石油与天然气地质 ›› 2024, Vol. 45 ›› Issue (5): 1456-1482.doi: 10.11743/ogg20240518
李茜1,2(), 胡安平1,2(), 沈安江1,2, 张建勇1,2, 乔占峰1,2, 段军茂1,2
收稿日期:
2024-03-06
修回日期:
2024-07-30
出版日期:
2024-10-30
发布日期:
2024-11-06
通讯作者:
胡安平
E-mail:geolixi@126.com;huap_hz@petrochina.com.cn
第一作者简介:
李茜(1996—),男,博士研究生,沉积地球化学与沉积储层评价。E-mail: geolixi@126.com。
基金项目:
Xi LI1,2(), Anping HU1,2(), Anjiang SHEN1,2, Jianyong ZHANG1,2, Zhanfeng QIAO1,2, Junmao DUAN1,2
Received:
2024-03-06
Revised:
2024-07-30
Online:
2024-10-30
Published:
2024-11-06
Contact:
Anping HU
E-mail:geolixi@126.com;huap_hz@petrochina.com.cn
摘要:
全球广布的白云岩中蕴含着丰富的油气资源,但是白云岩的成因机理和储集空间保持机制还存在诸多疑问。分析研究了近年来白云岩的成因机理、储集空间控制因素与新型实验技术等方面研究取得的重大进展。①通过溶解-再沉淀方法成功合成出低温有序白云石,白云岩的形成受热力学和动力学屏障共同制约。②研究建立、拓展和完善了多种白云石化模型。新建了有机物(微生物)诱导模型,完善了无机物催化模型,修订了混合水白云石化模型,拓展了蒸发泵和渗透回流白云石化模型,细化了埋藏白云石化类型。③原始沉积环境和后期成岩改造对白云岩储层演化具有重要控制作用。适度的白云石化作用及次生溶蚀作用增加白云岩储层的孔隙空间,过度的胶结作用、大量热液矿物沉淀及轻-中度重结晶作用减少白云岩储层的孔隙空间。④发展了微区元素分析、Mg-Ca同位素、激光原位U-Pb同位素、团簇同位素、激光共聚焦-CT扫描成像解析及核磁共振-频谱激发极化实验新技术。研发了白云岩储层正演模拟技术、多尺度定量表征白云岩孔隙的三维结构和流动性技术,为白云石成因机理、储集空间研究提供重要的技术支持。
中图分类号:
图4
溶解的SiO2促进无序白云石沉淀的背散射电子成像(BSE)图像[45]a. 在20 ℃、溶解SiO2浓度为2 mM、初始Mg/Ca摩尔比为5∶1的条件下,合成的无序白云石的BSE图像(右下角为晶体能谱); b. 在40 ℃、溶解SiO2的浓度为2 mM、初始Mg/Ca摩尔比为5∶1的条件下,合成的无序白云石的BSE图像(右下角为晶体能谱); c. 在40 ℃、溶解SiO2的浓度为2 mM、初始Mg/Ca摩尔比为5∶1的条件下,合成的镁硅酸盐的BSE图像(右下角为晶体能谱); d. 无序白云石纳米晶体的明场透射电子显微镜(TEM)图像[右上角为晶体能谱,右下角为选区电子衍射(SAED)图像]; e. 被镁硅酸盐凝胶包围的无序白云石高角度环形暗场成像(HAADF)图像; f.e相同视域下显示Mg,Ca和Si元素分布的X射线能量散射谱图像"
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