页岩等温吸附曲线SLD-PR模拟方法及应用

doi:10.11743/ogg20150121

石油与天然气地质 ›› 2015, Vol. 36 ›› Issue (1): 162-167.doi: 10.11743/ogg20150121

页岩等温吸附曲线SLD-PR模拟方法及应用

胡志明^1,2, 郭为², 熊伟^1,2, 左罗^1,2, 沈瑞^1,2, 高树生^1,2, 杨发荣³, 苗雪⁴

1. 中国科学院渗流流体力学研究所, 河北廊坊 065007;
2. 中国石油勘探开发研究院廊坊分院, 河北廊坊 065007;
3. 中国石油大港油田研究院, 天津 300280;
4. 中国石油华北油田分公司勘探开发研究院, 河北任丘 062550

收稿日期:2014-01-22 修回日期:2014-10-20 出版日期:2015-02-08 发布日期:2015-02-11
作者简介:胡志明(1977-), 男, 工程师, 油气田开发.E-mail:huzhiming69@petrochina.com.cn
基金资助:
国家科技重大专项(2011ZX05018-005);国家重点基础研究发展计划("973"计划)项目(2013CB228005).

SLD-PR simulation method for shale adsorption isotherm and its application

Hu Zhiming^1,2, Guo Wei², Xiong Wei^1,2, Zuo Luo^1,2, Shen Rui^1,2, Gao Shusheng^1,2, Yang Farong³, Miao Xue⁴

1. Institute of Porous Flow & Fluid Mechanics, Chinese Academy of Sciences, Langfang, Hebei 065007, China;
2. Research Institute of Petroleum Exploration & Development-Langfang, PetroChina Langfang, Hebei 065007, China;
3. Exploration & Development Research Institute, Dagang Oilfield Company, PetroChina, Tianjin 300280, China;
4. Exploration and Development Institute, Huabei Oilfield Company, PetroChina, Renqiu, Hebei 062550, China

Received:2014-01-22 Revised:2014-10-20 Online:2015-02-08 Published:2015-02-11
Contact: 郭为(1986-)男, 工程师, 非常规天然气开发.E-mail:guowei19860429@163.com E-mail:guowei19860429@163.com

摘要/Abstract

摘要：

页岩气主要由吸附气和游离气组成，吸附气体的含量直接影响页岩气藏的地质储量和页岩气井的产量。为了准确得到页岩的吸附气含量，以川南地区龙马溪组页岩为研究对象，设计了实验测量了温度在25～45 ℃，压力在0～8 MPa范围内页岩吸附甲烷的等温吸附曲线，发现页岩的吸附气量随着温度的升高而减少。通过简化局部密度函数（SLD-PR）理论计算了不同温度下页岩的等温吸附曲线并且与实验结果作对比，结果表明该方法可以用来计算页岩等温吸附曲线。利用SLD-PR方法预测了页岩气藏储层温度和压力条件下等温吸附曲线，弥补了高温高压下实验测量页岩等温吸附曲线误差大的不足。同时对比了利用SLD-PR方法和Langmuir方法计算的吸附气量，发现利用Langmuir方程计算得到的吸附气含量偏大，利用SLD-PR方法计算得到的页岩吸附气含量更加可靠。

关键词: 甲烷, 简化局部密度函数法(SLD), 等温吸附, 页岩气

Abstract:

Shale gas is mainly composed of adsorption gas and free gas.Adsorption gas content directly affects the geolo-gical reserves and well production for a shale gas reservoir.In order to accurately measure adsorption gas content, isothermal adsorption experiments were performed within temperature range of 25-45 ℃ and pressure range of 0-8 MPa on the Longmaxi Fm shale in South Sichuan Basin.Results indicate that shale adsorption capacity decreases as temperature increases.In addition, shale adsorption isotherms at different temperatures were calculated by using the simplified local density (SLD-PR) method and compared with the experimental results.The comparison shows that this method can be used to calculate shale adsorption isotherm.The SLD-PR method can be used to predict shale adsorption isotherm under reservoir pressure and temperature conditions, thus overcoming the disadvantage that the errors of isotherm experimental measurements under high temperature and pressure are large.Comparison between the calculated adsorption gas content by the SLD-PR method and that by the Langmuir method indicates that the former is more accurate and reliable than the latter.

Key words: methane, the simplified local density method(SLD), isothermal adsorption, shale gas

中图分类号:

TE132.2

胡志明,郭为,熊伟,等. 页岩等温吸附曲线SLD-PR模拟方法及应用[J]. 石油与天然气地质, 2015, 36(1): 162-167. doi: 10.11743/ogg20150121 Hu Zhiming,Guo Wei,Xiong Wei,et al. SLD-PR simulation method for shale adsorption isotherm and its application[J]. Oil & Gas Geology, 2015, 36(1): 162-167. doi: 10.11743/ogg20150121

参考文献

[1] 张大伟.加快中国页岩气勘探开发和利用的主要路径[J].天然气工业,2011,31(5):1-5. Zhang Dawei.Main solution ways to speed up shale gas exploration and development in China[J].Natural gas industry,2011,31(5):1-5.
[2] 于荣泽,卞亚南,齐亚东,等.页岩气藏数值模拟研究现状[J].石油与天然气地质,2014,35(1):131-137. Yu Rongze,Bian Yanan,Qi Yadong,et al.A review of numerical simulation of shale gas reservoirs[J].Oil & Gas Geology,2014,35(1):131-137.
[3] 涂乙,邹海燕,孟海平,等.页岩气评价标准与储层分类[J].石油与天然气地质,2014,35(1):153-157. Tu Yi,Zou Haiyan,Meng Haiping,et al.Evaluation criteria and classification of shale gas reservoirs[J].Oil & Gas Geology,2014,35(1):153-157.
[4] Hill R J,Zhang E T,Katz B J,et al.Modeling of gas generation from the Barnett shale,Fort Worth Basin,Texas[J].AAPG Bulletin,2007,91 (4):501-521.
[5] Ross D J,Bustin R M.Characterizing the shale gas resource potential of Devonian-Mississippian strata in the Western Canada sedimentary basin:Application of an integrated formation evaluation[J].AAPG Bulletin,2008,92 (1):87-95.
[6] Javadpour F,Fisher D,Unsworth M.Nanoscale gas flow in shale gas sediments[J]Journal of Canadian Petroleum Techno,2007,46(10):55-61.
[7] Schettler Jr P D,Parmely C R.Contributions to total storage capacity in devonian shales[C]//SPE Eastern Regional Meeting.Society of Petroleum Engineers,1991.
[8] Lu X C,Li F C,Watson A T.Adsorption studies of natural gas storage in Devonian shales[J].SPE Formation Evaluation,1995,10(2):109-113.
[9] Lu X C,Li F C,Watson A T.Adsorption measurements in Devonian shales[J].Fuel,1995,74(4):599-603.
[10] 熊伟,郭为,刘洪林,等.页岩的储层特征以及等温吸附特征[J].天然气工业,2012,32(1):113-116. Xiong Wei,Guo Wei,Liu Honglin et al.Shale reservoir characteristics and isothermal adsorption properties[J].Natural Gas Industry,2012,32(1):113-116.
[11] 郭为,熊伟,高树生,等.温度对页岩等温吸附/解吸特征影响研究[J].石油勘探与开发,2013,40 (4):481-485. Guo Wei,Xiong Wei,Gao Shusheng,et al.Impact of temperature on the isothermal adsorption/desorption characteristics of shale gas[J].Petroleum Exploration and Development,2013,40(4):481-485.
[12] Fitzgerald J E,Sudibandriyo M,Pan Z,et al.Modeling the adsorption of pure gases on coals with the SLD model[J].Carbon,2003,41(12):2203-2216.
[13] Elliott J R,Suresh S J,Donohue M D.A simple equation of state for nonspherical and associating molecules[J].Industiral & Engineering Chemistry Research,1990,29(7):1476-1485.
[14] Yan B,Yang X.Adsorption prediction for three binary supercritical gas mixtures on activated carbon based on a NDFT/PSD approach[J].Chemical Engineering Science,2005,60(12):3267-3277.
[15] Keith M,He J,Liu Y,et al.Molecular simulation of methane adsorption in micro-and mesoporous carbons with applications to coal and gas shale systems[J].International Journal of Coal Geology,2013,109(4):36-44.
[16] Bharath R,Carl T,Ramkumar S.Simplified local density model for adsorption-over large pressure ranges[J].AIChE Journal,1995,41(4):838-845.
[17] Soule A D,Smith C A,Yang X,et al.Adsorption modeling with the ESD equation of state[J].Langmuir,2001,17(10):2950-2957.
[18] Yang X,Lira C T.Modeling of adsorption on porous activated carbons using SLD-ESD model with a pore size distribution[J].Chemical engineering Journal,2012,195(7)-196:314-322.
[19] Fitzgerald J E.Adsorption of pure and multi-component gases of importance to enhanced coalbed methane recovery:measurements and simplified local density modeling[D].Oklahoma:Oklahoma State University,2005.
[20] Chareonsuppanit M P,mohammad S A,Robert L,et al.High-pressure adsorption of gases on shales:Measurements and modeling[J].International Journal of coal geology,2012,95:34-46.
[21] Gasem,K M,Gao W,Pan Z,et al.A modified temperature dependence for the Peng-Robinson equation of state[J].Fluid Phase Equilibria,2001,181(1):113–125.
[22] McCarty R C.Thermophysical properties of helium-4 from 2 to 1500 K with pressures to 1000 atmospheres[C].US.Nation,Bureau Stand.I,1972.
[23] Lee L L.Molecular Thermodynamics of non-ideal fluids[M].Boston:Butterworths,1988.
[24] Robinson D B,Peng D Y,Chung S Y.The development of the Peng-Robinson equation and its application to phase equilibrium in a system containing methanol[J].Fluid phase equlibria 1975,24(1-2):25-41.
[25] Meysam H,Farzad A,Farzaneh F.Simplified local density model for adsorption of pure gases on activated carbon using Sutherland and Kihara potentials[J].Microporous and Mesoporous Materials,2010,136(1):1-9.
[26] Chen J H,Wong D S,Tan C S,et al.Adsorption and desorption of carbon dioxide onto and from activated carbon at high pressures[J].Industrial and Engineering Chemistry Research,1997,36(7):2808-2815.
[27] Nasehzadeh A,Mohseni M,Azaza K.The Effect of Temperature on the Lennard-Jones (6-12) pair potential[J].Molecular Structure,2002,589-590:329-335.
[28] Ambrose R J,Hartman R C,Diaz-Campos M,et al.Shale gas-in-place calculations Part I:New pore-scale considerations[J].SPE Journal,2012,17(1):219-229.
[29] 林腊梅,张金川,韩双彪,等.泥页岩储层等温吸附测试异常探讨[J].油气地质与采收率,2012,19(6):30-32,41. Lin Lamei,Zhang Jinchuan,Han Shuangbiao,et al.Study on abnormal curves of isothermal adsorption of shale[J].Petroleum Geology and Recovery Efficiency,2012,19(6):30-32,41.
[30] 李艳丽.页岩气储量计算方法探讨[J].天然气地球科学,2009,20(3):476-470. Li Yanli.Calculation methods of shale gas reserves[J].Natural Gas Geoscience,2009,20(3):476-470.

页岩等温吸附曲线SLD-PR模拟方法及应用

SLD-PR simulation method for shale adsorption isotherm and its application

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