生物标志化合物热成熟度参数演化规律及意义——以Ⅲ型烃源岩HTHP生排烃热模拟液态烃产物为例

doi:10.11743/ogg20150406

石油与天然气地质 ›› 2015, Vol. 36 ›› Issue (4): 573-580.doi: 10.11743/ogg20150406

生物标志化合物热成熟度参数演化规律及意义——以Ⅲ型烃源岩HTHP生排烃热模拟液态烃产物为例

孙丽娜^1,2, 张中宁¹, 吴远东^1,2, 苏龙¹, 夏燕青¹, 王自翔^1,2, 郑有伟^1,2

1. 甘肃省油气资源研究重点实验室/中国科学院油气资源研究重点实验室, 甘肃兰州 730000;
2. 中国科学院大学, 北京 100049

收稿日期:2014-09-26 修回日期:2015-06-20 出版日期:2015-08-08 发布日期:2015-08-28
第一作者简介:孙丽娜(1989—),女,博士生,石油与天然气地球化学。E-mail:slina1029@163.com。
基金项目:
国家科技重大专项(2011ZX05008-002-23);中国科学院“西部之光”人才培养计划项目(Y404RC1)。

Evolution patterns and their significances of biomarker maturity parameters—a case study on liquid hydrocarbons from type Ⅲ source rock under HTHP hydrous pyrolysis

Sun Lina^1,2, Zhang Zhongning¹, Wu Yuandong^1,2, Su Long¹, Xia Yanqing¹, Wang Zixiang^1,2, Zheng Youwei^1,2

1. Key Laboratory of Petroleum Resources, Gansu Province/Key Laboratory of Petroleum Resources Research, Institute of Geology and Geophysics, Chinese Academy of Sciences, Lanzhou, Gansu 730000, China;
2. University of Chinese Academy of Sciences, Beijing 100049, China

Received:2014-09-26 Revised:2015-06-20 Online:2015-08-08 Published:2015-08-28
Contact: 张中宁(1964—),男,副研究员,油气地球化学。E-mail:ldlab@ns.lzb.ac.cn。 E-mail:ldlab@ns.lzb.ac.cn

摘要/Abstract

摘要：

为了探究烃源岩不同热演化阶段生物标志化合物成熟度参数的演化规律及其专属指示意义。通过对辽河盆地桃10井Ⅲ型烃源岩进行HTHP生排烃热模拟实验，获取的液态烃产物饱和烃组分进行GC/MS分析，以模拟温度为成熟度标尺，检测出正构烷烃、类异戊二烯类烷烃、三环二萜烷、藿烷及甾烷系列中对热成熟度演化具有一定指示意义的生物标志化合物，并计算出参数指标。依据不同生物标志化合物对热作用的敏感程度不同，利用不同热敏感性的生标化合物比值指示热演化阶段。结果发现，随着模拟温度的升高，藿烷会受热作用影响形成三环萜烷，Tm会转化为Ts，20R型生物型异构体会向20S型地质异构体转化，所以∑三环萜烷／∑藿烷、Ts/Tm和C₃₁-藿烷22S／（22S+22R）参数对有机质热演化阶段可以起到较好的指示作用。而受热作用的差异性影响，参数C₂₄-四环萜烷／∑藿烷、C₃₀βα-莫烷／C₃₀αβ-藿烷和C₂₉-甾烷ββ／（αα+ββ）则在成熟至过成熟阶段具有更强的指示意义。由此可见，样品不同热演化阶段均有其最佳适用的生标参数组合，这为正确利用成熟度参数判识该地区烃源岩成熟度演化阶段提供了一定的理论依据。

关键词: 热成熟度参数, 热模拟, 液态烃, GC/MS分析, 生物标志化合物, 烃源岩

Abstract:

High temperature and high pressure hydrous pyrolysis experiments were conducted on type Ⅲ source rocks from Well Tao 10 in Liaohe Basin under various conditions to investigate the role of biomarker maturity parameters at different thermal evolution stages.The expelled oils collected from these experiments were separated into saturated hydrocarbons, aromatic hydrocarbons, non-hydrocarbons and asphaltene, and the saturated fractions were analyzed by GC/MS.Taking the simulation temperature as the scales of maturity, the biomarkers that are indicative of thermal maturity evolution were detected from n-alkane, isoprenoid alkane, tricyclic terpane, tetracyclic terpane, hopane and sterane, and their parameter index were also calculated.Based on the different sensitivities of different biomarkers to thermal action, the ratio of different biomarkers may reflect different thermal stages.With the simulation temperature increasing, the hopanes may be turned into tricyclic terpanes, Tm may be turned into Ts, and the configurations of isomers will be transformed from 22R to 22S, thus the ∑tricyclic terpane/∑hopane, Ts/Tm and C₃₁-hopanes 22S/(22S+22R) may be good indicators of thermal stages.But in the stage of maturity to over-maturity, the C₂₄-tetracyclic terpane/∑hopanes, C₃₀βα-moretane / C₃₀αβ-hopane and C₂₉-sterane ββ/(αα+ββ) are more suitable indicators.Therefore, samples at different thermal evolution stages have their own optimal biomarker assemblages providing a theoretical basis for determining thermal evolution stage of source rocks by using maturity parameters in the study area.

Key words: thermal maturity parameter, pyrolysis, liquid hydrocarbons, GC/MS analysis, biomarker, source rock

中图分类号:

TE122.1

孙丽娜,张中宁,吴远东,等. 生物标志化合物热成熟度参数演化规律及意义——以Ⅲ型烃源岩HTHP生排烃热模拟液态烃产物为例[J]. 石油与天然气地质, 2015, 36(4): 573-580. doi: 10.11743/ogg20150406 Sun Lina,Zhang Zhongning,Wu Yuandong,et al. Evolution patterns and their significances of biomarker maturity parameters—a case study on liquid hydrocarbons from type Ⅲ source rock under HTHP hydrous pyrolysis[J]. Oil & Gas Geology, 2015, 36(4): 573-580. doi: 10.11743/ogg20150406

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生物标志化合物热成熟度参数演化规律及意义——以Ⅲ型烃源岩HTHP生排烃热模拟液态烃产物为例

Evolution patterns and their significances of biomarker maturity parameters—a case study on liquid hydrocarbons from type Ⅲ source rock under HTHP hydrous pyrolysis

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