石油与天然气地质 ›› 2020, Vol. 41 ›› Issue (6): 1162-1175.doi: 10.11743/ogg20200605
霍建峰1(), 高健2, 郭小文1,*(), 易积正3, 舒志国3, 包汉勇3, 杨锐1, 罗涛1, 何生1
收稿日期:
2018-06-27
出版日期:
2020-12-28
发布日期:
2020-12-09
通讯作者:
郭小文
E-mail:hhuojianfeng@126.com;guoxw@cug.edu.cn
作者简介:
霍剑锋(1994-),男,硕士研究生,页岩气研究。E-mail:基金资助:
Jianfeng Huo1(), Jian Gao2, Xiaowen Guo1,*(), Jizheng Yi3, Zhiguo Shu3, Hanyong Bao3, Rui Yang1, Tao Luo1, Sheng He1
Received:
2018-06-27
Online:
2020-12-28
Published:
2020-12-09
Contact:
Xiaowen Guo
E-mail:hhuojianfeng@126.com;guoxw@cug.edu.cn
摘要:
四川盆地川东地区是中国页岩气主要产区,目前发现的页岩气主要产自五峰-龙马溪组的富泥硅质页岩,而对富硅泥质和混合质页岩研究较少。为了确定川东地区龙马溪组富硅泥质和混合质页岩的孔隙发育特征,在对龙马溪组页岩岩相划分的基础之上,通过二氧化碳吸附,氮气吸附,高压压汞以及孔隙度测定,X-衍射,场发射扫描电子显微镜(FE-SEM)等实验手段,对比不同岩相页岩孔隙结构特征,研究不同岩相页岩孔隙结构的主控因素。研究结果表明:①川东地区富有机质页岩可划分为富硅泥质页岩相、硅/泥混合页岩相和富泥硅质页岩相,不同岩相页岩孔隙度范围在2.62%~5.65%;②页岩储层中孔隙体积以介孔为主,大约占总孔隙的50%~60%,其次是微孔和宏孔,大约占总孔隙的15%~20%,比表面积主要贡献来自微孔和介孔,分别占总比表面积的70%和30%;③龙马溪组页岩孔隙发育主要受有机质丰度的控制,粘土矿物含量不是控制页岩孔隙发育主要因素,高有机质丰度页岩可能由于骨架颗粒支撑较弱遭受更剧烈的压实作用使大部分孔隙消失;④高有机质丰度富泥质页岩和硅/泥混合页岩也具有较高的孔隙度,与大部分富泥硅质页岩具有相似的孔隙结构,表明富硅泥质页岩相和硅/泥混合页岩相页岩也能发育一定量的纳米级孔隙,可为页岩气赋存提供空间。
中图分类号:
表1
川东地区J1和J2井龙马溪组页岩孔隙参数"
井号 | 深度/m | 岩相 | TOC/% | 孔隙度/% | 二氧化碳吸附 | 氮气吸附 | |||||
微孔体积/(cc·g-1) | 微孔比表面积/(m2·g-1) | 介孔体积/(cc·g-1) | 介孔比表面积/(m2·g-1) | 宏孔体积/(cc·g-1) | 宏孔比表面积/(m2·g-1) | ||||||
J1 | 2 288.06 | M-2 | 1.64 | — | 0.003 7 | 11.49 | 0.0105 | 5.49 | 0.004 2 | 0.20 | |
J1 | 2 319.86 | CM-1 | 1.92 | 3.66 | 0.003 0 | 8.95 | 0.009 5 | 5.17 | 0.005 1 | 0.21 | |
J1 | 2 325.13 | M-2 | 3.13 | 4.05 | 0.005 5 | 17.12 | 0.013 8 | 7.79 | 0.006 1 | 0.23 | |
J1 | 2 334.95 | CM-1 | 3.16 | 5.54 | 0.005 6 | 17.75 | 0.013 3 | 7.74 | 0.004 9 | 0.18 | |
J1 | 2 338.55 | S-3 | 2.77 | 4.33 | 0.002 9 | 8.96 | 0.011 7 | 6.38 | 0.008 2 | 0.27 | |
J1 | 2 340.41 | CM-1 | 3.56 | 4.93 | 0.003 9 | 11.43 | 0.011 8 | 6.94 | 0.002 9 | 0.12 | |
J1 | 2 344.69 | S-3 | 3.81 | 4.15 | 0.005 5 | 17.08 | 0.012 7 | 7.64 | 0.004 9 | 0.18 | |
J1 | 2 349.17 | S-3 | 5.40 | 5.10 | 0.006 7 | 21.31 | 0.015 5 | 9.01 | 0.007 0 | 0.27 | |
J1 | 2 352.82 | S-3 | 4.78 | 5.65 | 0.007 2 | 22.98 | 0.015 7 | 8.97 | 0.005 5 | 0.19 | |
J1 | 2 357.04 | S-3 | 5.16 | — | 0.006 0 | 19.41 | 0.018 7 | 9.37 | 0.004 7 | 0.19 | |
J2 | 2 579.27 | S-3 | 2.56 | 3.43 | 0.004 2 | 12.86 | 0.010 8 | 5.80 | 0.007 8 | 0.29 | |
J2 | 2 585.50 | S-3 | 4.13 | 4.26 | 0.005 6 | 17.75 | 0.011 5 | 6.51 | 0.003 3 | 0.22 | |
J2 | 2 591.66 | CM-1 | 2.50 | 2.62 | 0.004 7 | 14.33 | 0.008 9 | 5.27 | 0.001 8 | 0.12 | |
J2 | 2 595.74 | M-2 | 3.13 | 4.82 | 0.005 7 | 17.59 | 0.011 2 | 5.73 | 0.003 5 | 0.19 | |
J2 | 2 598.44 | CM-1 | 3.77 | 4.26 | 0.005 9 | 18.45 | 0.011 8 | 7.18 | 0.006 6 | 0.17 | |
J2 | 2 604.45 | CM-1 | 4.00 | 4.74 | 0.005 9 | 17.97 | 0.011 3 | 6.43 | 0.004 4 | 0.23 | |
J2 | 2 606.65 | S-3 | 4.07 | — | 0.005 8 | 18.30 | 0.012 5 | 7.34 | 0.005 3 | 0.21 | |
J2 | 2 611.20 | S-3 | 4.97 | — | 0.006 5 | 19.90 | 0.013 8 | 7.79 | 0.003 0 | 0.14 | |
J2 | 2 552.10 | M-2 | 2.24 | — | 0.005 6 | 16.87 | 0.011 0 | 6.26 | 0.004 9 | 0.21 |
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