质 , 2013 , 40 ( 6 ): 1880 - 1888 . http://d.old.wanfangdata.com.cn/Periodical/zgdizhi201306017 http://d.old.wanfangdata.com.cn/Periodical/zgdizhi201306017
Jiang Chengfu , Wang Xiangzeng , Zhang Lixia , et al . Geological characteristics of shale and exploration potential of continental shale gas in 7th member of Yanchang Formation, southeast Ordos Basin [J ] . Geology in China , 2013 , 40 ( 6 ): 1880 - 1888 . http://d.old.wanfangdata.com.cn/Periodical/zgdizhi201306017 http://d.old.wanfangdata.com.cn/Periodical/zgdizhi201306017
刘化清 , 袁剑英 , 李相博 , 等 . 鄂尔多斯盆地延长期湖盆演化及其成因分析 [J ] . 岩性油气藏 , 2007 , 19 ( 1 ): 52 - 56 . DOI: 10.3969/j.issn.1673-8926.2007.01.009 http://doi.org/10.3969/j.issn.1673-8926.2007.01.009
Liu Huaqing , Yuan Jianying , Li Xiangbo . Lake basin evolution of Ordos Basin during Middle-Late Triassic and its origin analysis [J ] . Lithologic Reservoirs , 2007 , 19 ( 1 ): 52 - 56 . DOI: 10.3969/j.issn.1673-8926.2007.01.009 http://doi.org/10.3969/j.issn.1673-8926.2007.01.009
Arango I, Katz B J.Artificially-induced changes to organic matter properties as a consequence of the act of observation[C].AAPG Annual Convention and Exhibition.The Chevron, Houston, Texas, USA: 2017.
Sanei H , Ardakani O H . Alteration of organic matter by ion milling [J ] . International Journal of Coal Geology , 2016 , 163 , 123 - 131 . DOI: 10.1016/j.coal.2016.06.021 http://doi.org/10.1016/j.coal.2016.06.021
Mastalerz M , Schieber J . Effect of ion milling on the perceived maturity of shale samples:Implications for organic petrography and SEM analysis [J ] . International Journal of Coal Geology , 2017 , 183 , 110 - 119 . DOI: 10.1016/j.coal.2017.10.010 http://doi.org/10.1016/j.coal.2017.10.010
Grobe A , Schmatz J , Littke R , et al . Enhanced surface flatness of vitrinite particles by broad ion beam polishing and implications for reflectance measurements [J ] . International Journal of Coal Geology , 2017 , 180 , 113 - 121 . DOI: 10.1016/j.coal.2017.05.006 http://doi.org/10.1016/j.coal.2017.05.006
Hackley P C , Valentine B J , Hatcherian J J . On the petrographic distinction of bituminite from solid bitumen in immature to early mature source rocks [J ] . International Journal of Coal Geology , 2018 , 196 , 232 - 245 . DOI: 10.1016/j.coal.2018.06.004 http://doi.org/10.1016/j.coal.2018.06.004
Valentine B J , Hackley P C , Hatcherian J , et al . Reflectance increase from broad beam ion milling of coals and organic-rich shales due to increased surface flatness [J ] . International Journal of Coal Geology , 2019 , 201 , 86 - 101 . DOI: 10.1016/j.coal.2018.11.004 http://doi.org/10.1016/j.coal.2018.11.004
耳闯 , 赵靖舟 , 白玉彬 , 等 . 鄂尔多斯盆地三叠系延长组富有机质泥页岩储层特征 [J ] . 石油与天然气地质 , 2013 , 34 ( 5 ): 708 - 716 . http://ogg.pepris.com/CN/10.11743/ogg20130519 http://ogg.pepris.com/CN/10.11743/ogg20130519
Er Chuang , Zhao Jingzhou , Bai Yubin , et al . Reservoir characteristics of the organic-rich shales of the Triassic Yanchang Formation in Ordos Basin [J ] . Oil & Gas Geology , 2013 , 34 ( 5 ): 708 - 716 . http://ogg.pepris.com/CN/10.11743/ogg20130519 http://ogg.pepris.com/CN/10.11743/ogg20130519
Landis C R , Castaño J R . Maturation and bulk chemical properties of a suite of solid hydrocarbons [J ] . Organic Geochemistry , 1995 , 22 ( 1 ): 137 - 149 . DOI: 10.1016/0146-6380(95)90013-6 http://doi.org/10.1016/0146-6380(95)90013-6
Loucks R G , Reed R M . Scanning-electron-microscope petrographic evidence for distinguishing organic matter pores associated with depositional organic matter versus migrated organic matter in mudrocks [J ] . GCAGS Transactions , 2014 , 3 , 51 - 60 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=CC0214853297 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=CC0214853297
Bernard S , Horsfield B , Schulz H M , et al . Geochemical evolution of organic-rich shales with increasing maturity:A STXM and TEM study of the Posidonia Shale(Lower Toarcian, northern Germany) [J ] . Marine & Petroleum Geology , 2012 , 31 ( 1 ): 70 - 89 . https://www.sciencedirect.com/science/article/abs/pii/S0264817211001450 https://www.sciencedirect.com/science/article/abs/pii/S0264817211001450
Curiale J A . Origin of solid bitumens, with emphasis on biological marker results [J ] . Organic Geochemistry , 1986 , 10 ( 1 ): 559 - 580 . https://www.sciencedirect.com/science/article/abs/pii/0146638086900549 https://www.sciencedirect.com/science/article/abs/pii/0146638086900549
Hill R J , Tang Y , Kaplan I R . Insights into oil cracking based on laboratory experiments [J ] . Organic Geochemistry , 2003 , 34 ( 12 ): 1651 - 1672 . DOI: 10.1016/S0146-6380(03)00173-6 http://doi.org/10.1016/S0146-6380(03)00173-6
Blanc P . Preservation, degradation, and destruction of trapped oil [J ] . AAPG Memoir , 1994 , 60 , 237 - 247 .
Rogers M A , McAlary J D , Bailey N J L . Significance of reservoir bitumens to thermal-maturation studies, Western Canada Basin [J ] . AAPG Bulletin , 1974 , 58 ( 9 ): 1806 - 1824 .
Larter S , Wilhelms A , Head I , et al . The controls on the composition of biodegraded oils in the deep subsurface-part 1:biodegradation rates in petroleum reservoirs [J ] . Organic Geochemistry , 2003 , 34 ( 4 ): 601 - 613 . DOI: 10.1016/S0146-6380(02)00240-1 http://doi.org/10.1016/S0146-6380(02)00240-1
Larter S , Huang H , Adams J , et al . The controls on the composition of biodegraded oils in the deep subsurface:Part Ⅱ-Geological controls on subsurface biodegradation fluxes and constraints on reservoir-fluid property prediction1 [J ] . AAPG Bulletin , 2006 , 90 ( 6 ): 921 - 938 . DOI: 10.1306/01270605130 http://doi.org/10.1306/01270605130
Milner C W D , Rogers M A , Evans C R . Petroleum transformations in reservoirs [J ] . Journal of Geochemical Exploration , 1977 , 7 , 101 - 153 . DOI: 10.1016/0375-6742(77)90079-6 http://doi.org/10.1016/0375-6742(77)90079-6
卢龙飞 , 蔡进功 , 刘文汇 , 等 . 泥质烃源岩中蒙皂石与有机质的水桥结合作用——来自原位漫反射红外光谱的证据 [J ] . 石油与天然气地质 , 2011 , 32 ( 1 ): 47 - 56 . http://ogg.pepris.com/CN/10.11743/ogg20110106 http://ogg.pepris.com/CN/10.11743/ogg20110106
Lu Longfei , Cai Jingong , Liu Wenhui , et al . Water bridges mechanism of organo-smectite interaction in argillaceous hydrocarbon source rocks:evidences from in situ DRIFT spectroscopic study [J ] . Oil & Gas Geology , 2011 , 32 ( 1 ): 47 - 56 . http://ogg.pepris.com/CN/10.11743/ogg20110106 http://ogg.pepris.com/CN/10.11743/ogg20110106
Liu B , Schieber J , Mastalerz M . Combined SEM and reflected light petrography of organic matter in the New Albany Shale(Devonian-Mississippian)in the Illinois Basin:A perspective on organic pore development with thermal maturation [J ] . International Journal of Coal Geology , 2017 , 184 , 57 - 72 . DOI: 10.1016/j.coal.2017.11.002 http://doi.org/10.1016/j.coal.2017.11.002
相关文章
相关作者
相关机构
京公网安备11010802024621
