广西崇左柳桥地区上二叠统礁灰岩中沥青的地球化学特征

doi:10.11743/ogg20120603

石油与天然气地质 ›› 2012, Vol. 33 ›› Issue (6): 836-844.doi: 10.11743/ogg20120603

广西崇左柳桥地区上二叠统礁灰岩中沥青的地球化学特征

邱振^1,2, 王清晨², 贾望鲁³, 韦恒叶⁴, 彭平安³

1. 中国石油勘探开发研究院,北京 100083;
2. 中国科学院地质与地球物理研究所岩石圈演化国家重点实验室,北京100029;
3. 中国科学院广州地球化学研究所有机地球化学国家重点实验室, 广东广州 510640;
4. 东华理工大学地球科学学院,江西南昌 330013

收稿日期:2011-10-25 修回日期:2012-10-17 出版日期:2012-12-28 发布日期:2013-01-10
作者简介:邱振(1984—),男,博士后,石油地质学及油气资源评价。
基金资助:
国家科技重大专项(2011ZX05008,2011ZX05001)。

Geochemical characteristics of bitumen in the Upper Permian reef limestone in Liuqiao(Chongzuo)area,Guangxi province

Qiu Zhen^1,2, Wang Qingchen², Jia Wanglu³, Wei Hengye⁴, Peng Pingan³

1. PetroChina Research Institute of Petroleum Exploration and Development, Beijing 100083, China;
2. State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China;
3. State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, Guangdong 510640, China;
4. College of Earth Science, East China Institute of Technology, Nanchang, Jiangxi 330013, China

Received:2011-10-25 Revised:2012-10-17 Online:2012-12-28 Published:2013-01-10

摘要/Abstract

摘要：

广西崇左柳桥地区上二叠统生物礁灰岩中普遍发育沥青,沥青主要充填于生物礁内的溶蚀孔洞和裂隙中,其次在生物体腔内。研究区内上二叠统沥青的成熟度较高,H/C原子比一般小于0.1。对崇左柳桥地区上二叠统生物礁灰岩中的沥青和大隆组的硅质岩、硅质泥岩等进行饱和烃色谱-质谱分析,综合对比其所含直链烷烃、萜烷、藿烷、甾烷和生物标志物。结果表明,这些上二叠统沥青源自大隆组的可能性不大,但可能来源于泥盆系烃源岩。

关键词: 地球化学, 沥青, 上二叠统, 生物礁灰岩, 大隆组, 柳桥地区, 广西

Abstract:

Bitumen are well developed in the Upper Permian reef limestone in Liuqiao area,Chongzuo,Guangxi province,and they mainly occur in the cavities and fractures of bioherms,followed by biological coelomata.The bitumen samples show a high maturity and an atomic ratio of H/C generally less than 0.1.Based on the gas chromatography-mass spectrometry analyses of saturated hydrocarbon extracted from the bitumen in the Upper Permian as well as from the silicite and and siliceous mudstones in the Dalong Formation in the Liuqiao(Chongzuo)area,we correlated their n-alkane,terpane,hopane,sterane and biomarkers.The result shows that the possibility of the bitumen being sourced from the Dalong Formation of the Upper Permian is slime.Instead,it could come from the source rocks of the Devonian in the study area.

Key words: geochemistry, bitumen, Upper Permian, reef limestone, Dalong Formation, Liuqiao, Guangxi

中图分类号:

TE122.1

邱振,王清晨,贾望鲁,等. 广西崇左柳桥地区上二叠统礁灰岩中沥青的地球化学特征[J]. 石油与天然气地质, 2012, 33(6): 836-844. doi: 10.11743/ogg20120603 Qiu Zhen,Wang Qingchen,Jia Wanglu,et al. Geochemical characteristics of bitumen in the Upper Permian reef limestone in Liuqiao(Chongzuo)area,Guangxi province[J]. Oil & Gas Geology, 2012, 33(6): 836-844. doi: 10.11743/ogg20120603

参考文献

[1] 马永生,陈洪德,王国力,等.中国南方层序地层与古地理[M].北京:科学出版社,2009:303-312,383. Ma Yongsheng,Chen Hongde,Wang Guoli,et al.Sequence and palaeogeography in South China[M].Beijing:Science Press,2009:303-312,383.
[2] 韦恒叶,陈代钊,遇昊,等.鄂西地区中二叠统栖霞组下部烃源岩形成机理[J].地质科学,2011,46(1):68-82. Wei Hengye,Chen Daizhao,Yu Hao,et al.Formation mechanism of source rocks in the lower Chihsian Formation of Middle Permian,western Hubei province[J].Chinese Journal of Geology,2011,46 (1):68-82.
[3] 王一刚,文应初,洪海涛,等.四川盆地开江-梁平海槽内发现大隆组[J].天然气工业,2006,26(9):32-36. Wang Yigang,Wen Yingchu,Hong Haitao,et al.The discovery of the Dalong Formation in Kaijiang-Liangping trough in Sichuan Basin[J].Natural Gas Industry,2006,26(9):32-36.
[4] 马永生.普光气田天然气地球化学特征及气源探讨[J].天然气地球科学,2008,19(1):1-7. Ma Yongsheng.Geochemical characteristics and origin of natural gases from Puguang gas field in Eastern Sichuan Basin[J].Natural Gas Geoscience,2008,19(1):1-7.
[5] 蔡雄飞,冯庆来,顾松竹,等.海退型陆棚相:烃源岩形成的重要部位——以中、上扬子地区北缘上二叠统大隆组为例[J].石油与天然气地质,2011,32(1):29-37. Cai Xiongfei,Fen Qinglai,Gu Songzhu,et al.Regressive continental shelf as an important location for the development of source rocks—an example from the Upper Permian Dalong Farmation in the northern margin of the Upper Middle Yangtze region[J].Oil & Gas Geology,2011,32(1):29-37.
[6] 秦建中,申宝剑,付小东,等.中国南方海相优质烃源岩超显微有机岩石学与生排烃潜力[J].石油与天然气地质,2010,31(6):826-837. Qin Jianzhong,Shen Baojian,Fu Xiaodong,et al.Ultramicroscopic organic petrology and potential of hydrocarbon generation and expulsion of quality marine source rocks in South China[J].Oil & Gas Geology,2010,31(6):826-837.
[7] 康玉柱.中国古生代海相油气资源潜力巨大[J].石油与天然气地质,2010,31(6):699-706,752. Kang Yuzhu.Great hydrocarbon potential in the Paleozoic marine sequences in China[J].Oil & Gas Geology,2010,31(6):699-706,752.
[8] 王一刚,文应初,张帆,等.川东地区上二叠统长兴组生物礁分布规律[J].天然气工业,1998,18(6):10-15. Wang Yigang,Wen Yingchu,Zhang Fan,et al.The distribution of the Changxing Formation of the Upper Permian in Eastern Sichuan[J].Natural Gas Industry,1998,18(6):10-15.
[9] 马永生,牟传龙,郭旭升,等.四川盆地东北部长兴期沉积特征与沉积格局[J].地质论评,2006,52(1):25-29. Ma Yongsheng,Mu Chuanlong,Guo Xusheng,et al.Characte-ristics and framework of the Changxingian sedimentation in the northeastern Sichuan Basin[J].Geological Review,2006,52(1):25-29.
[10] 夏明军,曾大乾,邓瑞健,等.普光气田长兴组台地边缘礁、滩沉积相及储层特征[J].天然气地球科学,2009,20(4):549-562. Xia Mingjun,Zeng Dagan,Deng Ruijian,et al.Reef and shallow facies and reservoir characteristics in Changxing Formation platform margin,Puguang gas field[J].Natural Gas Geoscien-ce,2009,20(4):549-562.
[11] 王琳,周文,何胡军.川北地区二叠系生物礁储层特征研究[J].石油地质与工程,2011,25(1): 28-31. Wang Lin,Zhou Wen,He Hujun.Study on the Permian reef reservoir features in northern Sichuan Basin[J].Petroleum Geology and Engineering,2011,25(1): 28-31.
[12] 张永贵,宋在超,周小进,等.琼东南盆地南部中新统生物礁的识别[J].石油实验地质,2011,33(3):307-309. Zhang Yonggui,Song Zaichao,Zhou Xiaojin,et al.Identification of reef in Miocene,south of Qiongdongnan Basin[J].Petroleum Geology & Experiment,2011,33(3):307-309.
[13] 冯增昭,杨玉卿,金振奎,等.中国南方二叠纪岩相古地理[J].沉积学报,1996,14(2):1-11. Feng Zengzhao,Yang Yuqing,Jin Zhenkui,et al.Lithofacies paleogeography of the Permian of South China[J].Acta Sedi-mentologica Sinica,1996,14(2):1-11.
[14] 梅冥相,马永生,邓军,等.滇黔桂盆地及邻区二叠系乐平统层序地层格架及其古地理背景[J].中国科学(D辑),2007,37(5):605-617. Mei Mingxiang,Ma Yongsheng,Deng Jun,et al.Sequece stratigraphy framework and palaeogeographical setting of the Leping of the Permian of Dian-Qian-Gui Basin and its adjacent areas[J].Science in China(Series D),2007,37(5):605-617.
[15] 赵孟军,张水昌,赵陵,等.南盘江盆地古油藏沥青地球化学特征研究[J].地质学报,2006,80(6):893-901. Zhao Mengjun,Zhang Shuichang,Zhao Ling,et al.Geochemistry and genesis of bitumen in paleo-oil reservoir in the Nanpanjiang Basin,China[J].Acta Geologica Sinica,2006,80(6):893-901.
[16] 赵孟军,赵陵,张水昌,等.南盘江盆地主要烃源岩地球化学特征研究[J].石油实验地质,2006,28(2):162-167. Zhao Mengjun,Zhao Ling,Zhang Shuichang,et al.Geochemical characteristics of main source rocks in the Nanpanjiang Basin[J].Petroleum Geology & Experiment,2006,28(2):162-167.
[17] 赵孟军,张水昌,赵陵,等.南盘江盆地古油藏沥青、天然气的地球化学特征及成因[J].中国科学(D辑),2007,37(2):167-177. Zhao Mengjun,Zhang Shuichang,Zhao Ling,et al.Geochemistry and genesis of bitumen and gas in paleo-oil reservoir in the Nanpanjiang Basin,China[J].Science in China(Series D),2007,37(2):167-177.
[18] 冯庆来,蒙有言,何卫红,等.广西柳桥地区上二叠统礁灰岩中发现沥青[J].地球科学——中国地质大学学报,2007,32(6):868-870. Feng Qinglai,Meng Youyan,He Weihong,et al.Discovery of asphalt in the Upper Permian reef limestone in Liuqiao,Guang-xi[J].Earth Science—Journal of China University of Geoscien-ces,2007,32(6):868-870.
[19] 邱振,王清晨.桂西地区上二叠统硅质岩地球化学特征及对本区烃源岩发育潜力的指示意义[J].地质科学,2011,46(1):52-67. Qiu Zhen,Wang Qingchen.Geochemistry of the Upper Permian chert in the western Guangxi and its impact on forming hydrocarbon source rock[J].Chinese Journal of Geolgoy,2011,46(1):52-67.
[20] Huc A Y,Nederlof P,Debarre R,et al.Pyrobitumen occurrences and formation in a Cambro-Ordovician sandstone reservoir,Fahud Salt Basin,North Oman[J].Chemical Geology,2000,168(1-2):99-112.
[21] 高志农,胡华中.高压对天然沥青结构组成演变的影响[J].沉积学报,2002,20(3):499-503. Gao Zhizhong,Hu Huazhong.The influence of high pressure on the structural and compositional evolution of natural bitumen[J].Acta Sedimentologica Sinica,2002,20(3):499-503.
[22] 刘德汉,史继扬.高演化碳酸盐烃源岩非常规评价方法探讨[J].石油勘探与开发,1994,21(3) :113-115. Liu Dehan,Shi Jiyang.Discussion on non-conventional assessment methods of high evalution carbonate source rocks[J].Petroleum Exploration and Development,1994,21(3):113-115.
[23] 梁狄刚,陈建平.中国南方高、过成熟区海相油源对比问题[J].石油勘探与开发,2005,32(2):8-14. Liang Digang,Chen Jianping.Oil-source correlation for high and over matured marine source rocks in South China[J].Petroleum Exploration and Development,2005,32(2):8-14.
[24] 韦宝东.桂中坳陷泥盆系烃源岩特征[J].南方油气,2004,17(2):19-21. Wei Baodong.Features of hydrocarbon source rocks of Devonian in Guizhong Depression[J].Southern China Oil & Gas,2004,17(2):19-21.
[25] 贺训云,姚根顺,贺晓苏,等.桂中坳陷桂中1井沥青成因及油气成藏模式[J].石油学报,2010,31(3):420-425. He Xunyun,Yao Genshun,He Xiaosu,et al.Bitumen genesis and hydrocarbon accumulation pattern of Well Guizhong-1 in Guizhong Depression[J].Acta Petrolei Sinica,2010,31(3):420-425.
[26] 陈子炓,姚根顺,郭庆新,等.桂中坳陷海相地层油气成藏与热作用改造[J].海相油气地质,2010,15(3):1-10. Chen Ziliao,Yao Genshun,Guo Qingxin,et al.Hydrocarbon accumulation and thermal reconstruction of Neopaleozoic marine strata in Guizhong Depression[J].Marine Origin Petroleum Geology,2010,15(3):1-10.

广西崇左柳桥地区上二叠统礁灰岩中沥青的地球化学特征

Geochemical characteristics of bitumen in the Upper Permian reef limestone in Liuqiao(Chongzuo)area,Guangxi province

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