全二维气相色谱技术在石油地球化学中的应用进展

doi:10.11743/ogg20240219

Abstract

Abstract:

Petroleum， a complex multi-component organic mixture， is susceptible to various physical， chemical， and biological transformations during its formation and migration. Consequently， it is difficult to identify compounds of extremely low concentrations or special compounds in petroleum using conventional one-dimensional gas chromatography （1DGC）. In contrast， comprehensive two-dimensional gas chromatography （GC×GC）， enjoying ultra-high resolution and sensitivity， high peak capacity， and accurate qualitative and quantitative detection results， allows for the separation and identification of complex mixtures， thus meeting the challenge of performing accurate， quantitative analyses of complex petroleum components. Key findings of this study include：（1） Coupled with various detectors such as a sulfur chemiluminescence detector （SCD）， electron capture detector （ECD）， flame ionization detector （FID）， or a time-of-flight mass spectrometer （TOFMS）， the GC×GC exhibits wide application and notable efficiency in analyzing and detecting the hydrocarbon compositions and heteroatomic compounds of crude oil fractions；（2） GC×GC can be employed to analyze unresolved complex mixtures （UCMs） in heavy oil， assess the cracking degree of crude oil， determine the preservation threshold of ultra-deep liquid hydrocarbon， quantitatively assess the intensity of thermochemical sulfate reduction （TSR）， and identify potential trace molecular compounds in crude oil and their structures；（3） GC×GC， which has exhibited unique advantages in the field of petroleum geochemistry， is expected to play a significant role in shale oil and gas exploration and research on the migration， accumulation， preservation， and modification of liquid crude oil in deep to ultra-deep reservoirs.

Key words: adamantane, comprehensive two-dimensional gas chromatography （GC×GC）, separation principle, petroleum geochemistry, heavy oil, crude oil

CLC Number:

TE122.1

Jiakai HOU, Zhiyao ZHANG, Shengbao SHI, Guangyou ZHU. Advances in the application of comprehensive two-dimensional gas chromatography in petroleum geochemistry[J]. Oil & Gas Geology, 2024, 45(2): 565-580.

Figures/Tables 11

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地球化学意义	地球化学参数	样品号
地球化学意义	地球化学参数	A1	A2	A3	A4	A5	A6
成熟度判识	Ts/Tm/%	1.63	3.39	4.64	3.25	4.08	5.60
	Ts/（Ts+Tm）/%	0.65	0.78	2.54	6.43	2.03	2.79
	Ts/17α（H）-C₃₀藿烷/%	1.45	1.20	4.48	4.14	1.86	4.89
	ααα-C₂₉甾烷20S/（20S+20R）/%	1.03	2.72	15.12	8.01	4.71	6.56
	C₂₉甾烷ββ/（ββ+αα）/%	2.72	2.71	1.69	1.62	4.18	0.20
	碳优势指数（CPI）/%	2.53	1.51	0.78	1.73	2.41	1.65
	奇偶优势（OEP）/%	0.13	0.30	2.79	0.84	1.85	0.78
	MP_Ⅰ/%	3.17	4.27	3.07	2.01	3.07	3.44
	MP_Ⅱ/%	2.43	2.73	4.25	4.63	3.97	4.90
	甲基萘比（MNR）/%	4.92	4.56	4.30	0.49	2.66	4.51
	乙基萘比（ENR）/%	12.54	10.78	5.00	6.42	10.21	13.63
	二甲基萘比（DNR）/%	13.53	6.87	10.13	18.39	4.03	11.12
	甲基菲比（MPR）/%	3.10	4.63	3.58	3.87	4.06	7.59
	甲基菲指数（MPI）/%	4.54	1.10	11.84	5.09	10.73	10.70
	MDI	—	—	—	—	—	—
	MAI	—	—	—	—	—	—
	DMAI	—	—	—	—	—	—
沉积环境、物源判识	伽马蜡烷/α，β-藿烷/%	4.76	11.59	10.09	17.10	9.70	32.95
	Pr/Ph/%	1.52	4.90	5.44	2.87	1.51	3.53
	1， 2， 5-三甲基萘/菲/%	3.93	2.53	6.53	1.27	6.67	1.22
	二苯并噻吩/菲/%	1.37	1.10	1.79	2.15	2.53	1.62
	三芳甾烷C₂₈/（C₂₆—C₂₈）/%	2.96	3.14	1.51	4.68	3.66	1.90
	ααα（20R）甾烷 C₂₈/C₂₉/%	0.61	1.86	4.97	2.51	0.86	2.96

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Advances in the application of comprehensive two-dimensional gas chromatography in petroleum geochemistry

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