原油的红外谱线特征及其地质解译
CHARACTERISTICS OF INFRARED SPECTRUM OF CRUDE OIL AND ITS GEOLOGICAL INTERPRETATION
- 1980年1卷第3期 页码:191-206
网络首发:1980-12-25,
纸质出版:1980
DOI: 10.11743/ogg19800303
移动端阅览
网络首发:1980-12-25,
纸质出版:1980
移动端阅览
作为鉴定有机化合物官能团和研究分子结构强有力手段的红外吸收光谱
已广泛地应用于有机化学各领域中。我国自六十年代以来
已较为普遍地用于研讨生油岩、油源、原油对比、油气运移和原油的后生变化等方面的石油地质问题
积累了丰富的实际资料。笔者初步分析了我国大部分地区原油的红外谱线
发现不同地区、不同层位的原油红外谱线有共性亦有差异。其差异主要受控于原油形成的地质条件与保存环境
故据原油红外谱线特征可阐明某些石油地质问题。
The infrared absorption spectrometer is a powerful tool for detecting functional groups of organic compounds and analysing their molecular struc-tures.Since sixties
this tool has been adopted into areas of petroleum geology and a great quantity of data were achieved.A lot of facts demons-trate that the infrared spectrum of crude oil from various districts or differ-ent horizons exhibits both common and peculiar features
and it indicates some difference in geological settings.The main factors that lead to the above difference in properties of crude oil in China proper are as follows:(1)Source bed which may be of sapropelic or humic type;(2)Sedimentary and oil-generating environment which may have affectedon conservation
trans formation and maturity of organic substances;(3)Epigenetic changes of crude oil which may account for subsequente volution
oxidation
biological and physical processes.Majority of oil fields in China discovered now are concentrated in Mesozoic and Cenozoic continental basins
thus the source beds mostly are of mixed sapropel-humic type.The crude oil generated contains generally more high-molecular paraffin
aromatic and polycyclic naphthenic hydro-carbons and
moreover
was not deeply buried
but well concealed and underwent only a little of epigenetic alteration All these account for the displaying high absorption peaks of its infrared spectrum for high mole-cular paraffin and aromatic hydrocarbons.However
in places where it was deeply buried or the ancient geotherms were higher
it underwent to a cer-tain degree modification and therefore shows an infrared spesctrum oflight crude oil.Depending on geological setting of petroleum productive basins
the crude oil of individual basins may possess different infrared spectrum.In the continent of our country
there are relatively small amountsof oil and gas fields in marine sediments.The source beds generally are of sapropelic type and the crude oil derived there from is represented chiefly by alkanes and naphthenes which have lower molecular weight
but the aromatic hydrocarbon and high-molecular paraffin are rarely cantained.Further more
because of its aging
being deeply buried and extensive modi-fication
it usually has infrared spectrum with a nature of light crude oil which accounts for more intensive absorption peaks for methyl
methy leneand lower molecular alkanes and indistinct absorption peaks for aromatic hydrocarbon and heterocyclic compounds.Local crude oil maintains solidparaffin or has become oxidized heavy oil with entirely different infrared spectrum.
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