石油与天然气地质 ›› 2023, Vol. 44 ›› Issue (5): 1218-1230.doi: 10.11743/ogg20230511
• 油气地质 • 上一篇
吴进1,2(), 罗情勇1,2(), 钟宁宁1,2, 方子龙1,2, 段金材1,2, 张无忌1,2, 崔雅鑫1,2
收稿日期:
2023-03-07
修回日期:
2023-08-15
出版日期:
2023-10-01
发布日期:
2023-10-19
通讯作者:
罗情勇
E-mail:wujin209579@163.com;qingyong.luo@cup.edu.cn
第一作者简介:
吴进(1995—),男,博士研究生,有机岩石学与油气地球化学。E?mail: 基金项目:
Jin WU1,2(), Qingyong LUO1,2(), Ningning ZHONG1,2, Zilong FANG1,2, Jincai DUAN1,2, Wuji ZHANG1,2, Yaxin CUI1,2
Received:
2023-03-07
Revised:
2023-08-15
Online:
2023-10-01
Published:
2023-10-19
Contact:
Qingyong LUO
E-mail:wujin209579@163.com;qingyong.luo@cup.edu.cn
摘要:
华北北部中元古界下马岭组页岩是中国最古老的海相烃源岩之一,生源简单,有机质丰度高且成熟度低,但目前仍缺少对其显微组分面貌和成因的详细研究。通过有机岩石学方法,研究了下马岭组页岩中显微组分的组成、特征及其成因。结果表明,下马岭组页岩中显微组分组成较复杂,包括沥青质体、层状藻类体、类镜质组颗粒、矿物沥青基质和沥青铀钍矿。在显微镜下观察到类镜质组颗粒、沥青质体和层状藻类体存在光性过渡变化,它们的随机反射率呈现出逐渐减小的趋势,荧光逐渐增强。这种光性的过渡变化与它们的成因紧密相关。随着缺氧微生物降解作用的逐渐增强,层状藻类体会逐步降解形成沥青质体和类镜质组颗粒。有机质遭受放射性矿物颗粒的离子辐射聚合作用后形成沥青铀钍矿,其中放射性矿物颗粒主要为独居石和钍石。放射性矿物颗粒的热辐射对有机质成熟度有一定的影响,但是影响范围较小。
中图分类号:
表1
华北北部中元古界下马岭组页岩TOC、热解参数和元素分析参数[25]"
样品编号 | 采样类型 | TOC/% | S1/(mg/g) | S2/(mg/g) | (S1+S2)/(mg/g) | Tmax/℃ | HI/(mg/g) | VLM | EqRo/% | U含量/10-6 | Th含量/10-6 |
---|---|---|---|---|---|---|---|---|---|---|---|
XML-1 | 露头 | 8.48 | 0.96 | 34.25 | 35.21 | 434 | 404 | 0.56 | 0.42 | 2.49 | 7.70 |
XML-2 | 露头 | 2.19 | 0.50 | 7.03 | 7.53 | 432 | 321 | — | — | 1.93 | 6.14 |
XML-3 | 露头 | 4.30 | 0.71 | 15.85 | 16.56 | 434 | 368 | 0.53 | 0.39 | 2.81 | 5.74 |
XML-4 | 露头 | 14.10 | 1.66 | 62.73 | 64.39 | 442 | 445 | 0.54 | 0.39 | 2.69 | 8.59 |
XML-5 | 露头 | 5.80 | 0.45 | 18.96 | 19.41 | 441 | 327 | 0.58 | 0.44 | 2.45 | 10.20 |
XML-6 | 露头 | 4.56 | 0.72 | 21.50 | 22.22 | 439 | 472 | 0.60 | 0.46 | 3.01 | 6.11 |
XML-7 | 露头 | 2.84 | 0.23 | 8.94 | 9.17 | 440 | 315 | 0.48 | 0.33 | 2.91 | 5.22 |
表2
华北北部中元古界下马岭组页岩样品中类镜质组颗粒和沥青质体随机反射率"
样品 编号 | 类镜质组颗粒随机反射率 | 沥青质体随机反射率 | ||||||||
---|---|---|---|---|---|---|---|---|---|---|
最小值/% | 最大值/% | 平均值/% | 标准偏差/% | 测点数/个 | 最小值/% | 最大值/% | 平均值/% | 标准偏差/% | 测点数/个 | |
XML-1 | 0.45 | 0.66 | 0.56 | 0.06 | 30 | 0.16 | 0.26 | 0.19 | 0.03 | 30 |
XML-2 | — | — | — | — | — | 0.15 | 0.37 | 0.24 | 0.06 | 30 |
XML-3 | 0.47 | 0.63 | 0.53 | 0.04 | 30 | 0.23 | 0.39 | 0.30 | 0.05 | 30 |
XML-4 | 0.48 | 0.60 | 0.54 | 0.03 | 30 | 0.28 | 0.36 | 0.31 | 0.02 | 30 |
XML-5 | 0.49 | 0.68 | 0.58 | 0.05 | 30 | 0.20 | 0.25 | 0.23 | 0.01 | 30 |
XML-6 | 0.47 | 0.68 | 0.60 | 0.06 | 30 | 0.21 | 0.23 | 0.25 | 0.03 | 30 |
XML-7 | 0.44 | 0.56 | 0.48 | 0.03 | 30 | 0.22 | 0.34 | 0.29 | 0.04 | 30 |
表4
华北北部中元古界下马岭组页岩中沥青铀钍矿的放射性矿物颗粒元素组成"
样品 | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 独居石 | 锆石 | 钍石 | |
---|---|---|---|---|---|---|---|---|---|---|---|---|
元素 含量/% | O | 27.67 | 37.61 | 27.66 | 27.49 | 31.16 | 26.12 | 37.55 | 20.95 | nc | nc | nc |
Si | 0 | 12.19 | 0 | 0.04 | 0.14 | 0 | 5.58 | 9.14 | nc | 14.96 | 8.79 | |
P | 13.80 | 13.37 | 14.98 | 13.26 | 14.26 | 13.64 | 0 | 1.14 | 13.09 | nc | nc | |
Ca | 0 | 0 | 0 | 0 | 0.73 | 0 | 0 | 0.38 | nc | nc | nc | |
Y | 0 | 0 | 0 | 0 | 1.41 | 0 | 0 | 1.10 | nc | nc | nc | |
La | 14.16 | 4.69 | 12.84 | 15.60 | 8.80 | 11.16 | 0 | 0 | 11.08 | nc | nc | |
Ce | 32.01 | 25.03 | 32.71 | 34.76 | 23.22 | 30.27 | 0 | 0 | 23.05 | nc | nc | |
Pr | 1.51 | 0 | 1.73 | 0.63 | 2.43 | 2.67 | 0 | 0 | nc | nc | nc | |
Nd | 8.62 | 7.11 | 10.07 | 5.93 | 8.95 | 12.38 | 0 | 0 | 9.43 | nc | nc | |
Sm | 0 | 0 | 0 | 0 | 0.87 | 0 | 0 | 0 | nc | nc | nc | |
Th | 2.23 | 0 | 0 | 2.29 | 6.80 | 0 | 56.87 | 67.29 | 5.27 | nc | 69.88 | |
U | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | nc | nc | nc | |
Zr | 0 | 0 | 0 | 0 | 1.22 | 0 | 0 | 0 | nc | 47.38 | nc | |
Hf | 0 | 0 | 0 | 0 | 0 | 2.92 | 0 | 0 | nc | nc | nc | |
总含量 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | — | — | — | |
矿物颗粒 | 独居石 | 独居石 | 独居石 | 独居石 | 独居石 | 独居石 | 钍石 | 钍石 | — | — | — |
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