收稿：2019-07-30，
纸质出版：2020-02
移动端阅览
深层-超深层碳酸盐岩是目前油气勘探聚焦的重点领域，其储层的形成和保持机制是制约深层储层预测的关键科学问题。为了明确埋藏溶蚀作用下酸性流体对碳酸盐岩储层物性的影响，有必要开展烃源岩地层孔隙生烃模拟和溶蚀模拟实验（简称生烃及溶蚀模拟实验），定性定量厘清中、深层埋藏环境下烃源岩与碳酸盐岩储层演化过程。采用自主研发设计的生烃模拟实验装置和溶蚀模拟实验装置，以塔里木盆地奥陶系鹰山组灰岩和云南禄劝低成熟烃源岩为实验对象，利用岩相学和地球化学相结合的分析手段，查明中、深埋藏环境下生烃热演化过程中伴生的复杂酸性流体改造碳酸盐岩储层的过程及其控制因素，探索烃源岩生烃过程对碳酸盐岩围岩的改造规律。实验表明：中、深层埋藏环境下烃源岩热演化过程中伴生的有机酸和CO
2
等酸性流体对碳酸盐岩储层产生明显溶蚀作用，扩大原有储集空间并提高孔隙度，并且随着埋藏深度增加，溶蚀作用明显减弱；流体在运移过程中是否能够改善储层物性，由流体中的碳酸钙饱和度、流体流速、水岩比以及原始孔隙结构等因素共同决定。此研究能够为深层-超深层碳酸盐岩优质储层的预测提供一定的理论基础。
The deep and ultra-deep carbonate reservoirs are the major targets of exploration
but their prediction is quite complicated due to the poor understanding of their formation and maintenance mechanism. It is essential to perform hydrocarbon generation and dissolution simulation experiments to quantitatively and qualitatively clarify the evolution process of source rocks and carbonate reservoirs in deep layers. In this study
a series of experiments were conducted with the limestone samples from the Ordovician Yingshan Formation in the Tarim Basin
and the low maturity source rock samples from Luquan County
Yunnan Province
via self-designed hydrocarbon generation and dissolution simulation equipments. The controlling factors accounting for the alteration of carbonate reservoirs and dissolution modification process by the complex acidic fluids associated with hydrocarbon generation in medium-to-deep burial environments were investigated using petrographic and geochemical methods. In the meantime
the transformation mechanism of surrounding carbonate reservoirs during hydrocarbon generation process of source rocks was explored. The results show that: during the medium-deep burial stage
acidic flu
ids including organic acid and CO
2
associated with thermal evolution of source rocks could dissolve carbonate reservoirs
expanding their reservoir space
and thus improving porosity. Dissolution would decrease with the increasing burial depth. Whether the migrating fluids could improve the physical properties of reservoir largely depends on such factors as calcium carbonate saturation
fluid velocity
water/rock ratio
and original pore structure. The study can provide a theoretical basis for prediction of high-quality carbonate reservoirs in deep and ultra-deep formations.
焦方正 . 塔里木盆地顺北特深碳酸盐岩断溶体油气藏发现意义与前景 [J ] . 石油与天然气地质 , 2018 , 39 ( 2 ): 5 - 14 . http://d.old.wanfangdata.com.cn/Periodical/syytrqdz201802001 http://d.old.wanfangdata.com.cn/Periodical/syytrqdz201802001
Jiao Fangzheng . Significance of oil and gas exploration in NE strike-slip fault belts in Shuntuoguole area of Tarim Basin [J ] . Oil&Gas Geology , 2018 , 39 ( 2 ): 5 - 14 . http://d.old.wanfangdata.com.cn/Periodical/syytrqdz201802001 http://d.old.wanfangdata.com.cn/Periodical/syytrqdz201802001
何治亮 , 张军涛 , 丁茜 , 等 . 深层-超深层优质碳酸盐岩储层形成控制因素 [J ] . 石油与天然气地质 , 2017 , 38 ( 4 ): 633 - 644, 763 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=syytrqdz201704001 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=syytrqdz201704001
He Zhiliang , Zhang Juntao , Ding Qian , et al . Factors controlling the formation of high-quality deep to ultra-deep carbonate reservoirs [J ] . Oil&Gas Geology , 2017 , 38 ( 4 ): 633 - 644, 763 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=syytrqdz201704001 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=syytrqdz201704001
Schmoker J W , Halley R B . Carbonate porosity versus depth:A predictable relation for South Florida [J ] . AAPG Bulletin , 1982 , 66 ( 12 ): 2561 - 2570 .
Ehrenberg S N , Nadeau P H . Sandstone versus carbonate petroleum reservoirs:A global perspective on porosity depth and porosity-permeability relationships [J ] . AAPG Bulletin , 2005 , 89 ( 4 ): 435 - 445 .
Ehrenberg S N , Walderhaug O , Bjorlykke . Carbonate porosity cretation by mesogenetic dissolution:Reality or illusion? [J ] . AAPG Bulletin , 2012 , 97 ( 2 ): 345 - 345 . http://d.old.wanfangdata.com.cn/Periodical/nkxb-zxsh200901009 http://d.old.wanfangdata.com.cn/Periodical/nkxb-zxsh200901009
Zhu D Y , Meng Q Q , Jin Z J , et al . Formation mechanism of deep Cambrian dolomite reservoirs in the Tarim basin, northwestern China [J ] . Marine&Petroleum Geology , 2015 , 59 ( 59 ): 232 - 244 .
Hao F , Zhang X , Wang C , et al . The fate of CO 2 derived from thermochemical sulfate reduction (TSR) and effect of TSR on carbonate porosity and permeability, Sichuan Basin, China [J ] . Earth-Science Reviews , 2015 , 141 , 154 - 177 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=23fff16c3e5c9996f8e38751c375fc96 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=23fff16c3e5c9996f8e38751c375fc96
朱光有 , 张水昌 , 梁英波 , 等 . TSR对深部碳酸盐岩储层的溶蚀改造——四川盆地深部碳酸盐岩优质储层形成的重要方式 [J ] . 岩石学报 , 2006 , 22 ( 8 ): 2182 - 2194 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ysxb98200608008 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ysxb98200608008
Zhu Guangyou , Zhang Shuichang , Liang Yingbo , et al . Dissolution and alteration of the deep carbonate reservoir by TSR:An important type of deep-burial high-quality carbonate reservoirs in Sichuan Basin [J ] . Acta Petrologica Sinica , 2006 , 22 ( 8 ): 2182 - 2194 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ysxb98200608008 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ysxb98200608008
朱东亚 , 金之钧 , 胡文瑄 , 等 . 塔里木盆地深部流体对碳酸盐岩储层影响 [J ] . 地质论评 , 2008 , 54 ( 3 ): 348 - 354 . http://d.old.wanfangdata.com.cn/Periodical/dzlp200803008 http://d.old.wanfangdata.com.cn/Periodical/dzlp200803008
Zhu Dongya , Jin Zhijin , Hu Wenxuan , et al . Effects of deep fluid on carbonate reservoir in Tarim Basin [J ] . Geological Review , 2008 , 54 ( 3 ): 348 - 354 . http://d.old.wanfangdata.com.cn/Periodical/dzlp200803008 http://d.old.wanfangdata.com.cn/Periodical/dzlp200803008
朱东亚 , 张殿伟 , 张荣强 , 等 . 中国南方地区灯影组白云岩储层流体溶蚀改造机制 [J ] . 石油学报 , 2015 , 36 ( 10 ): 1188 - 1198 . http://d.old.wanfangdata.com.cn/Periodical/syxb201510002 http://d.old.wanfangdata.com.cn/Periodical/syxb201510002
Zhu Dongya , Zhang Dianwei , Zhang Rongqiang , et al . Fluid alteration mechanism of dolomite reservoirs in Dengying Formation, South China [J ] . Acta Petrolei Sinica , 2015 , 36 ( 10 ): 1188 - 1198 . http://d.old.wanfangdata.com.cn/Periodical/syxb201510002 http://d.old.wanfangdata.com.cn/Periodical/syxb201510002
Zhu D , Meng Q , Jin Z , et al . Fluid environment for preservation of pore spaces in a deep dolomite reservoir [J ] . Geofluids , 2014 , 15 ( 4 ): 527 - 545 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=10.1111/gfl.12123 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=10.1111/gfl.12123
Jia L , Cai C , Yang H , et al . Thermochemical and bacterial sulfate reduction in the Cambrian and Lower Ordovician carbonates in the Tazhong Area, Tarim Basin, NW China:Evidence from fluid inclusions, C, S and Sr isotopic data [J ] . Geofluids , 2015 , 15 ( 3 ): 421 - 437 .
Jiang L , Worden R H , Yang C . Thermochemical sulphate reduction can improve carbonate petroleum reservoir quality [J ] . Geochimica et Cosmochimica Acta , 2018 , 223 , 127 - 140 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=a4af4218f3c378e6ec4603ad5f5bf6bf http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=a4af4218f3c378e6ec4603ad5f5bf6bf
尤东华 , 王亮 , 胡文瑄 , 等 . 从成岩-蚀变特征探讨塔深1井白云岩储层成因 [J ] . 岩石矿物学杂志 , 2018 , 37 ( 1 ): 34 - 46 . http://d.old.wanfangdata.com.cn/Periodical/yskwxzz201801004 http://d.old.wanfangdata.com.cn/Periodical/yskwxzz201801004
You Donghua , Wang Liang , Hu Wenxuan , et al . Formation of deep dolomite reservoir of Well TS1:Insights from diagenesis and alteration investigations [J ] . Acta Petrologica et Mineralogica , 2018 , 37 ( 1 ): 34 - 46 . http://d.old.wanfangdata.com.cn/Periodical/yskwxzz201801004 http://d.old.wanfangdata.com.cn/Periodical/yskwxzz201801004
Lu Z , Chen H , Qing H , et al . Petrography, fluid inclusion and isotope studies in Ordovician carbonate reservoirs in the Shunnan area, Tarim basin, NW China:Implications for the nature and timing of silicification [J ] . Sedimentary Geology , 2017 , 359 , 29 - 43 .
李映涛 , 叶宁 , 袁晓宇 , 等 . 塔里木盆地顺南4井中硅化热液的地质与地球化学特征 [J ] . 石油与天然气地质 , 2015 , 36 ( 6 ): 934 - 944 . http://d.old.wanfangdata.com.cn/Periodical/syytrqdz201506008 http://d.old.wanfangdata.com.cn/Periodical/syytrqdz201506008
Li Yingtao , Ye Ning , Yuan Xiaoyu , et al . Geological and geochemical characteristics of silicified hydrothermal fluids in Well Shunnan 4, Tarim Basin [J ] . Oil&Gas Geology , 2015 , 36 ( 6 ): 934 - 944 . http://d.old.wanfangdata.com.cn/Periodical/syytrqdz201506008 http://d.old.wanfangdata.com.cn/Periodical/syytrqdz201506008
范明 , 胡凯 , 蒋小琼 , 等 . 酸性流体对碳酸盐岩储层的改造作用 [J ] . 地球化学 , 2009 , 38 ( 1 ): 20 - 26 . http://d.old.wanfangdata.com.cn/Periodical/dqhx200901002 http://d.old.wanfangdata.com.cn/Periodical/dqhx200901002
Fan Ming , Hu Kai , Jiang Xiaoqiong , et al . Effect of acid fluid on carbonate reservoir reconstruction [J ] . Geochimica , 2009 , 38 ( 1 ): 20 - 26 . http://d.old.wanfangdata.com.cn/Periodical/dqhx200901002 http://d.old.wanfangdata.com.cn/Periodical/dqhx200901002
鲜强 , 冯许魁 , 刘永雷 , 等 . 塔中地区碳酸盐岩缝洞型储层叠前流体识别 [J ] . 石油与天然气 , 2019 , 40 ( 1 ): 196 - 204 . http://d.old.wanfangdata.com.cn/Periodical/syytrqdz201901020 http://d.old.wanfangdata.com.cn/Periodical/syytrqdz201901020
Xian Qiang , Feng Xukui , Liu Yonglei , et al . Pre-stack fluid identification for fractured-vuggy carbonate reservoir in Tazhong area [J ] . Oil&Gas Geology , 2019 , 40 ( 1 ): 196 - 204 . http://d.old.wanfangdata.com.cn/Periodical/syytrqdz201901020 http://d.old.wanfangdata.com.cn/Periodical/syytrqdz201901020
贾晓静 , 柯光明 , 徐守成 , 等 . 超深层复杂碳酸盐岩滩相储层发育特征 [J ] . 石油地质与工程 , 2019 , 33 ( 5 ): 5 - 10 . http://d.old.wanfangdata.com.cn/Periodical/hnsy201905003 http://d.old.wanfangdata.com.cn/Periodical/hnsy201905003
Jia Xiaojing , Ke Guangming , Xu Shoucheng , et al . Development characteristics of ultra-deep complex carbonste shoal facies reservoirs [J ] . Petroleum Geology and Engineering , 2019 , 33 ( 5 ): 5 - 10 . http://d.old.wanfangdata.com.cn/Periodical/hnsy201905003 http://d.old.wanfangdata.com.cn/Periodical/hnsy201905003
寿建峰 , 佘敏 , 沈安江 . 深层条件下碳酸盐岩溶蚀改造效应的模拟实验研究 [J ] . 矿物岩石地球化学通报 , 2016 , 35 ( 5 ): 860 - 867 . http://d.old.wanfangdata.com.cn/Periodical/kwysdqhxtb201605012 http://d.old.wanfangdata.com.cn/Periodical/kwysdqhxtb201605012
Shou Jianfeng , She Min , Shen Anjiang . Experimental simulation of dissolution effect of carbonate rock under deep burial condition [J ] . Bulletion of Mineralogy, Petrology and Geochemistry , 2016 , 35 ( 5 ): 860 - 867 . http://d.old.wanfangdata.com.cn/Periodical/kwysdqhxtb201605012 http://d.old.wanfangdata.com.cn/Periodical/kwysdqhxtb201605012
丁茜 , 何治亮 , 沃玉进 , 等 . 高温高压条件下碳酸盐岩溶蚀过程控制因素 [J ] . 石油与天然气地质 , 2017 , 38 ( 4 ): 784 - 791 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=syytrqdz201704015 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=syytrqdz201704015
Ding Qian , He Zhiliang , Wo Yujin , et al . Factors controlling carbonate rock dissolution under high temperature and pressure [J ] . Oil&Gas Geology , 2017 , 38 ( 4 ): 784 - 791 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=syytrqdz201704015 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=syytrqdz201704015
He Z L , Ding Q , Wo Y J , et al . Experiment of carbonate dissolution:Implication for high quality carbonate reservoir formation in deep and ultradeep basins [J ] . Geofluids , 2017 , 8439259 , 1 - 8 .
彭军 , 王雪龙 , 韩浩东 , 等 . 塔里木盆地寒武系碳酸盐岩溶蚀作用机理模拟实验 [J ] . 石油勘探与开发 , 2018 , 45 ( 3 ): 415 - 425 . http://d.old.wanfangdata.com.cn/Periodical/syktykf201803006 http://d.old.wanfangdata.com.cn/Periodical/syktykf201803006
Peng Jun , Wang Xuelong , Han Haodong , et al . Simulation for the dissolution mechanism of Cambrian carbonate rocks in Tarim Basin, NW China [J ] . Petroleum Exploration and Development , 2018 , 45 ( 3 ): 415 - 425 . http://d.old.wanfangdata.com.cn/Periodical/syktykf201803006 http://d.old.wanfangdata.com.cn/Periodical/syktykf201803006
范明 , 蒋小琼 , 刘伟新 , 等 . 不同温度条件下CO 2 水溶液对碳酸盐岩的溶蚀作用 [J ] . 沉积学报 , 2007 , 25 ( 6 ): 825 - 830 . http://d.old.wanfangdata.com.cn/Periodical/cjxb200706002 http://d.old.wanfangdata.com.cn/Periodical/cjxb200706002
Fan Ming , Jiang Xiaoqiong , Liu Weixin , et al . Dissolution of carbonate rocks in CO 2 solution under the different temperature [J ] . Acta Sedimentologica Sinica , 2007 , 25 ( 6 ): 825 - 830 . http://d.old.wanfangdata.com.cn/Periodical/cjxb200706002 http://d.old.wanfangdata.com.cn/Periodical/cjxb200706002
Pokrovsky O S , Golubev S V , Schott J , et al . Calcite, dolomite and magnesite dissolution kinetics in aqueous solutions at acid to circumneutral pH, 25 to 150℃ and 1 to 55atm p CO2 :New constraints on CO 2 , sequestration in sedimentary basins [J ] . Chemical Geology , 2009 , 265 ( 1-2 ): 20 - 32 .
Elkhoury J E , Ameli P , Detwiler R L . Dissolution and deformation in fractured carbonates caused by flow of CO 2 -rich brine under reservoir conditions [J ] . International Journal of Greenhouse Gas Control , 2013 , 16 ( Si ): 203 - 215 .
杨云坤 , 刘波 , 秦善 , 等 . 基于模拟实验的原位观察对碳酸盐岩深部溶蚀的再认识 [J ] . 北京大学学报(自然科学版) , 2014 , 50 ( 2 ): 316 - 322 . http://d.old.wanfangdata.com.cn/Periodical/bjdxxb201402015 http://d.old.wanfangdata.com.cn/Periodical/bjdxxb201402015
Yang Yunkun , Liu Bo , Qin Shan , et al . Re-recognition of deep carbonate dissolution based on the observation of in-situ simulation experiment [J ] . Acta Scientiarum Naturalium Universitatis Pekinensis , 2014 , 50 ( 2 ): 316 - 322 . http://d.old.wanfangdata.com.cn/Periodical/bjdxxb201402015 http://d.old.wanfangdata.com.cn/Periodical/bjdxxb201402015
Garcia-Rios M , Luquot L , Soler J M , et al . Influence of the flow rate on dissolution and precipitation features during percolation of CO 2 -rich sulfate solutions through fractured limestone samples [J ] . Chemical Geology , 2015 , 414 , 95 - 108 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=6f167e3991bab786f372c5b580c2e914 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=6f167e3991bab786f372c5b580c2e914
赫俊民,王小圭,孙建芳,等.塔里木盆地塔河地区中-下奥陶统碳酸盐岩储层天然裂缝发育特征及主控因素[J].石油与天然气地质, 2019, 40(5): 1022-1030.
Hao Junmin, Wang Xiao Jianfang, et al.Characteristics and maincontrolling factors of natural frcatures in the Lower-to-Middle Ordovician carbonate ressrvoirs in Tahearea, northern Tarim Basin[J]. Oil&Geology, 2019, 40(5): 1022-1030.
胡明毅 , 蔡习尧 , 胡忠贵 , 等 . 塔中地区奥陶系碳酸盐岩深部埋藏溶蚀作用研究 [J ] . 石油天然气学报 , 2009 , 31 ( 6 ): 49 - 54 . http://d.old.wanfangdata.com.cn/Periodical/jhsyxyxb200906008 http://d.old.wanfangdata.com.cn/Periodical/jhsyxyxb200906008
Hu Mingyi , Cai Xirao , Hu Zhonggui , et al . Deep buried dissolution of Ordovician carbonates in Tazhong area of Tarim Basin [J ] . Journal of Oil and Gas Technology , 2009 , 31 ( 6 ): 49 - 54 . http://d.old.wanfangdata.com.cn/Periodical/jhsyxyxb200906008 http://d.old.wanfangdata.com.cn/Periodical/jhsyxyxb200906008
佘敏 , 寿建峰 , 贺训云 , 等 . 碳酸盐岩溶蚀机制的实验探讨:表面溶蚀与内部溶蚀对比 [J ] . 海相油气地质 , 2013 , 18 ( 3 ): 55 - 61 . http://d.old.wanfangdata.com.cn/Periodical/hxyqdz201303007 http://d.old.wanfangdata.com.cn/Periodical/hxyqdz201303007
She Min , Shou Jianfeng , He Xunyun , et al . Experiment of dissolution mechanism of carbonate rocks:Surface dissolution and internal dissolution [J ] . Marine Origin Petroleum Geology , 2013 , 18 ( 3 ): 55 - 61 . http://d.old.wanfangdata.com.cn/Periodical/hxyqdz201303007 http://d.old.wanfangdata.com.cn/Periodical/hxyqdz201303007
倪斌 , 汤良杰 , 郭颖 , 等 . 塔里木盆地玉北地区埋藏史及热史分析 [J ] . 现代地质 , 2017 , 31 ( 2 ): 151 - 160 . http://d.old.wanfangdata.com.cn/Periodical/xddz201702014 http://d.old.wanfangdata.com.cn/Periodical/xddz201702014
Ni Bin , Tang Liangjie , Guo Ying , et al . Analysis of burial history and thermal history in Yubei area, Tarim Basin [J ] . Geoscience , 2017 , 31 ( 2 ): 151 - 160 . http://d.old.wanfangdata.com.cn/Periodical/xddz201702014 http://d.old.wanfangdata.com.cn/Periodical/xddz201702014
郑剑锋 , 沈安江 , 黄理力 , 等 . 基于埋藏溶蚀模拟实验的白云岩储层孔隙效应研究——以塔里木盆地下寒武统肖尔布拉克组为例 [J ] . 石油实验地质 , 2017 , 39 ( 5 ): 716 - 723 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=sysydz201705020 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=sysydz201705020
Zheng Jianfeng , Shen Anjiang , Huang Lili , et al . Pore effect of dolomite reservoirs based on burial dissolution simulation:A case study of the Lower Cambrian Xiaoerbulake Formation in the Tarim Basin [J ] . Petroleum Geology and Experiment , 2017 , 39 ( 5 ): 716 - 723 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=sysydz201705020 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=sysydz201705020
何治亮 , 魏修成 , 钱一雄 , 等 . 海相碳酸盐岩优质储层形成机理与分布预测 [J ] . 石油与天然气地质 , 2011 , 32 ( 4 ): 489 - 498 . http://d.old.wanfangdata.com.cn/Periodical/syytrqdz201104001 http://d.old.wanfangdata.com.cn/Periodical/syytrqdz201104001
He Zhiliang , Wei Xiucheng , Qian Yixiong , et al . Forming mechanism and distribution prediction of quality marine carbonate reservoirs [J ] . Oil&Gas Geology , 2011 , 32 ( 4 ): 489 - 498 . http://d.old.wanfangdata.com.cn/Periodical/syytrqdz201104001 http://d.old.wanfangdata.com.cn/Periodical/syytrqdz201104001
马永生 , 蔡勋育 , 赵培荣 , 等 . 深层超深层碳酸盐岩优质储层发育机理和"三元控储"模式——以四川普光气田为例 [J ] . 地质学报 , 2010 , 84 ( 8 ): 1087 - 1094 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dizhixb201008001 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dizhixb201008001
Ma Yongsheng , Cai Xunyu , Zhao Peirong , et al . Formation mechanism of deep buried carbonate reservoir and its model of three element controlling reservoir:A case study from the Puguang oil field in Sichuan [J ] . Acta Geologica Sinica , 2010 , 84 ( 8 ): 1087 - 1094 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dizhixb201008001 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dizhixb201008001
Choquette P W , James N P . Diagenesis in limestones-(3).The deep burial environment [J ] . Geoscience , 1987 , 14 ( 3 ): 30 - 35 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=8fea325a3072df9ef0fc35c9297a3347 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=8fea325a3072df9ef0fc35c9297a3347
Zeebe R E , Wolf-G D . CO 2 in seawater:Equilibrium, kinetics, isotopes [M ] . Amsterdam : Elsevier , 2001 .
佘敏 , 寿建峰 , 沈安江 , 等 . 碳酸盐岩溶蚀规律与孔隙演化实验研究 [J ] . 石油勘探与开发 , 2016 , 43 ( 4 ): 564 - 572 . http://d.old.wanfangdata.com.cn/Periodical/syktykf201604008 http://d.old.wanfangdata.com.cn/Periodical/syktykf201604008
She Min , Shou Jianfeng , Shen Anjiang , et al . Experimental simulation of dissolution law and porosity evolution of carbonate rock [J ] . Petroleum Exploration and Development , 2016 , 43 ( 4 ): 564 - 572 . http://d.old.wanfangdata.com.cn/Periodical/syktykf201604008 http://d.old.wanfangdata.com.cn/Periodical/syktykf201604008
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