还原性流体-泥岩盖层相互作用的岩石学和地球化学记录——以松辽盆地南部王府凹陷青山口组泥岩为例

doi:10.11743/ogg20170514

石油与天然气地质 ›› 2017, Vol. 38 ›› Issue (5): 952-962.doi: 10.11743/ogg20170514

还原性流体-泥岩盖层相互作用的岩石学和地球化学记录——以松辽盆地南部王府凹陷青山口组泥岩为例

明晓冉¹, 刘立¹, 宋土顺², 刘娜¹, 杨会东³, 于雷¹, 白杭改¹

1. 吉林大学地球科学学院, 吉林长春 130061;
2. 华北理工大学矿业工程学院, 河北唐山 063009;
3. 中国石油吉林油田分公司勘探开发研究院, 吉林松原 138000

收稿日期:2017-03-31 修回日期:2017-08-12 出版日期:2017-10-28 发布日期:2017-11-10
通讯作者: 刘立(1955-),男,教授、博士生导师,储层、层序地层和沉积学。E-mail:liuli0892@vip.sina.com E-mail:liuli0892@vip.sina.com
第一作者简介:明晓冉(1988-),男,博士研究生,沉积岩石学。E-mail:mingy1@163.com。
基金项目:
国家自然科学基金面上项目（41172091，41572082，41372133）；河北省矿业开发与安全技术重点实验室开放基金项目（2016kykf02）。

Petrologic and geochemical records of interaction between reducing fluids and mudstone caprocks:A case from the mudstone in the Qingshankou Formation of Wangfu Depression in southern Songliao Basin

Ming Xiaoran¹, Liu Li¹, Song Tushun², Liu Na¹, Yang Huidong³, Yu Lei¹, Bai Hanggai¹

1. College of Earth Sciences, Jilin University, Changchun, Jilin 130061, China;
2. North China University of Science and Technology, Tangshan, Hebei 063009, China;
3. Research Institute of Exploration and Development, Jilin Oilfield Company, PetroChina, Songyuan, Jilin 138000, China

Received:2017-03-31 Revised:2017-08-12 Online:2017-10-28 Published:2017-11-10

摘要/Abstract

摘要： 天然气田（藏）中渗漏的还原性流体将导致泥岩盖层的成分（尤其是常量和微量元素）变化。这种变化记录了还原性流体-岩石相互作用事件，并具有指示油气藏位置的意义。利用天然类比方法，并以松辽盆地南部王府凹陷青山口组泥岩为对象，对天然气田（藏）中还原性流体引起的泥岩成分变化和流体在盖层中的运移方式进行了研究。结果表明：研究区渗漏流体的主要还原性成分为CH₄，其次为H₂S；在流体-岩石相互作用过程中，泥岩中红色的Fe³⁺被还原为无色的Fe²⁺，从而导致了漂白现象的出现。Fe²⁺以胶体的形式随流体运移至别处或以铁结核的形式重新沉淀；漂白过程中U含量的升高、Ga和Sc含量的降低，与U、Mo、V和Ni含量在纵向上的规律性变化均和流体的还原性有关；在泥岩盖层中，还原性流体主要在浮力的驱动下发生纵向运移，且地层抬升可导致其水位降低；天然气田（藏）泥岩盖层中微量元素的规律性变化具有指示还原性流体流动路径和方向的意义。

关键词: 泥岩盖层, 还原性流体, 漂白泥岩, 铁结核, 天然类比, 天然气田(藏), 松辽盆地

Abstract: Reducing fluids percolated from natural gas reservoirs or fields may cause composition variation (especially the macro and trace elements) of mudstone caprocks.The variation records the interaction between the reducing fluids and mudstone caprocks and may be used as an indicator of the locations of oil and gas reservoirs.By resorting to natural analogy,we studied the mudstone samples from the the Qingshankou Formation of Wangfu Depression in southern Songliao Basin to analyze the variation of mudstone composition caused by reducing fluids and the migration of the fluids in cap rocks of gas fields (reservoirs).The results show that the reducing components in the fluids are mainly methane,followed by hydrogen sulfide.During the fluid-rock interaction process,the red Fe³⁺ in the mudstone was reduced to colorless Fe²⁺,causing a phenomenon called bleach.The Fe²⁺ then migrated in the form of colloids with the fluids and reprecipitaed as iron concretions elsewhere.During the bleach process,the increasing U content,and decreasing Ga and Sc contents,as well as the veritical changes of the U,Mo,V and Ni contents,are suggested to be connected with the reductivity of the fluids.In mudstone caprocks,the reducing fluids were driven by buoyancy to migrate vertically and the uplifting of strata might cause dropping of fluid surface.The regular variation of trace elements in the mudstone caprocks may be used as indicators to the flow pathways and directions of the reductive fluids.

Key words: mudstone caprock, reducing fluid, bleached mudstone, iron concretion, natural analogy, natural gas field (reservoir), Songliao Basin

中图分类号:

TE122.1

明晓冉,刘立,宋土顺,等. 还原性流体-泥岩盖层相互作用的岩石学和地球化学记录——以松辽盆地南部王府凹陷青山口组泥岩为例[J]. 石油与天然气地质, 2017, 38(5): 952-962. doi: 10.11743/ogg20170514 Ming Xiaoran,Liu Li,Song Tushun,et al. Petrologic and geochemical records of interaction between reducing fluids and mudstone caprocks:A case from the mudstone in the Qingshankou Formation of Wangfu Depression in southern Songliao Basin[J]. Oil & Gas Geology, 2017, 38(5): 952-962. doi: 10.11743/ogg20170514

参考文献

[1] Garden I R,Guscott S C,Burley S D,et al.An exhumed palaeo-hydrocarbon migration fairway in a faulted carrier system,Entrada Sandstone of SE Utah,USA[J].Geofluids,2001,1(3):195-213.
[2] Beitler B,Chan M A,Parry W T.Bleaching of Jurassic Navajo Sandstone on Colorado Plateau Laramide highs:Evidence of exhumed hydrocarbon supergiants?[J].Geology,2003,31(12):1041-1044.
[3] Boles J R,Eichhubl P,Garven G,et al.Evolution of a hydrocarbon migration pathway along basin-bounding faults:Evidence from fault cement[J].AAPG bulletin,2004,88(7):947-970.
[4] Bowen B B,Martini B A,Chan M A,et al.Reflectance spectroscopic mapping of diagenetic heterogeneities and fluid-flow pathways in the Jurassic Navajo Sandstone[J].AAPG bulletin,2007,91(2):173-190.
[5] 马艳萍,刘池阳,赵俊峰,等.鄂尔多斯盆地东北部砂岩漂白现象与天然气逸散的关系[J].中国科学:地球科学,2007,37(SI):127-138. Ma Yanping,Liu Chiyang,Zhao Junfeng,et al.The relationship between the hydrocarbon leakage in northeastern Ordos Basin and the dissipation of natural gas[J].Scientia Sinica:Terrae,2007,37(SI):127-138.
[6] Petrovic A,Khan S D,Chafetz H S.Remote detection and geochemical studies for finding hydrocarbon-induced alterations in Lisbon Valley,Utah[J].Marine and Petroleum Geology,2008,25(8):696-705.
[7] Petrovic A,Khan S D,Thurmond A K.Integrated hyperspectral remote sensing,geochemical and isotopic studies for understanding hydrocarbon-induced rock alterations[J].Marine and Petroleum Geology,2012,35(1):292-308.
[8] 宋土顺,刘立,王玉洁,等.鄂尔多斯盆地漂白砒砂岩特征及成因[J].石油与天然气地质,2014,35(5):679-684. Song Tushun,Liu Li,Wang Yujie,et al.Characteristics and genesis of the bleached Pisha sandstone in Ordos Basin[J].Oil & Gas Geology,2014,35(5):679-684.
[9] Pons M J,Rainoldi A L,Franchini M,et al.Mineralogical signature of hydrocarbon circulation in Cretaceous red beds of the Barda González area,Neuquén Basin,Argentina[J].AAPG bulletin,2015,99(3):525-554.
[10] Rainoldi A L,Franchini M,Beaufort D,et al.Large-scale bleaching of red beds related to upward migration of hydrocarbons:Los Chihuidos High,Neuquen Basin,Argentina[J].Journal of Sedimentary Research,2014,84(5):373-393.
[11] Rainoldi A L,Franchini M,Beaufort D,et al.Mineral reactions associated with hydrocarbon paleomigration in the Huincul High,Neuquén Basin,Argentina[J].Geological Society of America Bulletin,2015,127(11-12):1711-1729.
[12] Chan M A,Johnson C M,Beard B L,et al.Iron isotopes constrain the pathways and formation mechanisms of terrestrial oxide concretions:A tool for tracing iron cycling on Mars?[J].Geosphere,2006,2(7):324-332.
[13] Chan M A,Ormö J,Park A J,et al.Models of iron oxide concretion formation:field,numerical,and laboratory comparisons[J].Geofluids,2007,7(3):356-368.
[14] Beitler B,Parry W T,Chan M A.Fingerprints of fluid flow:chemical diagenetic history of the Jurassic Navajo Sandstone,southern Utah,USA[J].Journal of Sedimentary Research,2005,75(4):547-561.
[15] Chan M A,Parry W T,Bowman J R.Diagenetic hematite and manganese oxides and fault-related fluid flow in Jurassic sandstones,southeastern Utah[J].AAPG bulletin,2000,84(9):1281-1310.
[16] Eichhubl P,Davatzes N C,Becker S P.Structural and diagenetic control of fluid migration and cementation along the Moab fault,Utah[J].AAPG bulletin,2009,93(5):653-681.
[17] Wigley M,Kampman N,Dubacq B,et al.Fluid-mineral reactions and trace metal mobilization in an exhumed natural CO₂ reservoir,Green River,Utah[J].Geology,2012,40(6):555-558.
[18] Duchscherer W.Geochemical hydrocarbon prospecting:with case histories[M].Tulsa:Pennwell Corporate,1984:1-30.
[19] Schumacher D.Hydrocarbon-induced alteration of soils and sediments[J].AAPG Memoir,1996,66:71-89.
[20] Parry W T,Chan M A,Beitler B.Chemical bleaching indicates episodes of fluid flow in deformation bands in sandstone[J].AAPG Bulletin,2004,88(2):175-191.
[21] Ming X R,Liu L,Yu M,et al.Bleached mudstone,iron concretions,and calcite veins:a natural analogue for the effects of reducing CO₂-bearing fluids on migration and mineralization of iron,sealing properties,and composition of mudstone cap rocks[J].Geofluids,2016,16(5):1017-1042.
[22] 陈发景,汪新文.含油气盆地地球动力学模式[J].地质论评,1996,42(4):304-309. Chen Fajing,Wang Xinwen.The geodynamic models of petroleum-bearing basins[J].Geological Review,1996,42(4):304-309.
[23] 邹才能,陶士振,张有瑜.松辽南部岩性地层油气藏成藏年代研究及其勘探意义[J].科学通报,2007,52(19):2319-2329. Zou Caineng,Tao Shizhen,Zhang Youyu.Exploration significance and accumulation time of lithologic stratigraphic oil and gas reservoirs in Songliao Basin[J].Chinese Science Bulletin,2007,52(19),2319-2329.
[24] 张学娟,张雷.松辽盆地北部登娄库组二段烃源岩分布定量研究[J].地质科学,2013,48(3):879-890. Zhang Xuejuan,Zhang Lei.Quantitive research on effective source rocks of the Denglouku Formation in northern Songliao Basin[J].Chinese Journal of Geology(Scientia Geologica Sinica),2013,48(3):879-890.
[25] 陈方文,卢双舫,石美娟.松辽盆地王府凹陷断层特征及对油气的控制[J].中南大学学报(自然科学版),2012,43(1):254-262. Chen Fangwen,Lu Shuangfang,Shi Meijuan.Characteristics of fault and its control on oil-gas in Wangfu Depression of Songliao Basin[J].Journal of Central South University(Science and Technology),2012,43(1):254-262.
[26] 邹才能,薛叔浩,赵文智,等.松辽盆地南部白垩系泉头组-嫩江组沉积层序特征与地层-岩性油气藏形成条件[J].石油勘探与开发,2004,31(2):14-17. Zou Caineng,Xue Shuhao,Zhao Wenzhi,et al.Depositional sequences and forming conditions ofthe Cretaceous stratigraphic-lithologic reservoirs in the Quantou-Nengjiang Formations,South Songliao Basin[J].Petroleum Exploration and Development,2004,31(2):14-17.
[27] 郭巍.松辽盆地南部白垩纪构造沉积演化与成藏动力学研究[D].长春:吉林大学,2007. Guo Wei.The study of Cretaceous tectono-sedimentary evolution and petroleum accumulation dynamics in southern Songliao basin[D].Changchun:Jilin University,2007.
[28] 郭英海,李壮福,李熙哲,等.松辽盆地王府凹陷的沉积充填及生储盖组合[J].中国矿业大学学报,2001,30(1):30-34. Guo Yinghai,Li Zhuangfu,Li Xizhe,et al.Sedimentary Filling and Source-Reservoir-Seal Combination at Wangfu Depression[J].Journal of China University of Mining & Technology,2001,30(1):30-34.
[29] 叶龙.王府断陷火山岭组天然气分布规律研究[D].大庆:东北石油大学,2014. Ye Long.The study of nature gas distributing in the Huoshiling Formation,Wangfu Fault Depression[D].Daqing:Northeast Petroleum University,2014.
[30] 蔡尧忠,刘玉梅,袁智广.松辽盆地东南隆起区油气地质特征[J].吉林地质,2002,21(3):22-28. Cai Yaozhong,Liu Yumei,Yuan Zhiguang.Geological features of oil and gas in the southeast upwelling area,Songliao Basin[J].Jilin Geology,2002,21(3):22-28.
[31] 罗霞,孙粉锦,邵明礼,等.松辽盆地深层煤型气与气源岩地球化学特征[J].石油勘探与开发,2009,36(3):339-346. Luo Xia,Sun Fenjin,Shao Mingli,et al.Geochemistry of deep coal-type gas and gas source rocks in Songliao Basin[J].Petroleum Exploration and Development,2009,36(3):339-346.
[32] 潘红卫,石存英,王晶淼,等.王府断陷天然气藏的识别[J].石油地球物理勘探,2012,47(S1):97-102. Pan Hongwei,Shi Cunying,Wang Jingsen,et al.Gas reservoir identification in Wangfu Fault Depression[J].Oil Geophysical Prospecting,2012,47(S1):97-102.
[33] 杨庆杰,林景晔,王雅峰.松辽盆地长春岭背斜带油气成藏过程探讨[J].石油天然气学报,2007,29(3):11-14. Yang Qingjie,Lin Jingye,Wang Yafeng.On reservoir forming process of Changchunling Anticlinal Belt in Songliao Basin[J].Journal of Oil and Gas Technology,2007,29(3):11-14.
[34] Mc Crea J M.On the isotopic chemistry of carbonates and a paleotemperature scale[J].The Journal of Chemical Physics,1950,18(6):849-857.
[35] Roser B P,Korsch R J.Provenance signatures of sandstone-mudstone suites determined using discriminant function analysis of major-element data[J].Chemical geology,1988,67(1-2):119-139.
[36] Sun S S,Mcdonough W F.Chemical and isotopic systematics of oceanic basalts:implications for mantle composition and processes[J].Geological Society London Special Publications,1989,42(1):313-345.
[37] Pearce J M,Kirby G A,Lacinska A,et al.Reservoir-scale CO₂-fluid rock interactions:Preliminary results from field investigations in the Paradox Basin,Southeast Utah[J].Energy Procedia,2011,4:5058-5065.
[38] Lee M K,Bethke C M.Groundwater flow,late cementation,and petroleum accumulation in the Permian Lyons Sandstone,Denver Basin[J].AAPG bulletin,1994,78(2):217-237.
[39] Rowe J,Burley S D.Faulting and porosity modification in the Sherwood Sandstone at Alderley Edge,northeastern Cheshire:an exhumed example of fault-related diagenesis[J].Geological Society London Special Publications,1997,124(1):325-352.
[40] 张勇.松辽盆地南部小城子地区登娄库组-泉一段储层特征研究[D].长春:吉林大学,2013. Zhang Yong.Research on reservoir characteristis of Denlongku group-Quan 1 section in Xiaochenzi area,the South of Songliao Basin[D].Changchun:Jilin University,2013.
[41] Garden I R,Guscott S C,Foxford K A,et al.An exhumed fill and spill hydrocarbon fairway in the Entrada sandstone of the Moab anticline,Utah[C]//Hendry J,CareyP,ParnellJ,et al.,eds.Migrationand interaction in sedimentary basins and orogenic belts:Geofluids.Second International Conference on Fluid Evolution,Belfast,Northern Ireland,1997,287-290.
[42] Zolotov M Y,Shock E L.Formation of jarosite-bearing deposits through aqueous oxidation of pyrite at Meridiani Planum,Mars[J].Geophysical Research Letters,2005,32(21):365-370.
[43] Nordstrom D K,Alpers C N.Negative pH,efflorescent mineralogy,and consequences for environmental restoration at the Iron Mountain Superfund site,California[J].Proceedings of the National Academy of Sciences,1999,96(7):3455-3462.
[44] Loope D B,Kettler R M,Weber K A,et al.Rinded iron-oxide concretions:hallmarks of altered siderite masses of both early and late diagenetic origin[J].Sedimentology,2012,59(6):1769-1781.
[45] Loope D B,Kettler R M.The footprints of ancient CO₂-driven flow systems:Ferrous carbonate concretions below bleached sandstone[J].Geosphere,2015,11(3):943-957.
[46] Goldhaber M B,Reynolds R L,Rye R O.Role of fluid mixing and fault-related sulfide in the origin of the Ray Point uranium district,south Texas[J]].Economic Geology,1983,78(6):1043-1063.

还原性流体-泥岩盖层相互作用的岩石学和地球化学记录——以松辽盆地南部王府凹陷青山口组泥岩为例

Petrologic and geochemical records of interaction between reducing fluids and mudstone caprocks:A case from the mudstone in the Qingshankou Formation of Wangfu Depression in southern Songliao Basin

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