Lin Renzi, Li Maowen. GEOCHEMICAL SIGNIFICANCE OF LIGHT HYDROCARBON COMPOSITION IN SOURCE ROCKS OF A TEST WELL[J]. 1985, 6(3): 241-249.DOI: 10.11743/ogg19850303.
是在分散沥青和干酪根聚合物形成与演化的过程中通过热降解或热裂解作用产生的。笔者用气相色谱法研究了取自某盆地一口探井的罐装岩屑样品中的 C
1
—C
7
轻烃组成
对轻烃的各项比值在不同埋藏深度的变化趋势进行了初步探讨。研究结果表明:生油岩中 C
1
—C
7
轻烃的生成及其分布
可能是研究有机质热演化程度的有效标志。
Abstract
C
1
-C
7
light hydrocarbon of 150 canned cutting samples collected from a test well are analysed with capillary GC so as to study the regularity how light hydrocarbon composition varies with buried depth.Light hydrocarbon is mainly methane when rocks yielding it are buriedless than 2
650m;the ratio of(C
2
-C
4
)/(C
1
-C
4
)increases rapidly from less than 30% to 60% when buried depth is about 2
650m;but C
4
-C
7
turn to bethe primary components when buried more than 3
650m.It is obvious that with the increase of buried depth
the content of N-alkana and cycloalkane increases gradully while the iso-alkane decreases.Within the depth of 3
750m
cyclohexane/cyclopentane ratio increases with the increase of the depth
suggesting that cyclohexane is more stable than cy-clopentane in thermo dynamics.But the ratio shows obviously a decrease tendency with the increase of depth
when it is buried bellow 3
750m
this ap-pears to be related to the preferential aromatization of cyclohexane.In accordance with the mass-producing of wet gas
the methyl cyclopentane/cyclopentane and methylcyclohexane/cyclohexane ratios get the maximum values
similar variation is also observed in the dimethyl cyclopentane/cyclo-pentane ratio.The ratio of 1
1-dimethylcyclopentane to isomers of dimethylcyclopentaneis usually less than 0.1 and changes slowly when the buried depth is shal-lower
but increases rapidly to more than 0.3-0.4 when buried greater than 3
300m.It is believed that differential evolution and maturation are probably thegeneral characters in the evolution process of organic matter
and various ra-tio of light hydrocarbons mentioned above may be considered as indices ofmaturity.