广西崇左柳桥地区上二叠统礁灰岩中沥青的地球化学特征

doi:10.11743/ogg20120603

Abstract

Abstract:

Bitumen are well developed in the Upper Permian reef limestone in Liuqiao area,Chongzuo,Guangxi province,and they mainly occur in the cavities and fractures of bioherms,followed by biological coelomata.The bitumen samples show a high maturity and an atomic ratio of H/C generally less than 0.1.Based on the gas chromatography-mass spectrometry analyses of saturated hydrocarbon extracted from the bitumen in the Upper Permian as well as from the silicite and and siliceous mudstones in the Dalong Formation in the Liuqiao(Chongzuo)area,we correlated their n-alkane,terpane,hopane,sterane and biomarkers.The result shows that the possibility of the bitumen being sourced from the Dalong Formation of the Upper Permian is slime.Instead,it could come from the source rocks of the Devonian in the study area.

Key words: geochemistry, bitumen, Upper Permian, reef limestone, Dalong Formation, Liuqiao, Guangxi

CLC Number:

TE122.1

Qiu Zhen, Wang Qingchen, Jia Wanglu, Wei Hengye, Peng Pingan. Geochemical characteristics of bitumen in the Upper Permian reef limestone in Liuqiao(Chongzuo)area,Guangxi province[J]. Oil & Gas Geology, 2012, 33(6): 836-844.

References

[1] 马永生,陈洪德,王国力,等.中国南方层序地层与古地理[M].北京:科学出版社,2009:303-312,383. Ma Yongsheng,Chen Hongde,Wang Guoli,et al.Sequence and palaeogeography in South China[M].Beijing:Science Press,2009:303-312,383.
[2] 韦恒叶,陈代钊,遇昊,等.鄂西地区中二叠统栖霞组下部烃源岩形成机理[J].地质科学,2011,46(1):68-82. Wei Hengye,Chen Daizhao,Yu Hao,et al.Formation mechanism of source rocks in the lower Chihsian Formation of Middle Permian,western Hubei province[J].Chinese Journal of Geology,2011,46 (1):68-82.
[3] 王一刚,文应初,洪海涛,等.四川盆地开江-梁平海槽内发现大隆组[J].天然气工业,2006,26(9):32-36. Wang Yigang,Wen Yingchu,Hong Haitao,et al.The discovery of the Dalong Formation in Kaijiang-Liangping trough in Sichuan Basin[J].Natural Gas Industry,2006,26(9):32-36.
[4] 马永生.普光气田天然气地球化学特征及气源探讨[J].天然气地球科学,2008,19(1):1-7. Ma Yongsheng.Geochemical characteristics and origin of natural gases from Puguang gas field in Eastern Sichuan Basin[J].Natural Gas Geoscience,2008,19(1):1-7.
[5] 蔡雄飞,冯庆来,顾松竹,等.海退型陆棚相:烃源岩形成的重要部位——以中、上扬子地区北缘上二叠统大隆组为例[J].石油与天然气地质,2011,32(1):29-37. Cai Xiongfei,Fen Qinglai,Gu Songzhu,et al.Regressive continental shelf as an important location for the development of source rocks—an example from the Upper Permian Dalong Farmation in the northern margin of the Upper Middle Yangtze region[J].Oil & Gas Geology,2011,32(1):29-37.
[6] 秦建中,申宝剑,付小东,等.中国南方海相优质烃源岩超显微有机岩石学与生排烃潜力[J].石油与天然气地质,2010,31(6):826-837. Qin Jianzhong,Shen Baojian,Fu Xiaodong,et al.Ultramicroscopic organic petrology and potential of hydrocarbon generation and expulsion of quality marine source rocks in South China[J].Oil & Gas Geology,2010,31(6):826-837.
[7] 康玉柱.中国古生代海相油气资源潜力巨大[J].石油与天然气地质,2010,31(6):699-706,752. Kang Yuzhu.Great hydrocarbon potential in the Paleozoic marine sequences in China[J].Oil & Gas Geology,2010,31(6):699-706,752.
[8] 王一刚,文应初,张帆,等.川东地区上二叠统长兴组生物礁分布规律[J].天然气工业,1998,18(6):10-15. Wang Yigang,Wen Yingchu,Zhang Fan,et al.The distribution of the Changxing Formation of the Upper Permian in Eastern Sichuan[J].Natural Gas Industry,1998,18(6):10-15.
[9] 马永生,牟传龙,郭旭升,等.四川盆地东北部长兴期沉积特征与沉积格局[J].地质论评,2006,52(1):25-29. Ma Yongsheng,Mu Chuanlong,Guo Xusheng,et al.Characte-ristics and framework of the Changxingian sedimentation in the northeastern Sichuan Basin[J].Geological Review,2006,52(1):25-29.
[10] 夏明军,曾大乾,邓瑞健,等.普光气田长兴组台地边缘礁、滩沉积相及储层特征[J].天然气地球科学,2009,20(4):549-562. Xia Mingjun,Zeng Dagan,Deng Ruijian,et al.Reef and shallow facies and reservoir characteristics in Changxing Formation platform margin,Puguang gas field[J].Natural Gas Geoscien-ce,2009,20(4):549-562.
[11] 王琳,周文,何胡军.川北地区二叠系生物礁储层特征研究[J].石油地质与工程,2011,25(1): 28-31. Wang Lin,Zhou Wen,He Hujun.Study on the Permian reef reservoir features in northern Sichuan Basin[J].Petroleum Geology and Engineering,2011,25(1): 28-31.
[12] 张永贵,宋在超,周小进,等.琼东南盆地南部中新统生物礁的识别[J].石油实验地质,2011,33(3):307-309. Zhang Yonggui,Song Zaichao,Zhou Xiaojin,et al.Identification of reef in Miocene,south of Qiongdongnan Basin[J].Petroleum Geology & Experiment,2011,33(3):307-309.
[13] 冯增昭,杨玉卿,金振奎,等.中国南方二叠纪岩相古地理[J].沉积学报,1996,14(2):1-11. Feng Zengzhao,Yang Yuqing,Jin Zhenkui,et al.Lithofacies paleogeography of the Permian of South China[J].Acta Sedi-mentologica Sinica,1996,14(2):1-11.
[14] 梅冥相,马永生,邓军,等.滇黔桂盆地及邻区二叠系乐平统层序地层格架及其古地理背景[J].中国科学(D辑),2007,37(5):605-617. Mei Mingxiang,Ma Yongsheng,Deng Jun,et al.Sequece stratigraphy framework and palaeogeographical setting of the Leping of the Permian of Dian-Qian-Gui Basin and its adjacent areas[J].Science in China(Series D),2007,37(5):605-617.
[15] 赵孟军,张水昌,赵陵,等.南盘江盆地古油藏沥青地球化学特征研究[J].地质学报,2006,80(6):893-901. Zhao Mengjun,Zhang Shuichang,Zhao Ling,et al.Geochemistry and genesis of bitumen in paleo-oil reservoir in the Nanpanjiang Basin,China[J].Acta Geologica Sinica,2006,80(6):893-901.
[16] 赵孟军,赵陵,张水昌,等.南盘江盆地主要烃源岩地球化学特征研究[J].石油实验地质,2006,28(2):162-167. Zhao Mengjun,Zhao Ling,Zhang Shuichang,et al.Geochemical characteristics of main source rocks in the Nanpanjiang Basin[J].Petroleum Geology & Experiment,2006,28(2):162-167.
[17] 赵孟军,张水昌,赵陵,等.南盘江盆地古油藏沥青、天然气的地球化学特征及成因[J].中国科学(D辑),2007,37(2):167-177. Zhao Mengjun,Zhang Shuichang,Zhao Ling,et al.Geochemistry and genesis of bitumen and gas in paleo-oil reservoir in the Nanpanjiang Basin,China[J].Science in China(Series D),2007,37(2):167-177.
[18] 冯庆来,蒙有言,何卫红,等.广西柳桥地区上二叠统礁灰岩中发现沥青[J].地球科学——中国地质大学学报,2007,32(6):868-870. Feng Qinglai,Meng Youyan,He Weihong,et al.Discovery of asphalt in the Upper Permian reef limestone in Liuqiao,Guang-xi[J].Earth Science—Journal of China University of Geoscien-ces,2007,32(6):868-870.
[19] 邱振,王清晨.桂西地区上二叠统硅质岩地球化学特征及对本区烃源岩发育潜力的指示意义[J].地质科学,2011,46(1):52-67. Qiu Zhen,Wang Qingchen.Geochemistry of the Upper Permian chert in the western Guangxi and its impact on forming hydrocarbon source rock[J].Chinese Journal of Geolgoy,2011,46(1):52-67.
[20] Huc A Y,Nederlof P,Debarre R,et al.Pyrobitumen occurrences and formation in a Cambro-Ordovician sandstone reservoir,Fahud Salt Basin,North Oman[J].Chemical Geology,2000,168(1-2):99-112.
[21] 高志农,胡华中.高压对天然沥青结构组成演变的影响[J].沉积学报,2002,20(3):499-503. Gao Zhizhong,Hu Huazhong.The influence of high pressure on the structural and compositional evolution of natural bitumen[J].Acta Sedimentologica Sinica,2002,20(3):499-503.
[22] 刘德汉,史继扬.高演化碳酸盐烃源岩非常规评价方法探讨[J].石油勘探与开发,1994,21(3) :113-115. Liu Dehan,Shi Jiyang.Discussion on non-conventional assessment methods of high evalution carbonate source rocks[J].Petroleum Exploration and Development,1994,21(3):113-115.
[23] 梁狄刚,陈建平.中国南方高、过成熟区海相油源对比问题[J].石油勘探与开发,2005,32(2):8-14. Liang Digang,Chen Jianping.Oil-source correlation for high and over matured marine source rocks in South China[J].Petroleum Exploration and Development,2005,32(2):8-14.
[24] 韦宝东.桂中坳陷泥盆系烃源岩特征[J].南方油气,2004,17(2):19-21. Wei Baodong.Features of hydrocarbon source rocks of Devonian in Guizhong Depression[J].Southern China Oil & Gas,2004,17(2):19-21.
[25] 贺训云,姚根顺,贺晓苏,等.桂中坳陷桂中1井沥青成因及油气成藏模式[J].石油学报,2010,31(3):420-425. He Xunyun,Yao Genshun,He Xiaosu,et al.Bitumen genesis and hydrocarbon accumulation pattern of Well Guizhong-1 in Guizhong Depression[J].Acta Petrolei Sinica,2010,31(3):420-425.
[26] 陈子炓,姚根顺,郭庆新,等.桂中坳陷海相地层油气成藏与热作用改造[J].海相油气地质,2010,15(3):1-10. Chen Ziliao,Yao Genshun,Guo Qingxin,et al.Hydrocarbon accumulation and thermal reconstruction of Neopaleozoic marine strata in Guizhong Depression[J].Marine Origin Petroleum Geology,2010,15(3):1-10.

Geochemical characteristics of bitumen in the Upper Permian reef limestone in Liuqiao(Chongzuo)area,Guangxi province

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

[1]	Chenglin LIU, Zhengang DING, Liyong FAN, Rui KANG, Sijie HONG, Yuxin ZHU, Jianfa CHEN, Haidong WANG, Nuo XU. Geochemical characteristics and enrichment factors of helium-bearing natural gas in the Ordos Basin [J]. Oil & Gas Geology, 2024, 45(2): 384-392.
[2]	Jiakai HOU, Zhiyao ZHANG, Shengbao SHI, Guangyou ZHU. Advances in the application of comprehensive two-dimensional gas chromatography in petroleum geochemistry [J]. Oil & Gas Geology, 2024, 45(2): 565-580.
[3]	Qingyong LUO, Ningning ZHONG, Meijun LI, Jin WU, Imran Khan, Ye ZHANG, Qing CHEN, Xiangzhong YE, Wenhao LI, Wenming JI, Anji LIU, Jingyue HAO, Lipeng YAO, Jia WU. Classification， origins， and evolution of macerals in the Precambrian-Eopaleozoic sedimentary rocks [J]. Oil & Gas Geology, 2023, 44(5): 1084-1101.
[4]	Dongjun FENG. Sweet spot assessment and its significance for the marine-continental transitional shale gas of Permian Longtan Fm. in southeastern Sichuan Basin [J]. Oil & Gas Geology, 2023, 44(3): 778-788.
[5]	Huiyuan XU, Quanyou LIU, Dongya ZHU, Qingqiang MENG, Zhijun JIN. Geochemical characteristics of crude oils under alteration of deep Pb-Zn-bearing hydrothermal fluids [J]. Oil & Gas Geology, 2023, 44(1): 178-185.
[6]	Jianghui Meng, Peixi Lyu, Wei Wu, Renfang Pan, Yiqing Zhu. A method for evaluating the thermal maturity of marine shale based on graptolite reflectance and Raman spectroscopy： A case from the Lower Palaeozoic Wufeng‒Longmaxi Formations， southern Sichuan Basin， SW China [J]. Oil & Gas Geology, 2022, 43(6): 1515-1528.
[7]	Pengwei Wang, Zhongbao Liu, Xiong Li, Haotian Liu, Lin Zhou, Xiong Xiao, Ruyue Wang, Peng Li. Development of the Upper Permian Wujiaping shale in Hongxing area， eastern Sichuan Basin， and its significance to shale gas enrichment [J]. Oil & Gas Geology, 2022, 43(5): 1102-1114.
[8]	Fang Xiang, Qian Xiao, Xiantao Yu, Hengxu Huang, Xiang Zhu. Reservoir characteristics of the Upper Permian marine tuffaceous deposits in Yuanba area， Sichuan Basin [J]. Oil & Gas Geology, 2022, 43(4): 889-901.
[9]	Xingang Zhang, Hong Pang, Xiongqi Pang, Junqing Cheng, Song Wu, Kuiyou Ma, Siyu Zhang. Hydrocarbon generation and expulsion characteristics and resource potential of source rocks in the Longtan Formation of Upper Permian， Sichuan Basin [J]. Oil & Gas Geology, 2022, 43(3): 621-632.
[10]	Bojiang Fan, Liang Shi, Jie Yang, Shan Su, Rong Ma, Yaoli Yuan, Cengyu Zeng. Sedimentary environment of lacustrine organic matter in the central Ordos Basin [J]. Oil & Gas Geology, 2022, 43(3): 648-657.
[11]	Xiaoqi Wu, Yingbin Chen, Changbo Zhai, Lingfang Zhou, Xiaojin Zhou, Jun Yang, Yanqing Wang, Xiaobo Song. Geochemical characteristics of bitumen and tracing of gas source in the Middle Triassic Leikoupo Formation， Western Sichuan Depression [J]. Oil & Gas Geology, 2022, 43(2): 407-418.
[12]	Chunquan Li, Honghan Chen, Xuewei Xiao, Zecheng Wang, Hua Jiang. Raman spectroscopy of bitumen from the Sinian Dengying Formation reservoirs， Gaoshiti-Moxi area， central Sichuan Basin [J]. Oil & Gas Geology, 2022, 43(2): 456-466.
[13]	Meijun Li, Xiaoqiang Liu, Qiuya Han, Hong Xiao, Ronghui Fang, Daxiang He, Zhiwei Gao. Progress of molecular simulation application research in petroleum geochemistry [J]. Oil & Gas Geology, 2021, 42(4): 919-930.
[14]	Yixiong Qian, Chenglin Chu, Yuejun Li, Qingzhen Zhang, Wangpeng Li, Xin Yang. Characteristics, enviornment and geological dating of primary dolomite in the Neoproterozoic Pingwagou Formation at Hongliugou, Ruoqiang County, Xinjiang [J]. Oil & Gas Geology, 2021, 42(3): 570-586.
[15]	Xiaohui Jin, Juntao Zhang, Dongsheng Sun, Qiang Ding, Jiaqi Yang. Discovery and significance of the Ordovician paleo-karst caves in shallow drilling in the southern Ordos Basin [J]. Oil & Gas Geology, 2021, 42(3): 595-603.