Oil & Gas Geology ›› 2016, Vol. 37 ›› Issue (4): 538-545.doi: 10.11743/ogg20160410

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Correction of light and heavy hydrocarbon loss for residual hydrocarbon S1 and its significance to assessing resource potential of E2s4(2) member in Damintun Sag, Bohai Bay Basin

Li Jinbu1, Lu Shuangfang1, Chen Guohui1, Shan Junfeng2, Hu Yingjie2, Mao Junli2, Xue Haitao1, Wang Min1   

  1. 1. Research Institute of Unconventional Petroleum and Renewable Energy(RIUP & RE), China University of Petroleum(East China), Qingdao, Shandong 266580, China;
    2. PetroChina Exploration and Development Institute of Liaohe Oilfield, Panjin, Liaoning 124010, China
  • Received:2014-09-01 Revised:2016-07-26 Online:2016-08-08 Published:2016-09-06

Abstract: Free hydrocarbon content(S1)is a frequently-used pyrolytic parameter in assessment of shale oil resource.However,light and heavy hydrocarbon losing during the process often yields result on the low side.For heavy hydrocarbon loss,we compared pyrolysed hydrocarbon content(S2)obtained through pyrolytic experiment before and after extraction of samples to estimate the lost heavy hydrocarbon of S1.For light hydrocarbon loss,we carried out Rock-Eval and PY-GC experiments on immature shale samples and gold tube experiment on crude samples to calculate the ratio of C6-13/C13+ in different stages of maturity according to chemical dynamic theory and Easy Ro model,then took this ratio as the ratio of residual C6-13/C13+ in shale,and finally performed correction of light hydrocarbon lose based on S1 obtained after heavy hydrocarbon correction.Using the corrected parameter in assessment of shale oil resource made a great difference.Taking the E2s4(2) member in Damintun Sag,Bohai Bay Basin as an example,the result is only 22.6 billion tons without correction but 2.86 times higher (64.7 billion tons) after the corrected parameter was used.It is therefore suggested that correction of light and heavy hydrocarbon loss for residual hydrocarbon S1 during assessment of shale oil resources is necessary.

Key words: free hydrocarbon content(S1), light and heavy hydrocarbon correction, shale oil, resource assessment, Damintun Sag, Bohai Bay Basin

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