泥质烃源岩的比表面与有机质关系研究进展及意义

doi:10.11743/ogg20120306

Abstract

Abstract:

The enrichment of organic matter in source rocks is a topic of concern and studying the relation between organic matter and specific surface is important to recognizing the enrichment mechanism of organic matter.Specific surface area of argillaceous source rocks is complex in components and is controlled by various factors such as pore size,components,mineral constituents,inner surface and external surface of clay minerals.Each measuring method for specific surface area has its own limitations.For example,mercury porosimetry is suitable for measuring mesopores and macropores,nitrogen adsorption method is the best in measuring micropores and external surface,and EGME method is fit for measuring micropores and inner surface.Therefore,it is crucial to choose the right method to detect the specific surface area of argillaceous source rocks.The occurrence modes are different for different organic matters,especially the soluble organic matter,which is absorbed on the external surface of minerals by physical adsorption,or enters into the inner surface of minerals via chemical adsorption.All of these result in the variations and differences of the correlation between organic matter and specific surface.Consequently,in addition to the features of minerals and organic matter's occurrence,it should be paid attention to find the suitable method to determine the specific surface area in argillaceous source rocks.

Key words: specific surface area, detection method, enrichment of organic matter, argillaceous source rock

CLC Number:

TE135

Zhu Xiaojun, Cai Jingong. Progress and significance of research on relation between specific surface area and organic matter in argillaceous source rocks[J]. Oil & Gas Geology, 2012, 33(3): 375-384.

References

[1] 关平,徐永昌,刘文汇.烃源岩有机质的不同赋存状态及定量估算[J].科学通报,1998,43(14):1556-1559. Guan Ping,Xu Yongchang,Liu Wenhui.Diverse occurrence and quantitative evaluation of organic matter in petroleum source rocks[J].Science Bulletin,1998,43(14):1556-1559.
[2] 樊馥.泥质烃源岩不同赋存态有机质的结构及生烃特征研究.上海:同济大学,2011. Fan Fu.Study on structure and generating hydrocarbon of organic matter with different preservation mechanisms in muddy source rock.Shanghai:Tongji University,2011.
[3] 蔡进功,卢龙飞,宋明水,等.有机粘土复合体抽提特征及其石油地质意义[J].石油与天然气地质,2010,31(3):300-308. Cai Jingong,Lu Longfei,Song Mingshui,et al.Characteristics of extraction of organo clay complexes and their significance to petroleum geology[J].Oil & Gas Geology,2010,31(3):300-308.
[4] Weiler R R,Mills A A.Surface properties and pore structure of marine sediments[J].Deep-Sea Research,1965,12:511-529.
[5] Suess E.Interaction of organic compounds with calcium carbona-te-Ⅱ:organo-carbonate association in recent sediments[J].Geochimica et Cosmochimca Acta,1973,37:2435-2447.
[6] Tanoue E,Handa N.Differential sorption of organic matter by various sized sediment particules in recent sediment from the Bering Sea[J].Journal of the Oceanographic Society of Japan,1979,35:199-208.
[7] Mayer L M.Relationships between mineral surfaces and organic carbon concentrations in soils and sediments[J].Chemical Geo-logy,1994,114:347-363.
[8] Van Olphen H.粘土胶体化学导论[M].许冀泉,译.北京:农业出版社,1982:81-87. Van Olphen H.Clay colloid chemistry introduction[M].Translate by Xu Jiquan.Beijing:Agriculture Press,1982:81-87.
[9] 蔡进功.泥质沉积物和泥岩中有机黏土复合体[M].北京:中国科学出版社,2004:53-144. Cai Jingong.Organo-clay complexes in muddy sediments and rocks[M].Beijing:Science Press,2004:53-144.
[10] 张永刚,蔡进功,许卫平,等.泥质烃源岩中有机质富集机制[M].北京:石油工业出版社,2007:26-108. Zhang Yonggang,Cai Jingong,Xu Weiping,et al.The organic matter enrichment mechanism in argillaceous source rocks[M].Beijing:Petroleum Industry Press House,2007:26-108.
[11] 卢龙飞,蔡进功,刘文汇,等.泥质烃源岩中蒙皂石与有机质的水桥结合作用-来自原位漫反射红外光谱的证据[J].石油与天然气地质,2011,32(1):47-55. Lu Longfei,Cai Jingong,Liu Wenhui,et al.Water bridges mechanism of organo-smectite interaction in argillaceous hydrocarbon source rocks:evidences from in situ DRIFT spectroscopic study[J].Oil & Gas Geology,2011,32(1):47-55.
[12] 罗兴树,杨坤鹏,崔茂荣.泥页岩比表面积测定方法实验研究[J].西南石油学院学报,1997,19(3):49-53. Luo Xingshu,Yang Kunpeng,Cui Maorong.The determining method experiment researching of specific surface area for mud shale[J].Journal of Southwest Petroleum Institute,1997,19(3):49-53.
[13] 马毅杰.测定土壤比表面的乙二醇乙醚吸附法[J].土壤,1981,3:105-107. Ma Yijie.The EGME method for determining specific surface area of soils[J].Soils,1981,3:105-107.
[14] 李凤生.超细粉体技术[M].北京:国防工业出版社,2000:339-341. Li Fengsheng.Super fine powder technology[M].Beijing:National Defence Industry Press,2000:339-341.
[15] Gregg S J,Sing K S W.Adsorption,Surface area and porosity(2^nd)[M].London:Academic Press,1982.
[16] 魏芸,李忠全,汪俊琴,等.GB/T 19587-2004气体吸附BET法测定固态物质比表面积[S].北京:中国标准出版社,2004:1-10. Wei Yun,Li Zhongquan,Wang Junqin,et al.GB/T 19587-2004 Determination of the specific surface area of solids by gas adsorption using the BET method[S].Beijing:Standards Press of China,2004:1-10.
[17] 辛勤,罗孟飞.现代催化研究方法[M].北京:科学出版社,2009:1-194. Xin Qin,Luo Mengfei.Modern catalytic research methods[M].Beijing:Science Press,2009:1-194.
[18] Philip H,Nelson.Pore-throat sizes in sandstones,tight sandstones,and shales[J].AAPG Bulletin,2009,93(3):329-340.
[19] Miyawaki J,Kanda T,Suzuki T,et al.Macroscopic evidence of enhanced formation of methane nanohydrates in hydrophobic nanospaces[J].The Journal of Physical Chemistry B,1998,102(12):2187-2192.
[20] Rouquerol F,Rouquerol J,Sing K.Adsorption by powder and porous solids[M].London:Academic Press,1999:10-45.
[21] 张晓东,秦勇,桑树勋.煤储层吸附特征研究现状及展望[J].中国煤田地质,2005,17(1):16-22. Zhang Xiaodong,Qin Yong,Sang Shuxun.Status quo and prospect of studies on CBM reservoir adsorptive characteristics[J].Coal Geology of China,2005,17(1):16-22.
[22] 霍多特 B B.煤与瓦斯突出[M].宋世钊,译.北京:中国工业出版社,1966:18-69. Ходот B B.Coal and gas outburst[M].Translate by Song Shizhao,Beijing:China Industry Press,1966:18-69.
[23] 钟玲文,张慧,员争荣,等.煤的比表面积孔体积及其对煤吸附能力的影响[J].煤田地质与勘探,2002,30(3):26-28. Zhong Lingwen,Zhang Hui,Yuan Zhengrong,et al.Influence of specific pore area and pore volume of coal on adsorption capacity[J].Coal Geology & Exploration,2002,30(3):26-28.
[24] 马毅杰.粘土矿物和有机质对土壤胶体比表面的影响[J].土壤学报,1988,25(4):374-378. Ma Yijie.The influence of clay minerals and organic matter on specific surface area of soil colloids[J].Acta Pedologica Sinica,1988,25(4):374-378.
[25] 张林晔,李政,朱日房.页岩气的形成与开发[J].天然气工业,2009,29(1):124-128. Zhang Linye,Li Zheng,Zhu Rifang.The formation and exploitation of shale gas[J].Natural Gas Industry,2009,29(1):124-128.
[26] Bergamaschi B A,Tsamakis E,Keil R G,et al.The effect of grain size and surface area on organic matter,lignin and carbohydrate concentration and molecular compositions in Peru Margin sediments[J].Geochimica et Cosmochimica Acta,1997,716:1247-1260.
[27] 田永东,李宁.煤对甲烷吸附能力的影响因素[J].西安科技大学学报,2007,27(2):247-250. Tian Yongdong,Li Ning.Affecting factors of the coal adsorbing methane capacity[J].Journal of Xi’an University of Science and Technology,2007,27(2):247-250.
[28] 司华,黄升谋.硼吸附对针铁矿表面性质的影响[J].安徽农业科学,2007,35(5):1569-1570. Si Hua,Huang Shengmou.Effect of boron adsorption on surface electrochemical properties of goethite[J].Journal of Anhui Agriculture Science.2007,35(5):1569-1570.
[29] 梁健伟,房营光,谷任国.极细颗粒黏土的比表面积测试与分析[J].科学技术与工程,2009,9(9):2371-2377. Liang Jianwei,Fang Yingguang,Gu Renguo.Experiment and analysis of specific surface area of tiny-particle clay[J].Science Technology and Engineering,2009,9(9):2371-2377.
[30] 路长春,陆现彩,刘显东,等.基于探针气体吸附等温线的矿物岩石表征技术Ⅳ:比表面积的测定和应用[J].矿物岩石地球化学通报,2008,27(1):28-34. Lu Changchun,Lu Xiancai,Liu Xiandong,et al.The technique of surface characteristics of mineral material based on probe gas adsorption isotherm Ⅳ:measurement and application of specific surface area[J].Bulletin of Mineralogy,petrology and Geochemistry,2008,27(1):28-34.
[31] 陆现彩,尹琳,赵连泽,等.常见层状硅酸盐矿物的表面特征[J].硅酸盐学报,2003,31(1):59-65. Lu Xiancai,Yin Lin,Zhao Lianze,et al.Surface characteristics of general phyllosilicate minerals[J].Journal of the Chinese Ceramic Society,2003,31(1):59-65.
[32] 王祥,刘玉华,张敏,等.页岩气形成条件及成藏影响因素研究[J].天然气地球科学,2010,21(2):350-356. Wang Xiang,Liu Yuhua,Zhang Min,et al.Conditions of formation and accumulation for shale gas[J].Natural Gas Geoscience,2010,21(2):350-356.
[33] Oladipo E O,Randy J M.High surface areas caused by smectitic interstratification of kaolinite and illite in Athabasca oil sands[J].Applied Clay Science,2004,25:37-47.
[34] Kennedy M J,Pevear D R,Hill R J.Mineral surface control of organic carbon in black shale[J].Science,2002,295(25):657-660.
[35] 田英姿,陈克用.用压汞法和氮吸附法测定孔径分布及比表面积[J].中国造纸,2004,23(4):21-23. Tian Yingzi,Chen Keyong.Determination of pore size distribution and surface area of several materials using mercury porosimetry and gas adsorption[J].China Pulp & Paper,2004,23(4):21-23.
[36] 巨文军,申丽红,郭丹丹.氮气吸附法和压汞法测定Al2O3载体孔结构[J].广东化工,2009,36(8):213-214. Ju Wenjun,Shen Lihong,Guo Dandan.Nitrogen adsorption method and mercury injection method determination the pore structure of alumina carrier[J].Guangdong cheuical Industriy,2009,36(8):213-214.
[37] 周素红,邹涛,朱庆山,等.GB/T 21650.1-2008压汞法和气体吸附法测定固体材料孔径分布和孔隙度_第1部分:压汞法[S].北京:中国标准出版社,2008:1-14. Zhou Suhong,Zou Tao,Zhu Qingshan,et al.GB/T 21650.1-2008.Pore size distribution and porosity of solid materials by mercury porosimetry and gas adsorption-Part1:Mercury porosimetry[S].Beijing:Standards Press of China,2008:1-14.
[38] 谢晓永,唐洪明,王春华,等.氮气吸附法和压汞法在测试泥页岩孔径分布中的对比[J].天然气工业,2006,26(12):100-102. Xie Xiaoyong,Tang Hongming,Wang Chunhua,et al.Contrast of nitrogen adsorption method and mercury porosimetry method in analysis of shale’s pore size distribution[J].Natural Gas Industry,2006,26(12):100-102.
[39] 赵振国.吸附作用应用原理[M].北京:化学工业出版社,2005:458-486. Zhao Zhenguo.Application principle of adsorption effect[M].Beijing:Chemical Industry Press,2005:458-486.
[40] 杨通在,罗顺忠,许云书.氮吸附法表征多孔材料的孔结构[J].炭素,2006,1:17-22. Yang Tongzai,Luo Shunzhong,Xu Yunshu.Characterization of pore structure based on N₂ adsorption applied to porous materia-ls[J].Carbon,2006,1:17-22.
[41] 陈金妹,张健.ASAP2020比表面积及孔隙分析仪的应用[J].分析仪器,2009,(3):61-64. Chen Jinmei,Zhang Jian.Application of ASAP2020 specific surface area and porosity analyzer[J].Analytical Instrument,2009,(3):61-64.
[42] 邱正松,丁锐,于连香.泥页岩比表面积测定方法研究[J].钻井液与完井液,1999,16(1):9-11. Qiu Zhengsong,Ding Rui,Yu Lianxiang.The determining method researching of specific surface area for mud shale[J].Drilling Fluid & Completion Fluid,1999,16(1):9-11.
[43] 梁大川.粘土和泥页岩比表面积测定和计算方法综述[J].钻井液与完井液,1995,12(5):11-15. Liang Dachuan.Review on the determination and calculation methods of specific surface area of clay and shale[J].Drilling Fluid & Completion Fluid,1995,12(5):11-15.
[44] Carter D L,Heilman M D,Gonzalez C L.Ethylene glycol monoe-thyl ether for determining surface area of silicate minerals [J].Soil Science,1965,100(6):356-360.
[45] Yeliz Y,Abidin K.Comparison of methods for determining specific surface area of soils [J].Journal of Geotechnical and Geoe-nvironmental Engineering,2006,132(7):931-936.
[46] Langmuir I.The adsorption of gases on plane surfaces of glass,mica and platinum[J].Journal of the American Chemical Socienty,1918,40(9):1361-1403.
[47] Brunauer S,Emmett P H,Teller E.Adsorption of gases in multimolecular layers[J].Journal of the American Chemical Socienty,1938,60(2):309-319.
[48] Seaton N A,Walton J P R B,Quirke N.A new analysis method for the determination of the pore size distribution of porous carbons from nitrogen adsorption measurements[J].Carbon,1989,6(27):853-861.
[49] Lastoskie C,Gubbins K E,Quirke N.Pore size distribution analysis of microporous carbons:a density functional theory approach[J].The Journal of Physical Chemistry,1993,97(18):4786-4796.
[50] 刘培生.多孔材料孔径及孔径分布的测定方法[J].钛工业进展,2006,23(2):29-34. Liu Peisheng.Determining methods for aperture and aperture distribution of porous materials[J].Tanium Industry Progress,2006,23(2):29-34.
[51] Carter M R,Angers D A,Gregorich E G,et al.Characterizing organic matter retention for surface soils in eastern Canada using density and particle size fractions[J].Canadian Journal of Soil Science.,2003,83(1):11-23.
[52] 熊毅.土壤胶体(第一册)土壤胶体的物质基础[M].北京:科学出版社,1983:276-409. Xiong Yi.Soil Colloid(volume1)Material Basis of Soil Colloid.Beijing:Science Press,1983.
[53] 王行信,周书欣.有机粘土化学在油气生成研究中的意义[J].地质地球化学,1991,5:3-8. Wang Xingxin,Zhou Shuxin.Significance of organic-clay complexes chemistry in oil-gas creation [J].Geology Geochemistry,1991,19(5):3-8.
[54] Mayer L M.Surface area control of organic carbon accumulation in continental shelf sediments[J].Geochim Cosmochim Acta,1994,58:1271-1284.
[55] Hedges J I,Keil R G.Organic geochemical perspective on esturine processes:sorption reactions and consequences[J].Marine Chemistry,1999,65:55-65.
[56] 李善营,于炳松,Hailiang Dong,等.青海湖底沉积物的矿物物相及有机质保存研究[J].岩石矿物学杂志,2006,25(6):493-498. Li Shanying,Yu Bingsong,Hailiang Dong,et al.The mineralogi-cal phase and preservation of organic matter in sediments of Qinghai Lake[J].Acta Petrologica et Mineralogica,2006,25(6):493-498.
[57] Ransom B,Bennett R H,Baerwald R,et al.TEM study of in situ organic matter on continental margins:occurrence and the "monolayer" hypothesis[J].Marine Geology,1997,138:1-9.
[58] Ransom B,Dongseon K,Kastner M,et al.Organic matter prese-rvation on continental slopes:importance of mineralogy and surface area[J].Geochemica et Cosmochimica Acta,1998,62:1329-1345.
[59] 张雪芬,陆现彩,张林晔,等.页岩气的赋存形式研究及其石油地质意义[J].地球科学进展,2010,25(6):597-604. Zhang Xuefen,Lu Xiancai,Zhang Linye,et al.Occurrences of shale gas and their petrolem geological significance[J].Advances in Earth Science,2010,25(6):597-604.
[60] Curtis J B.Fractured shale-gas system[J].AAPG Bulletin,2002,86(11):1921-1938.
[61] 苗建宇,祝总棋,刘文荣,等.泥岩有机质的赋存状态与油气初次运移的关系[J].沉积学报,2004,22(1):169-174. Miao Jianyu,Zhu Zongqi,Liu Wenrong,et al.Relationship between occurrence of organic matter and the primary migration of hydrocarbon in argillaceous rock[J].Acta Sedimentologica Sinica,2004,22(1):169-174.
[62] 张林晔,孔祥星,张春荣,等.济阳坳陷下第三系优质烃源岩的发育及其意义[J].地球化学,2003,32(1):35-42. Zhang Linye,Kong Xiangxing,Zhang Chunrong,et al.High-quality oil-prone source rocks in Jiyang Depression[J].Geochimica,2003,32(1):35-42.
[63] Durand B.Kerogen-insoluble organic matter from sedimentary rocks[M].Paris:Technip,1980:1-70.
[64] Tissot B P,Welte D H.石油的形成与分布[M].徐永元,徐濂,郝石生,等,译.北京:石油工业出版社,1989:339-390. Tissot B P,Welte D H.Petroleum formation and occurrence[M].Translate by Xu Yongyuan,Xu Lian,Hao Shisheng,et a1.Beijing:Petroleum Industry Press,1989:339-390.
[65] 蔡进功,卢龙飞,丁飞,等.烃源岩中黏土与可溶有机质相互作用研究展望[J].同济大学学报(自然科学版),2009,37(12):1679-1684. Cai Jingong,Lu Longfei,Ding Fei,et al.Significance of interaction between soluble organic matter and clay minerals in muddy source rocks[J].Journal of Tongji University(Natural Science),2009,37(12):1679-1684.
[66] 冯小萍.表层沉积物颗粒分级及有机质的分配差异性研究.上海:同济大学,2011. Feng Xiaoping.The fractionation classification of surface sediments and the research on difference in organic matter enrichment in different fractions.Shanghai:Tongji University,2011.
[67] 樊馥,蔡进功,徐金鲤,等.泥质烃源岩不同有机显微组分的原始赋存态[J].同济大学学报(自然科学版),2011,39(3):434-439. Fan Fu,Cai Jingong,Xu Jinli,et al.Original preservation of different organic micro-components in muddy source rock[J].Journal of Tongji University(Natural Science),2011,39(3):434-439.
[68] 宋一涛,廖永胜,张守春.半咸-咸水湖相烃源岩中两种赋存状态可溶有机质的测定及其意义[J].科学通报,2005,50(14):1531-1534. Song Yitao,Liao Yongsheng,Zhang Shouchun.Quantification and implications of two types of soluble organic matter from brackish to saline lake source rocks[J].Science Bulletin,2005,50(14):1531-1534.
[69] 陆现彩,胡文宣,符琦,等.烃源岩中可溶有机质与粘土矿物结合关系-以东营凹陷沙四段低熟烃源岩为例[J].地质科学,1999,34(1):69-77. Lu Xiancai,Hu Wenxuan,Fu Qi,et al.Study of combination pattern of soluble organic matters and clay minerals in the immature source rocks in Dongying Depression,China[J].China Scientia Geologica Sinica,1999,34(1):69-77.
[70] 刘建清,赖兴运,于炳松,等.成岩作用的研究现状及展望[J].石油实验地质,2006,28(1):65-72. Liu Jianqing,Lai Xingyun,Yu Bingsong,et al.The current situa-tion and developing tendency of the study on diagenesis[J].Petroleum Geology & Experiment,2006,28(1):65-72.

Progress and significance of research on relation between specific surface area and organic matter in argillaceous source rocks

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