木里冻土带天然气水合物赋存区浅层土壤地球化学特征及指示意义

doi:10.11743/ogg20140121

石油与天然气地质 ›› 2014, Vol. 35 ›› Issue (1): 159-166.doi: 10.11743/ogg20140121

• 技术方法 • 上一篇

木里冻土带天然气水合物赋存区浅层土壤地球化学特征及指示意义

邢学文¹, 刘松¹, 周红英¹, 邹立群¹, 李广之², 高伟²

1. 中国石油勘探开发研究院, 北京 100083;
2. 中国石化集团资产经营管理有限公司合肥培训测试中心, 安徽合肥 230022

收稿日期:2012-09-03 修回日期:2014-01-10 出版日期:2014-02-08 发布日期:2014-03-26
第一作者简介:邢学文（1976—），男，博士、高级工程师，遥感。E-mail：x5505@163.com。
基金项目:
国家科技重大专项（2011ZX05020-008）。

Geochemical behaviors of shallow soil in Muli permafrost and their significance as gas hydrate indicators

Xing Xuewen¹, Liu Song¹, Zhou Hongying¹, Zou Liqun¹, Li Guangzhi², Gao Wei²

1. PetroChina Research Institute of Petroleum Exploration and Development, Beijing 100083, China;
2. Hefei Training and Testing Center of Assets Management Ltd. of China Petrochemical Corporation, Hefei, Anhui 230022, China

Received:2012-09-03 Revised:2014-01-10 Online:2014-02-08 Published:2014-03-26

摘要/Abstract

摘要： 青海省祁连山木里是中国陆上唯一通过钻探发现天然气水合物样品的地区。在木里天然气水合物赋存区开展了土壤油气化探的研究工作，采用了顶空气、酸解烃和蚀变碳酸盐3种烃类检测技术，其中顶空气和酸解烃方法在木里冻土带比较有效，而蚀变碳酸盐方法相对较差。顶空气法提取的游离烃和酸解烃法提取的吸附烃显示：木里天然气水合物赋存区土壤中烃类气体组分复杂，除了主要成分甲烷外，还含有少量乙烷、丙烷、丁烷和戊烷。烃类气体既有热解成因，又有生物成因；气体类型包括油型气、煤成气和生物气。根据甲烷衬度异常图，结合研究区地质资料和发现天然气水合物的钻井资料，认为工区中东部的甲烷高异常区断裂发育，应该是天然气水合物的有利赋存区。

关键词: 永久冻土带, 土壤地球化学, 天然气水合物, 青海木里

Abstract: Muli,the only gas hydrate hosting area in China proved by core sampling,is located in Qilian Mountain permafrost area.Petroleum geochemical exploration was carried out with three hydrocarbon detection techniques(HS,acidolysis hydrocarbon and altered carbonate survey methods)in the area.The results show that the former two methods are more effective than the latter one.Analysis of free hydrocarbons extracted through HS and absorbed hydrocarbons from acidolysis indicates that the components of hydrocarbon gas in soil of areas containing gas hydrate in Muli are complex.In addition to the major component of methane,there are also small amount of ethane,propane,butane and pentane.There are both hydrocarbon gas of pyrolytic origin and that of microbiogenic genesis.The hydrocarbon gas can be classified as oil-prone gas,coal-drived gas and biogas.Methane contrast diagram in combination with the geologic background and core samples in wells discovering gas hydrate reveal that its eastern-central part with well-developed faults and high methane anomaly may be a favorable target for gas hydrate exploration.

Key words: permafrost, soil geochemistry, gas hydrate, Muli area in Qinhai province

中图分类号:

TE122.1

邢学文,刘松,周红英,等. 木里冻土带天然气水合物赋存区浅层土壤地球化学特征及指示意义[J]. 石油与天然气地质, 2014, 35(1): 159-166. doi: 10.11743/ogg20140121 Xing Xuewen,Liu Song,Zhou Hongying,et al. Geochemical behaviors of shallow soil in Muli permafrost and their significance as gas hydrate indicators[J]. Oil & Gas Geology, 2014, 35(1): 159-166. doi: 10.11743/ogg20140121

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木里冻土带天然气水合物赋存区浅层土壤地球化学特征及指示意义

Geochemical behaviors of shallow soil in Muli permafrost and their significance as gas hydrate indicators

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