Li Zhenguang, Feng Zihui, Song Guixia, et al. Distribution and composition of aromatic hydrocarbons and classification of oil in Songliao basin[J]. 2005, 26(4): 494-500.DOI: 10.11743/ogg20050416.
Through gas chromatographic-mass spectrometric(GC-MS) analyses
11 series and 164 aromatic hydrocarbons
including naphthalene
phenanthrene
chrysene
biphenyl
fluorene
dibenzofuran
dibenzothiophene
triaromatic steroid
etc.
have been detected in oil sampled from Heidimiao
Saertu
Putaohua
Gaotaizi and Fuyu oil layers in Songliao Basin.Crude oil in Heidimiao and Saertu layers are mainly composed of triaromatic sterides and compounds of phenanthrene family.Crude oil in Putaohua layer are mainly composed of compounds of phenanthrene and chrysene families.Crude oil in Gaotaizi and Fuyu layers are mainly composed of compounds of phenanthrene and chrysene families and triaromatic sterides.All the break-points in vertical distributions of compounds of phenanthrene and chrysene families and triaromatic sterides appear at Putaohua layer
i.e.from the shallower Heidimiao layer to the deeper Fuyu layer
the contents of phenanthrene and chrysene families are tending to increase
while that of triaromatic sterides are tending to decrease.According to the content of triaromatic steroid and the combination of triaromatic sterides/phenanthrene family and dimethylphenanthrene/triaromatic steroid
crude oil in Songliao basin can be divided into three types
including the high triaromatic sterides crude oil in Heidimiao and Saertu layers
the low triaromatic sterides crude oil in Gaotaizi and Fuyu layers and trace triaromatic sterides crude oil in Putaohua layer.Based on crude oil in Songliao basin containing triaromatic sterides and the dibenzothiophene/phenanthrene being very low
it is believed that the source rocks in Songliao basin would have been deposited in weak oxidizing environment in freshwater-brackish lake.