石油与天然气地质 ›› 1984, Vol. 5 ›› Issue (2): 113-121.doi: 10.11743/ogg19840204

• 论文 • 上一篇    下一篇

干酪根的沥青降解潜力

杨文宽   

  1. 地质矿产部石油地质综合大队
  • 收稿日期:1983-09-19 出版日期:1984-06-25 发布日期:2012-01-16

BITUMEN GENERATION POTENTIAL OF KEROGEN

Yang Wenkuan   

  1. Comprehensive Research Institute of Petroleum Geology, Ministry of Geology and Mineral Resources
  • Received:1983-09-19 Online:1984-06-25 Published:2012-01-16

摘要:

本文所说的"沥青降解潜力"Pb,指的是干酪根生成沥青的极限能力。它是一个没有量纲的量,可用百分数或毫克/克表示之。对于酪根热降解过程的数学模拟来说,沥青降解潜力是一项基本参数。如果人工热解干酪根的实验装置允许沥青从干酪根中释放出来之后立即被收集起来而不会进一步演化,那么,从开始降解到彻底降解这一全过程中干酪根样品陆续释放出来的沥青的总重量同干酪根样品初始重量之比,就是这一样品的沥青降解潜力。

Abstract:

Methods for estimating the bitumen and the methane generation potentials of kerogen are proposed in this paper.The problem of estimating the initial abundance of kerogen according to the abundance value of organic carbon is also discussed.It is worth noting that,in these methods,not only the changes of atomic ratio of kerogen have taken into account,but also the TGA weight loss of kerogen has considered.The bitumen generation potential means the maximum capacity of kerogento yield liquid bitumen plus gaseous hydrocarbon.As for the types Ⅰ,Ⅱ,andⅢ of kerogen being at the threshold of petroleum generation,their bitumen ge-neration potentials are about 61%,43% and 6% respectively.The methane generation potential means the weight ratio of the methane versus the initial kerogen generated after complete degradation of the latter,with res-pect to the types Ⅰ,Ⅱ and Ⅲ of kerogen being at the threshold of petroleum generation,the methane generation potentials are respectively about 35%,25% and 6%.For a close system of petroleum generation,after complete degradation of kerogen,residual solid carbon abundance being multified by factors of 1.42,1.30 and 1.09 may correspond respectively to the carbon abundance of the kerogen types of Ⅰ,Ⅱ and Ⅲ being at the threshold of petroleum generation. While for a open system,factors to be multified are 2.66,1.83 and 1.10 res-pectively.