Oil & Gas Geology ›› 2021, Vol. 42 ›› Issue (6): 1451-1463.doi: 10.11743/ogg20210619
• Methods and Technologies • Previous Articles Next Articles
Qiulin Guo(), Jian Wang, Xiaoming Chen, Ningsheng Chen, Xiaozhi Wu, Zhuangxiaoxue Liu
Received:
2020-04-13
Online:
2021-12-28
Published:
2021-12-16
CLC Number:
Qiulin Guo, Jian Wang, Xiaoming Chen, Ningsheng Chen, Xiaozhi Wu, Zhuangxiaoxue Liu. Discussion on evaluation method of total oil and movable oil in-place[J]. Oil & Gas Geology, 2021, 42(6): 1451-1463.
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Table 1
Rock-Eval pyrolysis results, adsorbed oil content, and correction coefficient of the Qianjiang Formation shale, Jianghan Basin (Rock-Eval data from reference [26])"
样品 编号 | 井名 | 深度/ m | 全岩热解数据 | 抽提后的全岩热解数据 | 未校正的 | 等价TOC校正后的 | ||||||||||||
S1/(mg·g-1) | S2/(mg·g-1) | TOCA/% | S1EX/(mg·g-1) | S2EX/(mg·g-1) | TOCEX/% | (S1- S1EX)/ (mg·g-1) | (S2- S2EX)/ (mg·g-1) | ΔS2eq/(mg·g-1) | keq | TOCB/% | |TOCA-TOCB|/% | |ΔS2eq-ΔS2|/ (mg·g-1) | ||||||
1 | Wangyun-11 | 1 746.1 | 2.99 | 14.48 | 2.59 | 0.04 | 11.30 | 2.03 | 2.95 | 3.18 | 2.67 | 1.05 | 2.48 | 0.11 | 0.51 | |||
2 | Wangyun-11 | 1 747.0 | 4.60 | 25.60 | 4.48 | 0.06 | 22.62 | 3.80 | 4.54 | 2.98 | 2.35 | 1.03 | 4.43 | 0.05 | 0.63 | |||
3 | Wangyun-11 | 1 749.3 | 20.86 | 17.14 | 4.48 | 0.06 | 3.59 | 1.44 | 20.80 | 13.55 | 12.99 | 1.16 | 4.30 | 0.18 | 0.56 | |||
4 | Wangyun-11 | 1 714.3 | 3.05 | 2.10 | 0.94 | 0.01 | 0.69 | 0.65 | 3.04 | 1.41 | 1.50 | 0.86 | 1.02 | 0.08 | 0.09 | |||
5 | Wangyun-11 | 1 710.6 | 9.09 | 9.78 | 3.68 | 0.03 | 4.77 | 2.33 | 9.06 | 5.01 | 4.57 | 1.09 | 3.50 | 0.18 | 0.44 | |||
6 | Wangyun-11 | 1 707.3 | 10.97 | 7.61 | 2.98 | 0.01 | 1.95 | 1.25 | 10.96 | 5.66 | 5.04 | 1.32 | 2.64 | 0.35 | 0.62 | |||
7 | Wangyun-11 | 1 705.9 | 9.92 | 8.17 | 3.40 | 0.03 | 2.80 | 2.01 | 9.89 | 5.37 | 5.18 | 1.07 | 3.28 | 0.12 | 0.19 | |||
8 | Wangyun-11 | 1 704.7 | 2.02 | 1.47 | 0.62 | 0.01 | 0.44 | 0.26 | 2.01 | 1.03 | 0.82 | 1.48 | 0.51 | 0.11 | 0.21 | |||
9 | Wangyun-11 | 1 649.2 | 4.50 | 55.96 | 8.54 | 0.15 | 50.82 | 7.52 | 4.35 | 5.14 | 1.58 | 1.07 | 8.31 | 0.23 | 3.56 | |||
10 | Wangyun-11 | 1 646.5 | 17.09 | 16.70 | 4.63 | 0.04 | 3.99 | 1.93 | 17.05 | 12.71 | 12.16 | 1.14 | 4.41 | 0.22 | 0.55 | |||
11 | Wangyun-11 | 1 645.1 | 8.81 | 12.61 | 3.02 | 0.03 | 5.72 | 1.48 | 8.78 | 6.89 | 5.55 | 1.23 | 2.79 | 0.23 | 1.34 | |||
12 | Wangyun-11 | 1 633.0 | 4.65 | 31.39 | 5.33 | 0.10 | 26.13 | 4.48 | 4.55 | 5.26 | 4.89 | 1.01 | 5.30 | 0.03 | 0.37 | |||
13 | Wangyun-11 | 1 632.3 | 8.82 | 57.62 | 9.71 | 0.26 | 49.11 | 8.14 | 8.56 | 8.51 | 6.71 | 1.04 | 9.56 | 0.15 | 1.80 | |||
14 | Wangyun-11 | 1 309.3 | 5.57 | 46.03 | 6.03 | 0.28 | 36.94 | 4.92 | 5.29 | 9.09 | 10.88 | 0.95 | 6.12 | 0.09 | 1.79 | |||
15 | Qianyeping-2 | 1 451.6 | 0.73 | 3.80 | 0.98 | 0.04 | 2.98 | 0.90 | 0.69 | 0.82 | 1.03 | 0.93 | 1.03 | 0.05 | 0.21 | |||
16 | Qianyeping-2 | 1 463.5 | 3.67 | 33.15 | 5.58 | 0.21 | 27.54 | 4.75 | 3.46 | 5.61 | 4.77 | 1.03 | 5.51 | 0.07 | 0.84 | |||
17 | Qianyeping-2 | 1 467.8 | 3.49 | 17.57 | 4.35 | 0.11 | 13.30 | 3.57 | 3.38 | 4.27 | 3.50 | 1.06 | 4.21 | 0.14 | 0.77 | |||
18 | Qianyeping-2 | 1 471.1 | 1.53 | 10.98 | 2.72 | 0.10 | 8.17 | 2.19 | 1.43 | 2.81 | 1.85 | 1.12 | 2.54 | 0.18 | 0.96 | |||
19 | Qianyeping-2 | 1 476.5 | 3.01 | 31.11 | 5.00 | 0.15 | 24.76 | 4.21 | 2.86 | 6.35 | 6.09 | 1.01 | 4.98 | 0.02 | 0.26 | |||
20 | Qianyeping-2 | 1 481.9 | 0.80 | 6.50 | 1.47 | 0.07 | 4.61 | 1.20 | 0.73 | 1.89 | 1.60 | 1.06 | 1.42 | 0.05 | 0.29 | |||
21 | Qianyeping-2 | 1 485.7 | 1.68 | 7.58 | 2.11 | 0.12 | 4.86 | 1.72 | 1.56 | 2.72 | 2.60 | 1.03 | 2.08 | 0.03 | 0.12 | |||
22 | Qianyeping-2 | 1 492.2 | 3.76 | 24.63 | 3.89 | 0.17 | 21.87 | 3.29 | 3.59 | 2.76 | 1.69 | 1.05 | 3.82 | 0.07 | 1.07 | |||
23 | Qianyeping-2 | 1 500.3 | 1.82 | 23.90 | 4.34 | 0.15 | 21.73 | 3.99 | 1.67 | 2.17 | 1.87 | 1.01 | 4.31 | 0.03 | 0.30 | |||
24 | Qianyeping-2 | 1 507.1 | 0.35 | 2.37 | 0.90 | 0.03 | 1.65 | 0.88 | 0.32 | 0.72 | 0.87 | 0.91 | 0.97 | 0.07 | 0.15 | |||
25 | Qianyeping-2 | 1 513.2 | 3.25 | 12.56 | 3.45 | 0.07 | 4.08 | 1.94 | 3.18 | 8.48 | 7.10 | 1.34 | 2.91 | 0.54 | 1.38 | |||
26 | Qianyeping-2 | 1 518.8 | 1.91 | 6.89 | 2.60 | 0.05 | 3.49 | 2.05 | 1.86 | 3.40 | 3.18 | 1.06 | 2.49 | 0.11 | 0.22 | |||
27 | Qianyeping-2 | 1 528.7 | 4.67 | 10.20 | 2.86 | 0.08 | 4.33 | 1.70 | 4.59 | 5.87 | 4.93 | 1.22 | 2.57 | 0.29 | 0.94 | |||
28 | Qianyeping-2 | 1 535.2 | 10.95 | 34.75 | 6.85 | 0.20 | 23.45 | 4.85 | 10.75 | 11.30 | 9.98 | 1.06 | 6.69 | 0.16 | 1.32 | |||
29 | Qianyeping-2 | 1 537.2 | 8.07 | 17.72 | 3.51 | 0.12 | 9.10 | 2.85 | 7.95 | 8.62 | 11.77 | 0.65 | 4.23 | 0.72 | 3.15 | |||
平均值 | — | — | — | 3.83 | — | — | — | — | 5.30 | 4.82 | 1.07 | 3.74 | 0.16 | 0.85 |
Table 2
Rock-Eval pyrolysis results, adsorbed oil content, and correction coefficient of the Shahejie Formation shale, Bohai Bay Basin (Rock-Eval data from reference [16])"
全岩热解数据 | 抽提后的全岩热解数据 | 未校正的 | 等价TOC含量校正后的 | ||||||||||||||||
样品编号 | 井名 | 深度/m | S1/(mg·g-1) | S2/(mg·g-1) | TOCA/% | S1EX/(mg·g-1) | S2EX/(mg·g-1) | TOCEX/% | (S1- S1EX)/ (mg·g-1) | (S2- S2EX)/ (mg·g-1) | ΔS2eq/(mg·g-1) | keq | TOCB/% | |TOCA-TOCB|/% | |ΔS2eq-ΔS2|/ (mg·g-1) | ||||
1 | LY1–18 | 3 580.17 | 5.34 | 11.86 | 3.58 | 1.31 | 8.90 | 2.83 | 4.03 | 2.96 | 2.21 | 1.08 | 3.30 | 0.28 | 0.75 | ||||
2 | LY1–17 | 3 587.18 | 4.47 | 7.54 | 2.43 | 1.49 | 6.15 | 1.87 | 2.98 | 1.39 | 0.41 | 1.16 | 2.10 | 0.33 | 0.98 | ||||
3 | LY1–16 | 3 600.10 | 11.90 | 18.44 | 4.97 | 0.50 | 8.64 | 3.13 | 11.40 | 9.8 | 9.53 | 1.03 | 4.82 | 0.15 | 0.27 | ||||
4 | LY1–15 | 3 613.38 | 9.23 | 12.88 | 3.63 | 1.84 | 7.78 | 2.53 | 7.39 | 5.10 | 4.83 | 1.03 | 3.51 | 0.12 | 0.27 | ||||
5 | LY1–14 | 3 624.31 | 5.46 | 8.52 | 2.70 | 1.10 | 5.29 | 1.91 | 4.36 | 3.23 | 2.63 | 1.11 | 2.42 | 0.28 | 0.60 | ||||
6 | LY1–13 | 3 635.56 | 6.05 | 12.60 | 3.93 | 0.29 | 6.52 | 2.54 | 5.76 | 6.08 | 4.75 | 1.20 | 3.26 | 0.67 | 1.33 | ||||
7 | LY1–12 | 3 644.95 | 9.35 | 18.13 | 5.15 | 0.62 | 10.90 | 4.01 | 8.73 | 7.23 | 7.91 | 0.94 | 5.49 | 0.34 | 0.68 | ||||
8 | LY1–11-a | 3 659.12 | 13.76 | 24.96 | 6.93 | 1.60 | 15.09 | 4.96 | 12.16 | 9.87 | 9.30 | 1.04 | 6.68 | 0.25 | 0.57 | ||||
9 | LY1–10 | 3 671.64 | 10.01 | 18.93 | 5.97 | 0.66 | 13.01 | 4.90 | 9.35 | 5.92 | 6.62 | 0.95 | 6.31 | 0.34 | 0.70 | ||||
10 | LY1–9 | 3 690.20 | 2.64 | 4.85 | 1.73 | 1.15 | 3.47 | 1.43 | 1.49 | 1.38 | 1.18 | 1.06 | 1.63 | 0.10 | 0.20 | ||||
11 | LY1–8 | 3 748.10 | 3.42 | 5.48 | 2.22 | 0.50 | 2.93 | 1.47 | 2.92 | 2.55 | 1.82 | 1.25 | 1.78 | 0.44 | 0.73 | ||||
12 | LY1–7 | 3 757.16 | 3.02 | 4.80 | 1.94 | 0.38 | 2.14 | 1.44 | 2.64 | 2.66 | 2.56 | 1.05 | 1.85 | 0.09 | 0.10 | ||||
13 | LY1–5 | 3 786.35 | 8.43 | 8.87 | 3.26 | 0.41 | 3.33 | 1.93 | 8.02 | 5.54 | 5.13 | 1.12 | 2.90 | 0.36 | 0.41 | ||||
14 | LY1–4 | 3 797.74 | 7.29 | 7.99 | 3.25 | 3.41 | 6.58 | 2.90 | 3.88 | 1.41 | 1.70 | 0.96 | 3.40 | 0.15 | 0.29 | ||||
15 | LY1–3 | 3 812.73 | 6.35 | 7.72 | 2.97 | 3.85 | 6.23 | 2.54 | 2.50 | 1.49 | 1.13 | 1.06 | 2.81 | 0.16 | 0.36 | ||||
16 | LY1–2 | 3 817.87 | 11.52 | 14.87 | 5.58 | 0.71 | 5.89 | 3.77 | 10.81 | 8.98 | 8.69 | 1.05 | 5.31 | 0.27 | 0.29 | ||||
17 | LY1–1 | 3 822.75 | 5.27 | 6.81 | 2.43 | 0.23 | 2.23 | 1.43 | 5.04 | 4.58 | 4.22 | 1.16 | 2.09 | 0.34 | 0.36 | ||||
18 | NY1–22 | 3 307.06 | 1.98 | 13.87 | 2.60 | 0.69 | 13.31 | 2.57 | 1.29 | 0.56 | 1.74 | 0.91 | 2.85 | 0.25 | 1.18 | ||||
19 | NY1–21 | 3 314.10 | 4.95 | 26.87 | 4.45 | 0.67 | 21.72 | 3.55 | 4.28 | 5.15 | 3.68 | 1.07 | 4.17 | 0.28 | 1.47 | ||||
20 | NY1–20 | 3 351.47 | 2.58 | 9.69 | 2.14 | 0.29 | 8.11 | 1.90 | 2.29 | 1.58 | 2.14 | 0.93 | 2.30 | 0.16 | 0.56 | ||||
21 | NY1–19 | 3 360.55 | 2.35 | 9.96 | 2.11 | 0.23 | 9.62 | 1.94 | 2.12 | 0.34 | 0.64 | 0.97 | 2.18 | 0.07 | 0.30 | ||||
22 | NY1–18 | 3 374.19 | 6.04 | 26.98 | 4.64 | 0.48 | 23.73 | 4.37 | 5.56 | 3.25 | 7.93 | 0.80 | 5.78 | 1.14 | 4.68 | ||||
23 | NY1–17 | 3 380.60 | 2.25 | 8.37 | 1.75 | 0.25 | 5.1 | 1.09 | 2.00 | 3.27 | 1.52 | 1.34 | 1.30 | 0.45 | 1.75 | ||||
24 | NY1–16 | 3 398.85 | 7.48 | 31.52 | 4.94 | 0.39 | 21.52 | 3.57 | 7.09 | 10.00 | 10.67 | 0.97 | 5.10 | 0.16 | 0.67 | ||||
25 | NY1–15 | 3 401.63 | 3.50 | 9.71 | 1.89 | 0.26 | 9.29 | 1.82 | 3.24 | 0.42 | 2.55 | 0.77 | 2.45 | 0.56 | 2.13 | ||||
26 | NY1–14 | 3 404.99 | 3.47 | 9.24 | 1.85 | 0.75 | 6.04 | 1.33 | 2.72 | 3.20 | 2.99 | 1.03 | 1.79 | 0.06 | 0.21 | ||||
27 | NY1–11 | 3 434.83 | 6.31 | 16.54 | 5.37 | 0.53 | 13.94 | 5.04 | 5.78 | 2.6 | 3.94 | 0.90 | 5.94 | 0.57 | 1.34 | ||||
28 | NY1–10 | 3 439.13 | 8.31 | 11.06 | 2.38 | 0.37 | 4.4 | 0.92 | 7.94 | 6.66 | 4.61 | 1.47 | 1.62 | 0.76 | 2.05 | ||||
29 | NY1–9 | 3 468.65 | 4.49 | 12.55 | 3.73 | 0.35 | 6.37 | 2.59 | 4.14 | 6.18 | 5.30 | 1.14 | 3.28 | 0.45 | 0.88 | ||||
30 | NY1–8 | 3 471.24 | 0.20 | 0.27 | 0.25 | 0.01 | 0.05 | 0.15 | 0.19 | 0.22 | 0.20 | 1.45 | 0.17 | 0.08 | 0.02 | ||||
31 | NY1–6 | 3 478.13 | 1.58 | 0.91 | 1.10 | 0.03 | 0.16 | 0.59 | 1.55 | 0.75 | 0.66 | 1.55 | 0.71 | 0.39 | 0.09 | ||||
32 | NY1–5 | 3 483.03 | 4.19 | 3.94 | 2.10 | 0.22 | 0.97 | 1.02 | 3.97 | 2.97 | 2.44 | 1.54 | 1.36 | 0.74 | 0.53 | ||||
平均值 | — | — | — | 3.25 | — | — | — | — | 3.98 | 3.93 | 1.1 | 3.15 | 0.34 | 0.84 |
Table 3
ΔS2, ΔS2eq and post-correction deviation for the shale samples"
江汉盆地潜江组页岩 | 渤海湾盆地沙河街组页岩 | |||||||
样品编号 | 校正前ΔS2/ (mg·g-1) | 校正后ΔS2eq/ (mg·g-1) | 相对于ΔS2的偏差/ % | 样品编号 | 校正前ΔS2/ (mg·g-1) | 校正后ΔS2eq/ (mg·g-1) | 相对于ΔS2的偏差/ % | |
1 | 3.18 | 2.67 | 16.04 | 1 | 2.96 | 2.21 | 25.45 | |
2 | 2.98 | 2.35 | 21.14 | 2 | 1.39 | 0.41 | 70.25 | |
3 | 13.55 | 12.99 | 4.13 | 3 | 9.80 | 9.53 | 2.73 | |
4 | 1.41 | 1.50 | 6.38 | 4 | 5.10 | 4.83 | 5.22 | |
5 | 5.01 | 4.57 | 8.78 | 5 | 3.23 | 2.63 | 18.73 | |
6 | 5.66 | 5.04 | 10.95 | 6 | 6.08 | 4.75 | 21.93 | |
7 | 5.37 | 5.18 | 3.54 | 7 | 7.23 | 7.91 | 9.39 | |
8 | 1.03 | 0.82 | 20.39 | 8 | 9.87 | 9.30 | 5.75 | |
9 | 5.14 | 1.58 | 69.26 | 9 | 5.92 | 6.62 | 11.83 | |
10 | 12.71 | 12.16 | 4.33 | 10 | 1.38 | 1.18 | 14.64 | |
11 | 6.89 | 5.55 | 19.45 | 11 | 2.55 | 1.82 | 28.54 | |
12 | 5.26 | 4.89 | 7.03 | 12 | 2.66 | 2.56 | 3.82 | |
13 | 8.51 | 6.71 | 21.15 | 13 | 5.54 | 5.13 | 7.43 | |
14 | 9.09 | 10.88 | 19.69 | 14 | 1.41 | 1.70 | 20.50 | |
15 | 0.82 | 1.03 | 25.61 | 15 | 1.49 | 1.13 | 23.98 | |
16 | 5.61 | 4.77 | 14.97 | 16 | 8.98 | 8.69 | 3.28 | |
17 | 4.27 | 3.50 | 18.03 | 17 | 4.58 | 4.22 | 7.88 | |
18 | 2.81 | 1.85 | 34.16 | 18 | 0.56 | 1.74 | 210.30 | |
19 | 6.35 | 6.09 | 4.09 | 19 | 5.15 | 3.68 | 28.59 | |
20 | 1.89 | 1.60 | 15.34 | 20 | 1.58 | 2.14 | 35.29 | |
21 | 2.72 | 2.60 | 4.41 | 21 | 0.34 | 0.64 | 88.48 | |
22 | 2.76 | 1.69 | 38.77 | 22 | 3.25 | 7.93 | 144.07 | |
23 | 2.17 | 1.87 | 13.82 | 23 | 3.27 | 1.52 | 53.47 | |
24 | 0.72 | 0.87 | 20.83 | 24 | 10.00 | 10.67 | 6.68 | |
25 | 8.48 | 7.10 | 16.27 | 25 | 0.42 | 2.55 | 507.53 | |
26 | 3.40 | 3.18 | 6.47 | 26 | 3.20 | 2.99 | 6.59 | |
27 | 5.87 | 4.93 | 16.01 | 27 | 2.60 | 3.94 | 51.51 | |
28 | 11.30 | 9.98 | 11.68 | 28 | 6.66 | 4.61 | 30.77 | |
29 | 8.62 | 11.77 | 36.54 | 29 | 6.18 | 5.30 | 14.22 | |
平均值 | 5.30 | 4.82 | 17.56 | 30 | 0.22 | 0.20 | 10.32 | |
31 | 0.75 | 0.66 | 11.83 | |||||
32 | 2.97 | 2.44 | 17.79 | |||||
平均值 | 3.98 | 3.93 | 46.84 |
Table 4
Rock-Eval pyrolysis results, adsorbed oil content, and correction coefficient of samples from Chang 7 shale oil layer group, Ordos Basin"
样品编号 | 全岩热解数据 | 抽提后的全岩热解数据 | 吸附油含量 | ||||||||
S1/(mg·g-1) | S2/(mg·g-1) | TOCA/% | S1EX/(mg·g-1) | S2EX/(mg·g-1) | TOCEX/% | ΔS2/(mg·g-1) | ΔS2eq/(mg·g-1) | |ΔS2-ΔS2eq | /(mg·g-1) | |||
1 | 1.56 | 1.58 | 0.85 | 0.02 | 0.59 | 0.62 | 0.99 | 0.39 | 0.60 | ||
2 | 1.75 | 8.07 | 5.89 | 0.08 | 2.41 | 2.06 | 5.66 | 5.45 | 0.21 | ||
3 | 2.02 | 12.77 | 8.73 | 0.13 | 9.61 | 7.03 | 3.16 | 8.53 | 5.37 | ||
4 | 3.62 | 6.91 | 3.56 | 0.07 | 3.16 | 3.12 | 3.75 | 3.25 | 0.50 | ||
5 | 2.70 | 7.43 | 4.82 | 0.08 | 4.17 | 4.23 | 3.26 | 4.60 | 1.34 | ||
6 | 2.26 | 7.36 | 5.77 | 0.11 | 6.60 | 6.36 | 0.76 | 5.63 | 4.87 | ||
7 | 2.28 | 8.45 | 5.86 | 0.09 | 4.80 | 4.20 | 3.65 | 5.62 | 1.97 | ||
8 | 2.20 | 7.72 | 5.33 | 0.07 | 3.96 | 3.48 | 3.76 | 5.07 | 1.31 | ||
9 | 3.23 | 38.61 | 10.98 | 0.21 | 33.08 | 10.22 | 5.53 | 10.51 | 4.98 | ||
10 | 1.17 | 2.32 | 1.44 | 0.03 | 0.91 | 1.27 | 1.41 | 1.20 | 0.21 | ||
11 | 0.81 | 1.76 | 1.42 | 0.02 | 0.80 | 1.31 | 0.96 | 1.25 | 0.29 | ||
12 | 6.77 | 64.81 | 14.17 | 0.08 | 54.81 | 13.54 | 10.00 | 13.50 | 3.50 | ||
13 | 5.48 | 44.66 | 15.30 | 0.06 | 37.46 | 14.84 | 7.20 | 14.94 | 7.74 | ||
14 | 8.14 | 80.50 | 21.72 | 0.12 | 69.00 | 20.95 | 11.50 | 21.23 | 9.73 | ||
15 | 1.07 | 8.44 | 3.86 | 0.03 | 6.95 | 3.69 | 1.49 | 3.61 | 2.12 | ||
16 | 1.22 | 5.31 | 1.92 | 0.04 | 3.38 | 1.64 | 1.93 | 1.52 | 0.41 | ||
平均值 | 2.89 | 19.17 | 6.98 | 0.08 | 15.11 | 6.16 | 4.06 | 6.64 | 2.82 |
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