塔里木盆地麦盖提斜坡罗斯2井奥陶系油气藏的TSR作用:来自分子标志物的证据

doi:10.11743/ogg20180410

石油与天然气地质 ›› 2018, Vol. 39 ›› Issue (4): 730-737,748.doi: 10.11743/ogg20180410

塔里木盆地麦盖提斜坡罗斯2井奥陶系油气藏的TSR作用:来自分子标志物的证据

马安来^1,2, 金之钧¹, 朱翠山³, 顾忆⁴, 李慧莉¹, 路清华⁴

1. 中国石化石油勘探开发研究院, 北京 100083;
2. 有机地球化学国家重点实验室, 广东广州 510640;
3. 长江大学资源学院, 湖北武汉 430100;
4. 中国石化石油勘探开发研究院无锡石油地质研究所, 江苏无锡 214126

收稿日期:2017-09-14 修回日期:2018-05-02 出版日期:2018-08-28 发布日期:2018-07-23
作者简介:马安来(1969-),男,副教授、博士,油气地球化学与成藏机理。E-mail:maal.syky@sinopec.com。
基金资助:
国家自然科学基金项目（41772153）；有机地球化学国家重点实验室开放基金项目（SKLOG-201702）；国家科技重大专项（2017ZX05005-002）；中石化科技部项目（P16090，P17049-1）。

Effect of TSR on the crude oil in Ordovician reservoirs of Well Luosi-2 from Maigaiti Slope,Tarim Basin: Evidences from molecular markers

Ma Anlai^1,2, Jin Zhijun¹, Zhu Cuishan³, Gu Yi⁴, Li Huili¹, Lu Qinghua⁴

1. Petroeum Exploration and Production Research Institute, SINOPEC, Beijing, 100083;
2. State Key Laboratory of Organic Geochemistry, Guangzhou, Guangdong 510640, China;
3. College of Resources and Environment, Yangtze University, Wuhan, Hubei 430100, China;
4. Wuxi Research Institute of Petroleum Geology Petroleum Exploration and Production Research Institute, SINOPEC, Wuxi, Jiangsu 214126, China

Received:2017-09-14 Revised:2018-05-02 Online:2018-08-28 Published:2018-07-23

摘要/Abstract

摘要：

采用内标物色谱质谱方法，对罗斯2井原油中金刚烷系列、二苯并噻吩系列和硫代金刚烷系列进行了定量分析。罗斯2井原油中金刚烷系列化合物含量、4-甲基双金刚烷+3-甲基双金刚烷含量分别为10 818，331 μg/g，表明原油经历了较强的裂解作用，裂解比例达到90%左右。金刚烷指标表明原油成熟度在1.6%以上。罗斯2井原油可以检测到完整的硫代单金刚烷、硫代双金刚烷和硫代三金刚烷系列，硫代金刚烷、硫代单金刚烷、硫代双金刚烷和硫代三金刚烷含量分别为192，160，26和6 μg/g。高含量的硫代金刚烷表明罗斯2井原油的TSR强度大于绝大多数塔中地区下奥陶统鹰山组原油。TSR作用导致罗斯2井原油具有较高含量的二苯并噻吩，含量为8 201 μg/g，使得原油二苯并噻吩/菲比值（DBT/P）增加，导致C₀-/C₁-DBTs和C₁-/C₂-DBTs比值增加。

关键词: 硫代金刚烷, 金刚烷, 二苯并噻吩, 硫酸盐热化学还原反应(TSR), 罗斯2井, 塔里木盆地

Abstract:

The study made a quantitative analysis of diamondoid, dibenzothiophenes and thiadiamondoid series in the crude oil from Well Luosi-2 via the GC-MS method with internal standards.The concentrations of diamondoid and 4-+3-methyldiamantane(4-+3-MD)are 10818 and 331 g/g in the study area,suggesting that the crude oil suffered serious cracking and the proportion of cracking oil is up to about 90%.The diamondoid indexes show that the maturity of crude oil from Well Luosi-2 is above 1.6% R_c.Complete thiaadamantane,thiadiamantane,thiatriamantane series were detected from the Well Luosi-2 crude oil,with the contents of thiadiamondoid,thiaadamantane,thiadiamantane,thiatriamantane being 192,160,26 and 6 μg/g respectively.The high concentration of thiadiamondoid is a sign that the degree of thermochemical sulfate reduction(TSR)of oil from Well Luosi-2 is higher than that of most crude oil from the Lower Ordovician Yingshan Formation in Tazhong uplift.TSR results in the higher DBTs, about 8 201 μg/g,in the oil from Well Luosi-2, and in turn the higher ratios of DBT/P,C₀-/C₁-DBT and C₁-/C₂-DBT.

Key words: thiadiamondoid, diamondoid, dibenzothiophene, thermochemical sulfate reduction(TSR), Well Luosi-2, Tarim Basin

中图分类号:

TE135

马安来,金之钧,朱翠山,等. 塔里木盆地麦盖提斜坡罗斯2井奥陶系油气藏的TSR作用:来自分子标志物的证据[J]. 石油与天然气地质, 2018, 39(4): 730-737,748. doi: 10.11743/ogg20180410 Ma Anlai,Jin Zhijun,Zhu Cuishan,et al. Effect of TSR on the crude oil in Ordovician reservoirs of Well Luosi-2 from Maigaiti Slope,Tarim Basin: Evidences from molecular markers[J]. Oil & Gas Geology, 2018, 39(4): 730-737,748. doi: 10.11743/ogg20180410

参考文献

[1] Orr W L.Changes in sulfur content and isotopic ratios of sulfur during petroleum maturation-Study of the Big Horn Paleozoic oils[J].AAPG Bulletin,1974,58(11):2295-2318.
[2] Worden R H,Smallwy P C,Oxtoby N H.Gas souring by thermochemical sulfate reduction at 140℃[J].AAPG Bulletin,1995,79(6):854-863.
[3] Machel H G,Krouse H R,Sassen R.Prodcuts and distinguishing criteria of bacterial and thermochemical sulfate reduction[J].Applied Geochemistry,1995,10(4):373-389.
[4] Cai C F,Worden R H,Wang Q F,et al.,Chemical and isotopic evidence for secondary alteration of natural gases in the Hetianhe Field,Bachu Uplift of the Tarim Basin[J].Organic Geochemistry,2002,33:1415-1427.
[5] Zhu G Y,Zhang S C,Liang Y B,et al.,Isotopic evidence of TSR origin for natural gas bearing high H2S content within Feixianguan Formation of the Northeastern Sichuan Basin,southwest China[J].Science in China Series D:Earth Science,2005,48(11):1037-1046.
[6] 朱光有,费安国,赵杰,等.TSR成因H₂S的硫同位素分馏特征与机制[J].岩石学报,2014,30(12):3772-3786. Zhu Guangyou,Fei Anguo,Zhao Jie,et al.,Sulfur isotopic fractionation and mechanism for thermochemical sulfate reduction genetic H2S[J].Acta Petrologica Sinica,2014,30(12):3772-3786.
[7] Walter C C,Wang F C,Qian Kuangnan,et al.,Petroleum alteration by thermochemical sulfate reduction:A comprehensive molecular study of aromatic hydrocarbons and polar compounds[J].Geochimica et Cosomochimica Acta,2015,153:37-71.
[8] Amrani A,Deev A,Sessions A L,et al.,The sulfur-isotopic compositions of benzothiophenes and dibenzothiophenes as a proxy for thermochemical sulfate reduction[J].Geochimica et Cosmochimica Acta,2012,84:152-164.
[9] Li Sumei,Amrani A,Pang Xiongqi,et al.,Origin and quantitative source assessment of deep oils in the Tazhong Uplift,Tarim Basin[J].Organic Geochemistry,2015,78:1-22.
[10] Gvirtzman Z,Said-Ahmad W,Ellis G S,et al.,Compound-specific sulfur isotope analysis of thiadiamondoids of oils from the Smackover Formation,USA[J].Geochimica et Cosmochimica Acta,2015,167:144-161.
[11] Cai Chunfang,Amrani A,Worden R H,et al.,Sulfur isotopic composition of individual organosulfur compounds and their genetic links in the Lower Paleozoic petroleum pools of the Tarim Basin,NW China[J].Geochimica et Cosmochimica Acta,2016,182:88-108.
[12] 朱心健,陈践发,贺礼文,等.塔里木盆地麦盖提斜坡罗斯2井油气地球化学特征及油气源分析[J].天然气地球科学,2017,28(4):566-574. Zhu Xinjian,Chen Jianfa,He Liwen,et al.Geochemical characteristics and source correlation of hydrocarbons in the Well Luosi 2 of Maigaiti Slope,Tarim Basin,China[J].Natural Gas Geoscience,2017,28(4):566-574.
[13] Chen Junhong,Fu Jiamo,Shen Guoying,et al.,Diamondoid hydrocarbon ratios:Novel maturity indices for highly mature crude oils[J].Organic Geochemistry,1996,25(3/4):179-190.
[14] 马安来.金刚烷类化合物在有机地球化学中的应用进展[J].天然气地球科学,2016,27(5):851-860. Ma Anlai.New advancement in application of diamondoids on organic geochemistry[J].Natural Gas Geoscience,2016,27(5):851-860.
[15] Dahl J E,Moldowan J M,Peter K E,et al.Diamondoid hydrocarbons as indicators of natural oil cracking[J].Nature,1999,399(5):54-56.
[16] 王广利,李宁熙,高波,等.麻江奥陶系古油藏中硫酸盐热化学还原反应:来自分子标志物的证据[J].科学通报,2013,58(33):3450-3457. Wang Guangli,Li Ningxi,Gao Bo,et al.Thermochemical sulfate reduction in fossil Ordovician deposits of the Majiang area:Evidence from a molecular-marker investigation[J].Chinese Science Bulletin,2013,58(33):3450-3457.
[17] Cai Chunfang,Xiao Qilin,Fang Chenchen,et al.The effect of thermochemical sulfate reduction on formation and isomerization of thiadiamondoids and diamondoids in the Lower Paleozoic petroleum pools of the Tarim Basin,NW China[J].Organic Geochemistry,2016,101:49-62.
[18] 马安来,金之钧,朱翠山,等.塔河油田原油中金刚烷化合物绝对定量分析[J].石油学报,2009,30(2):214-218. Ma Anlai,Jin Zhijun,Zhu Cuishan,et al.,Quantitative analysis on absolute concentration of diamondoids in oils from Tahe oilfield[J].Acta Petrolei Sinica,2009,30(2):214-218.
[19] 马安来,金之钧,朱翠山.塔里木盆地塔河油田奥陶系原油成熟度及裂解程度研究[J].天然气地球科学,2017,28(2):313-323. Ma Anlai,Jin Zhijun,Zhu Cuishan.Maturity and oil-cracking of the Ordovician oils from Tahe Oilfield,Tarim Basin,NW China[J].Natural Gas Geoscience,2017,28(2):313-323.
[20] Hanin S,Adam P,Kowalewski I,et al.,Bridgehead alkylated 2-thiaadamantanes:a novel markers for sulfurization processes occurring under high thermal stress in deep petroleum reservoirs[J].Journal of Chemical Society,Chemical Communications,2002,1750-1751.
[21] Wei Zhibin.Molecular organic geochemistry of cage compounds and biomarkers in the geosphere:a novel approach to understand petroleum evolution and alteration[D].California:Stanford University,2006.
[22] Wei Zhibin,C.C.Walters,J.M.Moldowan,et al.,Thiadiamondoids as proxies for the extent of thermochemical sulfate reduction[J].Organic Geochemistry,2012,44:53-70.
[23] 姜乃煌,朱光有,张水昌等.塔里木盆地塔中83井原油中检测出2-硫代金刚烷及其地质意义[J].科学通报,2007,52(24):2871-2875. Jiang Naihuang,Zhu Guangyou,Zhang Shuichang,et al.,Detection of 2-thiaadamantanes in the oil from Well TZ-83 in Tarim Basin and its geological implication[J].Chinese Science Bulletin,2007,52(24):2871-2875.
[24] Zhu Guangyou,Wang Huitong,Weng Na.TSR-altered oil with high-abundance thiaadamantanes of a deep-buried Cambrian gas condensate reservoir in Tarim Basin[J].Marine and Petroleum Geology,2016,69:1-12.
[25] 马安来,金之钧,朱翠山.塔里木盆地顺南1井原油硫代金刚烷系列的检出及意义[J].石油学报,2018,39(1):42-53. Ma Anlai,Jin Zhijun,Zhu Cuishan.Detection and research significance of thiadiamondoids from crude oil in Well Shunnan 1,Tarim Basin[J].Acta Petrolei Sinica,39(1):42:53.
[26] Wei Zhibin,Moldowan J M,Fago F,et a.,Origin of thiadiamondoids and diamondoidthiols in petroleum[J].Energy & Fuels,2007,21:3431-3436.
[27] Sinninghe Damste J S,Eglinton T L,de Leeuw J W,et al.,Organic Sulphur in macromolecular sedimentary organic matter.Part I.Structure and origin of Sulphur-containing moieties in kerogen,asphaltene and coal as revealed by flash pyrolysis[J].Geochimica et Cosmochimica Acta,1989,53:873-889.
[28] Hughes W B,Holba A G,Dzou L I.The ratios of dibenzothiophene to phenanthrene and pristine to phytane as indicators of depositional environment and lithology of petroleum source[J].Geochimica et Cosmochimica Acta,1995,59(17):3581-3598.
[29] Manzano B K,Fowler M G,Machel H G.The influence of thermochemical sulfate reduction on hydrocarbon composition in Nisku reservoirs,Brzaeau River area,alverta,Canada[J].Organic Geochemistry,1997,27:507-521.
[30] Zhang Shuichang,Su Jin,Huang Haiping,et al.,Genetic origin of sour gas condensates in the Paleozoic dolomite reservoirs of the Tazhong Uplift,Tarim Basin[J].Marine and Petroleum Geology,2015,68:107-119.
[31] Zhang Shuichang,Huang Haiping.Geochemistry of Palaeozoic marine petroleum from the Tarim Basin,NW China:Part 1.Oil family classification[J].Organic Geochemistry,2005,36:1204-1214.
[32] Zhang Shuichang,Huang Haiping,Su Jin,et al.,Geochemistry of Paleozoic marine petroleum from the Tarim Basin,NW China:Part 5.Effect of maturation,TSR and mixing on the occurrence and distribution of alkyldibenzothiophenes[J].Organic Geochemistry,2015,86:5-18.

塔里木盆地麦盖提斜坡罗斯2井奥陶系油气藏的TSR作用:来自分子标志物的证据

Effect of TSR on the crude oil in Ordovician reservoirs of Well Luosi-2 from Maigaiti Slope,Tarim Basin: Evidences from molecular markers

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

[1]	张天付, 黄理力, 倪新锋, 熊冉, 杨果, 孟广仁, 郑剑锋, 陈薇. 塔里木盆地柯坪地区下寒武统吾松格尔组岩性组合及其成因和勘探意义——亚洲第一深井轮探1井突破的启示[J]. 石油与天然气地质, 2020, 41(5): 928-940.
[2]	李慧莉, 李婧婧, 杨素举, 马中远. 塔里木盆地顺托果勒地区志留系成藏特征与勘探启示[J]. 石油与天然气地质, 2020, 41(5): 941-952.
[3]	郭春涛, 宋海强, 梁洁, 倪玲梅. 塔东地区米兰1井寒武系白云岩成因及其对储层的影响[J]. 石油与天然气地质, 2020, 41(5): 953-964.
[4]	王斌, 赵永强, 何生, 郭小文, 曹自成, 邓尚, 吴鲜, 杨毅. 塔里木盆地顺北5号断裂带北段奥陶系油气成藏期次及其控制因素[J]. 石油与天然气地质, 2020, 41(5): 965-974.
[5]	曹自成, 路清华, 顾忆, 吴鲜, 尤东华, 朱秀香. 塔里木盆地顺北油气田1号和5号断裂带奥陶系油气藏特征[J]. 石油与天然气地质, 2020, 41(5): 975-984.
[6]	宁超众, 胡素云, 潘文庆, 姚子修, 李勇, 袁文芳. 塔里木盆地哈拉哈塘地区奥陶系良里塔格组古地貌与岩溶洞穴特征[J]. 石油与天然气地质, 2020, 41(5): 985-995, 1047.
[7]	程洪, 张杰, 张文彪. 断溶体储层类型识别、预测及发育模式探讨——以塔里木盆地塔河十区TH10421单元为例[J]. 石油与天然气地质, 2020, 41(5): 996-1003.
[8]	何大祥, 唐友军, 胡锦杰, 莫少武, 陈践发. 塔里木盆地天然气中稀有气体地球化学特征[J]. 石油与天然气地质, 2020, 41(4): 755-762.
[9]	姚尧, 何治亮, 李慧莉, 张瑜, 高晓鹏, 王康宁, 焦存礼. 塔里木盆地阿瓦提断陷中-上奥陶统萨尔干组沉积地质模型与烃源岩分布预测[J]. 石油与天然气地质, 2020, 41(4): 763-775.
[10]	朱可丹, 张友, 林彤, 王雅春, 郑兴平, 朱琳. 基于CT成像的白云岩储层孔喉非均质性分析——以塔东古城地区奥陶系GC601井鹰三段为例[J]. 石油与天然气地质, 2020, 41(4): 862-873.
[11]	冯建伟, 孙建芳, 张亚军, 戴俊生, 魏荷花, 权莲顺, 任启强, 赵力彬. 塔里木盆地库车坳陷断层相关褶皱对裂缝发育的控制[J]. 石油与天然气地质, 2020, 41(3): 543-557.
[12]	孙福宁, 胡文瑄, 胡忠亚, 刘永立, 康逊, 朱峰. 断裂-层序双控机制下的热液活动及成储效应——以塔里木盆地塔河、玉北地区下奥陶统为例[J]. 石油与天然气地质, 2020, 41(3): 558-575.
[13]	闫亮, 季苗, 贾宝迁, 陈晓彤, 高平. 塔里木盆地顺北断溶体油气藏微生物特征及有利区预测[J]. 石油与天然气地质, 2020, 41(3): 576-585.
[14]	王朋, 孙灵辉, 王核, 李自安. 库车坳陷下侏罗统阿合组致密砂岩储层孔隙微观结构特征及其对致密气富集的控制作用[J]. 石油与天然气地质, 2020, 41(2): 295-304.
[15]	程丽娟, 李忠, 刘嘉庆, 于靖波. 塔里木盆地巴楚-塔中地区寒武系盐下白云岩储层成岩作用及物性特征[J]. 石油与天然气地质, 2020, 41(2): 316-327.