Zhou Sandong, Liu Dameng, Cai Yidong, et al. Characterization and fractal nature of adsorption pores in low rank coal[J]. 2018, 39(2): 373-383.DOI: 10.11743/ogg20180216.
We collected 8 kinds of low rank coal (LRC) with distinguished macrolithotypes
carried out some experiments like the low-temperature liquid nitrogen adsorption and isothermal methane adsorption
discussed the LRC adsorption pore characteristics
and established the relationship between fractal model suitable for LRC adsorption pores and fractal dimension with pore structures and adsorption capacities.From this
the LRC absorption/desorption curves are divided into four categories with 4 corresponding pore types:taper-shaped pores with one end closed being dominant in bright coal
open-cylindric pores and wedge-shaped ones occurring in semidull coal
and open-cylindric pores being predominant in dull coal.Results show that (1) compared with the BET model
the FHH model is more appropriate for the characterization of LRC pores in respect of fractal nature;(2) the various macrolithotypes in FHH model show different adsorption characteristics at relative pressure 0~0.5 and 0.5~0.5 and have fractal dimensions D
21
and D
22
respectively
with D
21
representing the surface roughness of adsorption pores and D
22
the irregularity of the pore structures.As D
21
gets bigger
the pore specific surface area increases
whereas the bigger D
22
gets
the smaller the average pore size becomes
the higher the micropore content is
and the larger the pore heterogeneity is;(3) D
21
is more effective than D
22
in controlling the adsorption capacity of LRC.When the coal is characterized by high D
21
and low D
22
the adsorption capacity is the strongest
and the adsorption capacity enlarges as the fractal dimension of cumulative specific surface area increases.The LRC adsorption process subsequently shows transition from predominance of monomolecular layer adsorption to predominance of polymolecular layer adsorption with increasing pressure.