收稿：2018-06-27，
纸质出版：2020-12-28
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四川盆地川东地区是中国页岩气主要产区，目前发现的页岩气主要产自五峰-龙马溪组的富泥硅质页岩，而对富硅泥质和混合质页岩研究较少。为了确定川东地区龙马溪组富硅泥质和混合质页岩的孔隙发育特征，在对龙马溪组页岩岩相划分的基础之上，通过二氧化碳吸附，氮气吸附，高压压汞以及孔隙度测定，X-衍射，场发射扫描电子显微镜（FE-SEM）等实验手段，对比不同岩相页岩孔隙结构特征，研究不同岩相页岩孔隙结构的主控因素。研究结果表明：①川东地区富有机质页岩可划分为富硅泥质页岩相、硅/泥混合页岩相和富泥硅质页岩相，不同岩相页岩孔隙度范围在2.62%~5.65%；②页岩储层中孔隙体积以介孔为主，大约占总孔隙的50%~60%，其次是微孔和宏孔，大约占总孔隙的15%~20%，比表面积主要贡献来自微孔和介孔，分别占总比表面积的70%和30%；③龙马溪组页岩孔隙发育主要受有机质丰度的控制，粘土矿物含量不是控制页岩孔隙发育主要因素，高有机质丰度页岩可能由于骨架颗粒支撑较弱遭受更剧烈的压实作用使大部分孔隙消失；④高有机质丰度富泥质页岩和硅/泥混合页岩也具有较高的孔隙度，与大部分富泥硅质页岩具有相似的孔隙结构，表明富硅泥质页岩相和硅/泥混合页岩相页岩也能发育一定量的纳米级孔隙，可为页岩气赋存提供空间。
The eastern Sichuan Basin is one of the major shale gas producing areas in China.However
with gas being mostly found in the clay-rich siliceous shale
the silica-rich argillaceous and mixed argillaceous/siliceous shal
es in the Wufeng-Longmaxi formation have been largely neglected.This study focuses on pore structure features of the shales by comparing the structural features of diverse lithofacies and investigating their main controlling factors based on the lithofacies classification of the shale samples from the Longmaxi Formation by means of low pressure N
2
/CO
2
gas adsorption
high pressure mercury intrusion
porosity measurement
XRD analyses
FE-SEM and so on.The results show that the organic-rich shales in the eastern Sichuan Basin can be divided to silica-rich argillaceous
mixed argillaceous/siliceous and clay-rich siliceous lithofacies with a porosity ranging from 2.62% to 5.65%.Pore volume of the shale reservoirs is primarily contributed by mesopores
accounting for 50% to 60% of the total
followed by micropores and macropores
accounting for 15% to 20% of the total; while the total specific surface area is mainly contributed by micropores and mesopores
accounting for 70% and 30% of total respectively.The pore development is chiefly controlled by the abundance of organic matters instead of the clay mineral content.Shale with high abundance of organic matters may contain less pores as it could not withstand intense compaction with its soft matrix.The organic-rich shale of silica-rich argillaceous and mixed argillaceous/siliceous lithofacies is high in porosity and shares the similar pore structure with most of the clay-rich siliceous shale
suggesting that the silica-rich argillaceous and mixed argillaceous/siliceous shales can also generate certain amount of nano-scaled pores for shale gas storage.
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