Oil & Gas Geology ›› 2020, Vol. 41 ›› Issue (2): 270-283.doi: 10.11743/ogg20200204
• Petroleum Geology • Previous Articles Next Articles
Zhenhuan Shen1(), Bingsong Yu1, Chenyang Bai1, Shujun Han1, Zhihui Yang1, Zhibin Fei2
Received:
2018-03-28
Online:
2020-04-28
Published:
2020-04-03
CLC Number:
Zhenhuan Shen, Bingsong Yu, Chenyang Bai, Shujun Han, Zhihui Yang, Zhibin Fei. The impact of thermodynamics and kinetics of feldspar dissolution-precipitation on reservoir quality: A case study from the Es3, Bonan Sag, Bohai Bay Basin[J]. Oil & Gas Geology, 2020, 41(2): 270-283.
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Table 1
The list of kinetic rate parameters used in the simulations and the n-reaction order with respect to H+"
矿物 | 表面积/(cm2·g-1) | 溶解 | 成核 | 反应级数n | |||
k25/(mol·cm-2·s-1) | Ea/(kJ·mol-1) | k25/(mol·cm-2·s-1) | Ea/(kJ·mol-1) | ||||
钾长石 | 9.8 | 8.710×10-15 | 51.7 | 3.890×10-17 | 38.0 | 0.500 | |
钠长石 | 9.8 | 6.918×10-15 | 65.0 | 2.754×10-17 | 69.8 | 0.457 | |
钙长石 | 9.8 | 3.162×10-8 | 16.6 | 7.568×10-17 | 17.8 | 1.411 | |
高岭石 | 151.6 | 6.918×10-18 | 22.2 | 0.777 | |||
石英 | 9.8 | 1.023×10-18 | 87.7 | 0 |
Table 2
The list of formation water parameters in the Es3, Bonan sag, Bohai Bay Basin"
序号 | 井号 | 深度/m | 温度/℃ | pH值 | 总矿化度/ (g·L-1) | 水型 | 离子浓度/(mmol·L-1) | aCa2+ | |||||||||||
Na+ | K+ | Ca2+ | Mg2+ | Cl- | SO42- | OH- | HCO3- | CO32- | I | aNa+ | aK+ | ||||||||
1 | 义69 | 3520.1 | 144.3 | 6 | 1.66 | 硫酸钠 | 18.4 | 0.1 | 2.2 | 1.2 | 14.7 | 2.1 | 0 | 6.4 | 0 | 0.031 | 15.14 | 0.08 | 1.04 |
2 | 义601-1 | 3275.6 | 134.3 | 8.25 | 13.31 | 碳酸氢钠 | 163.6 | 0.8 | 3.2 | 2.6 | 133.1 | 0 | 0 | 42.9 | 0 | 0.182 | 116.25 | 0.56 | 0.86 |
3 | 义288 | 2932.6 | 120.2 | 6.62 | 4.46 | 氯化镁 | 63.5 | 0.3 | 2.5 | 2.6 | 63.8 | 2.4 | 0 | 5.6 | 0 | 0.082 | 48.64 | 0.24 | 0.91 |
4 | 渤古403 | 3034.4 | 124.4 | 6.5 | 1.89 | 氯化镁 | 15.6 | 0.1 | 3.3 | 5.0 | 25.2 | 1.3 | 0 | 4.2 | 0 | 0.042 | 12.64 | 0.06 | 1.45 |
5 | 渤深8 | 3828.7 | 157.0 | 6.5 | 1.95 | 氯化镁 | 14.8 | 0.1 | 4.2 | 3.3 | 15.2 | 3.0 | 0 | 8.7 | 0 | 0.040 | 11.92 | 0.06 | 1.81 |
6 | 罗902 | 2259.0 | 92.6 | 7 | 12.34 | 碳酸氢钠 | 183.4 | 0.9 | 2.4 | 0.4 | 131.1 | 8.9 | 0 | 40.8 | 0 | 0.202 | 131.82 | 0.63 | 0.68 |
7 | 义135 | 3704.0 | 151.9 | 6 | 13.37 | 氯化钙 | 200.1 | 1.0 | 2.2 | 2.9 | 210.0 | 0 | 0 | 14.3 | 0 | 0.223 | 138.57 | 0.66 | 0.54 |
8 | 义136 | 3082.0 | 126.4 | 7 | 7.15 | 碳酸氢钠 | 98.4 | 0.5 | 0.9 | 0.7 | 54.5 | 0.6 | 0 | 46.4 | 0 | 0.104 | 73.66 | 0.36 | 0.31 |
9 | 义141 | 3052.9 | 125.2 | 6.5 | 2.32 | 氯化钙 | 16.7 | 0.1 | 9.8 | 1.2 | 29.9 | 3.2 | 0 | 2.3 | 0 | 0.053 | 13.25 | 0.07 | 4.04 |
10 | 义142 | 2638.0 | 108.2 | 7 | 7.28 | 碳酸氢钠 | 95.6 | 0.5 | 0.8 | 5.0 | 58.3 | 6.0 | 0 | 37.3 | 0 | 0.119 | 71.29 | 0.35 | 0.27 |
11 | 义172 | 3187.4 | 130.7 | 5 | 69.95 | 氯化钙 | 707.3 | 3.6 | 132.4 | 143.4 | 1246.3 | 0 | 0 | 10.2 | 0 | 1.535 | 490.85 | 1.89 | 26.91 |
12 | 义115 | 3855.5 | 158.1 | 6 | 4.51 | 氯化镁 | 33.9 | 0.2 | 7.9 | 13.7 | 60.3 | 2.2 | 0 | 12.1 | 0 | 0.101 | 25.14 | 0.12 | 2.53 |
13 | 埕915 | 1699.6 | 69.7 | 9 | 14.10 | 碳酸氢钠 | 213.4 | 1.1 | 1.1 | 0.4 | 151.8 | 4.2 | 0 | 52.0 | 2.6 | 0.226 | 153.91 | 0.74 | 0.30 |
14 | 义631 | 2858.6 | 117.2 | 7 | 11.85 | 碳酸氢钠 | 139.6 | 0.7 | 10.9 | 4.2 | 90.8 | 0 | 0 | 79.7 | 0 | 0.186 | 99.79 | 0.48 | 3.04 |
15 | 义943 | 3163.0 | 129.7 | 8 | 28.90 | 碳酸氢钠 | 473.4 | 2.4 | 5.1 | 0.8 | 471.1 | 0 | 0 | 16.5 | 0 | 0.494 | 315.09 | 1.43 | 1.07 |
16 | 义283 | 3162.7 | 129.7 | 5.78 | 3.83 | 氯化钙 | 46.1 | 0.2 | 4.7 | 6.0 | 66.0 | 0 | 0 | 1.5 | 0 | 0.078 | 35.32 | 0.17 | 1.71 |
17 | 义944 | 3574.1 | 146.5 | 6.37 | 126.32 | 氯化镁 | 1199.3 | 6.0 | 8.2 | 542.8 | 1996.0 | 138.1 | 0 | 18.5 | 0 | 2.988 | 982.69 | 3.05 | 2.25 |
18 | 义601 | 3232.8 | 132.5 | 7.5 | 20.09 | 碳酸氢钠 | 315.5 | 1.6 | 3.6 | 1.2 | 283.0 | 2.4 | 0 | 38.5 | 0 | 0.334 | 214.05 | 1.00 | 0.83 |
19 | 义173 | 3424.4 | 140.4 | 7.5 | 22.70 | 碳酸氢钠 | 323.2 | 1.6 | 2.3 | 3.0 | 186.7 | 23.3 | 0 | 101.7 | 0 | 0.364 | 217.14 | 1.01 | 0.50 |
20 | 义251 | 3191.4 | 130.8 | 7 | 19.43 | 碳酸氢钠 | 276.7 | 1.4 | 3.0 | 15.1 | 251.8 | 7.6 | 0 | 47.4 | 0 | 0.340 | 187.67 | 0.88 | 0.69 |
21 | 义281 | 2288.5 | 93.8 | 6 | 20.45 | 氯化钙 | 216.0 | 1.1 | 51.4 | 10.3 | 296.5 | 1.5 | 0 | 40.7 | 0 | 0.403 | 148.17 | 0.69 | 12.08 |
22 | 义361 | 3464.9 | 142.1 | 8.02 | 24.36 | 碳酸氢钠 | 379.5 | 1.9 | 2.1 | 0.1 | 297.9 | 15.6 | 0 | 56.3 | 0 | 0.403 | 253.21 | 1.17 | 0.44 |
23 | 义180 | 3216.9 | 131.9 | 6.8 | 12.30 | 碳酸氢钠 | 179.6 | 0.9 | 1.2 | 2.2 | 127.8 | 3.9 | 0 | 51.4 | 0 | 0.194 | 127.03 | 0.61 | 0.31 |
24 | 义184 | 3245.6 | 133.1 | 10.75 | 7.51 | 碳酸氢钠 | 108.2 | 0.5 | 8.7 | 0.0 | 88.3 | 0 | 0 | 12.6 | 12.6 | 0.147 | 78.29 | 0.38 | 2.56 |
25 | 义185 | 3218.6 | 132.0 | 7.35 | 6.42 | 氯化镁 | 78.0 | 0.4 | 7.8 | 5.5 | 81.7 | 5.2 | 0 | 12.7 | 0 | 0.123 | 57.38 | 0.28 | 2.42 |
26 | 义179 | 2926.1 | 120.0 | 8.69 | 2.07 | 硫酸钠 | 26.2 | 0.1 | 1.9 | 1.6 | 24.0 | 2.6 | 0 | 4.1 | 0 | 0.039 | 21.33 | 0.11 | 0.86 |
27 | 渤古4 | 3444.3 | 141.2 | 7.11 | 7.06 | 碳酸氢钠 | 97.8 | 0.5 | 0.3 | 0.5 | 50.1 | 1.3 | 0 | 47.2 | 0 | 0.102 | 72.89 | 0.36 | 0.08 |
28 | 罗683 | 2785.6 | 114.2 | 6.06 | 4.05 | 碳酸氢钠 | 49.5 | 0.2 | 4.6 | 1.5 | 40.2 | 2.8 | 0 | 16.2 | 0 | 0.071 | 38.50 | 0.19 | 1.76 |
29 | 罗322 | 2257.0 | 92.5 | 7.34 | 6.86 | 碳酸氢钠 | 102.9 | 0.5 | 1.6 | 1.0 | 86.1 | 0.9 | 0 | 20.6 | 0 | 0.112 | 77.60 | 0.38 | 0.55 |
30 | 义183 | 3998.0 | 163.9 | 8.6 | 19.33 | 碳酸氢钠 | 281.0 | 1.4 | 1.2 | 1.2 | 167.7 | 17.6 | 0 | 83.9 | 0 | 0.307 | 188.55 | 0.88 | 0.25 |
31 | 罗69 | 2966.0 | 121.6 | 6.5 | 11.22 | 氯化镁 | 169.0 | 0.8 | 5.2 | 4.0 | 171.0 | 3.3 | 0 | 10.3 | 0 | 0.201 | 119.82 | 0.57 | 1.40 |
32 | 义123-1 | 3344.8 | 137.1 | 7.82 | 97.21 | 氯化钙 | 1625.9 | 8.2 | 11.6 | 0.0 | 1638.9 | 0 | 0 | 16.0 | 0 | 1.668 | 1138.31 | 4.29 | 2.38 |
33 | 罗152 | 3096.0 | 126.9 | 9 | 15.58 | 氯化钙 | 189.2 | 1.0 | 38.3 | 0.5 | 256.1 | 0 | 0 | 7.2 | 2.2 | 0.309 | 129.44 | 0.61 | 9.03 |
34 | 义289 | 3500.0 | 143.5 | 7.58 | 49.59 | 碳酸氢钠 | 682.4 | 3.4 | 11.8 | 25.1 | 530.0 | 0 | 0 | 228.4 | 0 | 0.796 | 447.13 | 1.93 | 2.24 |
35 | 义176 | 3773.8 | 154.7 | 8.32 | 22.97 | 碳酸氢钠 | 363.4 | 1.8 | 2.4 | 1.3 | 306.4 | 16.9 | 0 | 32.0 | 0 | 0.393 | 241.10 | 1.11 | 0.49 |
36 | 义286 | 3260.0 | 133.7 | 7.37 | 40.87 | 碳酸氢钠 | 643.2 | 3.2 | 1.2 | 1.2 | 506.1 | 32.2 | 0 | 79.8 | 0 | 0.685 | 423.83 | 1.86 | 0.23 |
37 | 罗321 | 1800.0 | 73.8 | 8.5 | 10.05 | 碳酸氢钠 | 158.4 | 0.8 | 0.3 | 0.1 | 120.0 | 1.4 | 0 | 28.2 | 4.4 | 0.166 | 116.66 | 0.56 | 0.09 |
38 | 罗357 | 2579.0 | 105.7 | 8 | 6.93 | 碳酸氢钠 | 88.9 | 0.4 | 0.8 | 0.2 | 27.7 | 0.4 | 0 | 62.6 | 0 | 0.092 | 67.76 | 0.33 | 0.27 |
39 | 罗151 | 3062.6 | 125.6 | 8 | 24.08 | 氯化钙 | 351.0 | 1.8 | 23.6 | 1.8 | 377.7 | 0 | 0 | 25.8 | 0 | 0.429 | 235.68 | 1.08 | 5.12 |
40 | 垦629 | 2042.0 | 83.7 | 8 | 6.09 | 碳酸氢钠 | 83.8 | 0.4 | 0.7 | 1.2 | 49.8 | 0 | 0 | 38.2 | 0 | 0.090 | 64.64 | 0.32 | 0.27 |
41 | 义501-1 | 2936.3 | 120.4 | 7.25 | 15.12 | 氯化镁 | 247.4 | 1.2 | 2.4 | 2.4 | 252.4 | 1.8 | 0 | 2.2 | 0 | 0.265 | 171.72 | 0.81 | 0.59 |
42 | 义193 | 3312.5 | 135.8 | 8.45 | 1.53 | 氯化镁 | 18.1 | 0.1 | 1.8 | 1.5 | 18.6 | 1.6 | 0 | 3.0 | 0 | 0.030 | 14.99 | 0.07 | 0.88 |
43 | 罗71 | 1987.2 | 81.5 | 8.15 | 9.37 | 碳酸氢钠 | 145.3 | 0.7 | 1.4 | 1.0 | 127.6 | 0.6 | 0 | 22.1 | 0 | 0.154 | 107.31 | 0.52 | 0.44 |
44 | 义292 | 3556.6 | 145.8 | 8.58 | 0.72 | 硫酸钠 | 8.3 | 0.0 | 1.0 | 0.9 | 8.1 | 1.2 | 0 | 0.8 | 0.4 | 0.015 | 7.15 | 0.04 | 0.55 |
45 | 义189 | 3174.0 | 130.1 | 7.28 | 15.28 | 氯化镁 | 244.2 | 1.2 | 1.2 | 6.3 | 247.7 | 5.1 | 0 | 2.6 | 0 | 0.273 | 168.22 | 0.80 | 0.30 |
46 | 义50 | 3149.4 | 129.1 | 7.3 | 18.24 | 碳酸氢钠 | 288.8 | 1.5 | 3.2 | 1.0 | 262.4 | 3.7 | 0 | 28.9 | 0 | 0.306 | 197.48 | 0.93 | 0.75 |
47 | 义633 | 2740.5 | 112.4 | 7 | 8.92 | 氯化钙 | 125.3 | 0.6 | 5.5 | 7.9 | 142.0 | 3.0 | 0 | 4.8 | 0 | 0.169 | 90.52 | 0.44 | 1.58 |
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